Composition containing recycled materials for pipes

Patent metadata

Field	Value
Publication number	US-12084565-B2
Application number	US-202017593630-A
Country	US
Kind code	B2
Filing date	Mar 16, 2020
Priority date	Mar 29, 2019
Publication date	Sep 10, 2024
Grant date	Sep 10, 2024

Abstract

Composition comprising a heterophasic propylene copolymer with low melt flow rate and rather low amount of xylene cold solubles and a recycled polymer composition being rich in polypropylene.

First claim

The invention claimed is:

1. A composition comprising a recycled polymer composition (RPC) and a heterophasic propylene copolymer (HECO), the composition is obtained by blending,
wherein
(a) the recycled polymer composition (RPC) comprises at least 80 wt.-%, based on the weight of the recycled polymer composition (RPC), of a recycled polypropylene, and
(b) the heterophasic propylene copolymer (HECO) has
(b1) a xylene cold soluble (XCS) fraction determined at 25° C. according to ISO 16152 in the range of 5.0 to 18 wt.-%, and
(b2) a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 in the range of 0.05 to 1.5 g/10 min,

wherein further
(a) the weight ratio between the heterophasic propylene copolymer (HECO) and the recycled polymer composition (RPC) [(HECO)/(RPC)] is in the range of 1.1 to 7.0, (b) the percentage by weight of the heterophasic propylene copolymer (HECO) together with the recycled polymer composition (RPC) [(HECO)+(RPC)], based on the weight of the composition, is at least 85 wt.-%, and (c) the composition has a tensile modulus measured according to ISO 527-2 in the range of 1100 to 1600 MPa and/or a content of limonene as determined using solid phase microextraction (HS-SPME-GC-MS) of from 0.5 to 40 mg/kg.

2. The composition according to claim 1 consisting of the recycled polymer composition (RPC), the heterophasic propylene copolymer (HECO) and optional additives (AD).

3. The composition according to claim 2 , wherein:
(a) the percentage by weight of the heterophasic propylene copolymer (HECO) together with the recycled polymer composition (RPC) [(HECO)+(RPC)], based on the weight of the composition, is at least 90 wt.-%,

and
(b) the remaining part up to 100 wt.-%, based on the weight of the composition are additives (AD).

4. The composition according to claim 1 , wherein the composition has a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 in the range of 0.05 to 2.0 g/10 min.

5. The composition according to claim 1 , wherein the recycled polymer composition (RPC) has
(a) a content of limonene determined by using solid phase microextraction (HS-SPME-GC-MS) of from 5 to 100 mg/kg;

and/or
(b) a total fatty acid content determined by using solid phase microextraction (HS-SPME-GC-MS) of from 20 to 100 mg/kg.

6. The composition according to claim 1 , wherein the recycled polymer composition (RPC) additionally comprises minor amounts of recycled polyethylene, recycled polystyrene, recycled polyamide and inorganic compounds selected from the group consisting of talc, chalk and mixtures thereof,
with the proviso that the amounts are as follows:
(a) not more than 15.0 wt.-%, based on the weight of the recycled polymer composition (RPC), of recycled polyethylene;
(b) not more than 8.00 wt.-%, based on the weight of the recycled polymer composition (RPC), of recycled polystyrene;
(c) not more than 1.50 wt.-%, based on the weight of the recycled polymer composition (RPC), of recycled polyamide; and
(d) not more than 2.50 wt.-% based on the weight of the recycled polymer composition (RPC), of inorganic components selected from the group consisting of talc, Chalk, and mixtures thereof.

7. The composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) contains only propylene and ethylene derived units, wherein further
(a) the heterophasic propylene copolymer (HECO) has an ethylene content determined by 13 C-NMR spectroscopy in the range of 3.0 to 8.0 wt.-%, and/or
(b) the ethylene content of the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO) determined by 13 C-NMR spectroscopy is in the range of 30 to 36 wt.-%.

8. The composition according to claim 1 , wherein the intrinsic viscosity determined according to DIN ISO 1628/1 (in decalin at 135° C.) of the xylene cold soluble (XCS) fraction of the heterophasic propylene copolymer (HECO) is in the range of 2.9 to 4.5 dl/g.

9. The composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) comprises a semicrystalline propylene homopolymer (PPH) as matrix in which a propylene-ethylene rubber as elastomeric propylene copolymer (EPC) is dispersed.

10. The composition according to claim 9 , wherein the semicrystalline propylene homopolymer (PPH) has a melt flow rate MFR 2 (230 C/2.16 kg) measured according to ISO 1133 in the range of 0.05 to 1.5 g/10 min.

11. The composition according to claim 9 , wherein the semicrystalline polypropylene (PPH) comprises two semicrystalline propylene homopolymer fractions (PPH1) and (PPH2),
wherein
(a) the percentage by weight of the two semicrystalline propylene homopolymer fractions (PPH1) and (PPH2) together ((PPH1)+(PPH2)), based on the weight of the semicrystalline propylene homopolymer (PPH), is at least 90 wt.-%;

and
(b) weight ratio between the two semicrystalline propylene homopolymer fractions (PPH1) and (PPH2) ((PPH1)/(PPH2)) is in the range of 0.8 to 1.4;

wherein further
(c) the semicrystalline propylene homopolymer fraction (PPH1) has a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 in the range of 0.01 to 1.0 g/10 min;

and
(d) the semicrystalline propylene homopolymer (PPH) has a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 in the range of 0.05 to 2.0 g/10 min.

12. The composition according to claim 11 , wherein the melt flow rate MFR2 ratio of the semicrystalline propylene homopolymer (PPH) to the semicrystalline propylene homopolymer fraction (PPH1) (MFR2 (PPH)/MFR2(PPH1)) is at least 3.

13. The composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO) is alpha-nucleated.

14. A process for producing a composition according to claim 1 , wherein the heterophasic propylene copolymer (HECO), the recycled polymer composition (RPC) and any optional additives (AD) are mixed, obtaining thereby the composition.

15. A pipe comprising at least 90 wt.-%, based on the weight of the pipe, of a composition according to claim 1 .

16. The composition according to claim 1 , wherein the recycled polymer composition (RPC) has a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 of at least 8.0 g/10 min.

Assignees

• Borealis Ag

Inventors

• Ruemer Franz
• Boragno Luca
• Schiesser Stefan
• Dreiling Guenter
• Hollsten Christian
• Liedauer Siegfried
• Ollikainen Andrei
• Pezard Thierry

Classifications

• C08L2207/20

  Recycled plastic · CPC title

• C08L2207/10

  Peculiar tacticity · CPC title

• C08L2207/02

  Heterophasic composition · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C08L2203/18

  used for pipes · CPC title