Foamable polypropylene composition

Patent metadata

Field	Value
Publication number	US-12084564-B2
Application number	US-201917278028-A
Country	US
Kind code	B2
Filing date	Oct 2, 2019
Priority date	Oct 8, 2018
Publication date	Sep 10, 2024
Grant date	Sep 10, 2024

Abstract

The present invention relates to a polypropylene composition, an injection molded article comprising the polypropylene composition, a foamed article comprising the polypropylene composition as well as the use of said polypropylene composition for reducing the stiffness reduction factor of a foamed injection molded article by at least 200 as determined by the difference of the flexural modulus measured according to ISO 178 of the non-foamed and foamed injection molded article.

First claim

The invention claimed is:

1. A polypropylene composition comprising:
a) from 65 to 85 wt. %, based on the total weight of the composition, of a polypropylene homopolymer (HPP),
b) from 10 to 35 wt. %, based on the total weight of the composition, of a polypropylene copolymer (CPP),
c) from 0 to 20 wt. %, based on the total weight of the composition, of a filler (F), wherein the filler (F) is selected from the group consisting of talcum, mica, wollastonite, glass fibers, carbon fibers, and mixtures thereof, and
d) from 2.5 to 5 wt. %, based on the total weight of the composition, of at least one additive selected from the group consisting of colorants, pigments, stabilisers, acid scavengers, foaming agents, antioxidants and mixtures thereof,
wherein the composition comprises from 0.1 to 0.5 wt. %, based on the total weight of the composition, of one or more nucleating agents, and
wherein the sum of the amount of the polypropylene homopolymer (HPP), the polypropylene copolymer (CPP), the filler (F), the at least one additive and the one or more nucleating agents in the polypropylene composition is 100.0 wt. %,
wherein the polypropylene homopolymer (HPP) has:
i) a melting temperature Tm measured by differential scanning calorimetry (DSC) in the range from 150 to 160° C.,
ii) a content of 2,1 erythro regiodefects as determined from 13 C-NMR spectroscopy in the range from 0.50 to 1.00 mol. %,
iii) an isotactic triad fraction (mm) determined from 13 C-NMR spectroscopy of at least 97.5%, and
iv) a xylene cold soluble fraction (XCS) determined at 23° C. according ISO 16152 of equal or below 1.5 wt. %.

2. The polypropylene composition according to claim 1 , wherein the composition comprises:
a) from 65 to 75 wt. %, based on the total weight of the composition, of the polypropylene homopolymer (HPP),
b) from 25 to 35 wt. %, based on the total weight of the composition, of a polypropylene copolymer (CPP), and
c) from 2.5 to 5 wt. %, based on the total weight of the composition, of at least one additive selected from the group consisting of colorants, pigments, stabilisers, acid scavengers, foaming agents, antioxidants and mixtures thereof.

3. The polypropylene composition according to claim 1 , wherein the polypropylene composition has:
a) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 15.0 to 80.0 g/10 min; and/or
b) a content of volatile organic compounds no greater than 150 μg/g composition in pellet form; and/or
c) a glass transition temperature Tg (measured with DMTA according to ISO 6721-7) of −10° C. or above.

4. The polypropylene composition according to claim 1 , wherein the polypropylene homopolymer (HPP) has been polymerized in the presence of a Ziegler-Natta catalyst or a single-site catalyst.

5. The polypropylene composition according to claim 1 , wherein the polypropylene copolymer (CPP) has been polymerized in the presence of a Ziegler-Natta catalyst or a single-site catalyst.

6. The polypropylene composition according to claim 1 , wherein the polypropylene copolymer (CPP) is a random copolymer of propylene with ethylene and/or C4 to C8 alpha-olefins.

7. The polypropylene composition according to claim 1 , wherein the polypropylene copolymer (CPP) has:
i) a comonomer content in the range from 2.0 to 6.0 wt. %; and/or
ii) a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 in the range of 0.1 to 10.0 g/10 min.

8. A injection molded article comprising the polypropylene composition according to claim 1 .

9. The injection molded article according to claim 8 , wherein the article has:
i) a flexural modulus measured according to ISO 178 of at least 1000 MPa; and/or
ii) a puncture energy measured according to ISO 6603-2 of at least 3.5 J.

10. A foamed article, comprising the polypropylene composition according to claim 1 .

11. The foamed article according to claim 10 , wherein the foamed article has a stiffness reduction factor of that is reduced by at least 200 compared to a stiffness reduction factor for a foamed article comprising the polypropylene homopolymer (HPP) without the polypropylene copolymer (CPP), wherein the stiffness reduction factor is determined by the difference of the flexural modulus measured according to ISO 178 of a non-foamed injection molded article comprising the polypropylene composition and the foamed injection molded article.

Assignees

• Borealis Ag

Inventors

• Mileva Daniela
• Kahlen Susanne
• Rover Patrick
• Grestenberger Georg
• Wang Jingbo
• Bernreitner Klaus
• Gahleitner Markus

Classifications

• C08J2423/14

  Copolymers of propene (C08J2423/16 takes precedence) · CPC title

• C08J2323/12

  Polypropene · CPC title

• C08J9/04

  using blowing gases generated by a previously added blowing agent · CPC title

• C08L23/12 Primary

  Polypropene · CPC title

• C08L2314/06

  Metallocene or single site catalysts · CPC title