Sinter powder containing a multivalent alcohol for producing moulded bodies

Patent metadata

Field	Value
Publication number	US-12084560-B2
Application number	US-201917256410-A
Country	US
Kind code	B2
Filing date	Jun 25, 2019
Priority date	Jun 27, 2018
Publication date	Sep 10, 2024
Grant date	Sep 10, 2024

Abstract

The present invention relates to a method of producing a shaped body, wherein, in step i), a layer of a sinter powder (SP) comprising at least one polyhydric alcohol inter alia is provided and, in step ii), the layer provided in step i) is exposed. The present invention further relates to a method of producing a sinter powder (SP) and to a sinter powder (SP) obtainable by this method. The present invention also relates to use of the sinter powder (SP) in a sintering method, and shaped bodies obtainable by the method of the invention.

First claim

The invention claimed is:

1. A method of producing a shaped body, comprising the steps of:
i) providing a layer of a sinter powder (SP) comprising the following components
(A) at least one semicrystalline polyamide,
(B) at least one amorphous polyamide,
(C) at least one polyhydric alcohol,
(D) optionally at least one additive,
(E) optionally at least one reinforcer and
(F) optionally at least one mineral flame retardant,

ii) exposing the layer of the sinter powder (SP) provided in step i).

2. The method according to claim 1 , wherein component (C) has a number-average molecular weight (M n ) of less than 2000 g/mol.

3. The method according to claim 1 , wherein component (C) is selected from the group consisting of glycerol, trimethylolpropane, 2,3-di-(2′-hydroxyethyl)cyclohexan-1-ol, hexane-1,2,6-triol, 1,1,1-tris(hydroxymethyl)ethane, 3-(2′-hydroxyethoxy)propane-1,2-diol, 3-(2′-hydroxypropoxy)propane-1,2-diol, 2-(2′-hydroxyethoxy)hexane-1,2-diol, 6-(2′-hydroxypropoxy)hexane-1,2-diol, 1,1,1-tris-[(2′-hydroxyethoxy)methyl]ethane, 1,1,1-tris-[(2′-hydroxypropoxy)methyl]propane, 1,1,1-tris-(4′-hydroxyphenyl)ethane, 1,1,1-tris-(hydroxyphenyl)propane, 1,1,3-tris-(dihydroxy-3-methylphenyl)propane, 1,1,4-tris(dihydroxyphenyl)butane, 1,1,5-tris(hydroxyphenyl)-3-methylpentane, ditrimethylopropane, trimethylolpropane ethoxylates, trimethylolpropane propoxylates, pentaerythritol, dipentaerythritol, tripentaerythritol, cyclodextrins, D-mannose, glucose, galactose, sucrose, fructose, xylose, arabinose, D-mannitol, D-sorbitol, D-arabitol, L-arabitol, xylitol, iditol, talitol, allitol, altritol, gulitol, erythritol, threitol and D-gulono-γ-lactone.

4. The method according to claim 1 , wherein component (A) is selected from the group consisting of PA 4, PA 6, PA 7, PA 8, PA 9, PA 11, PA 12, PA 46, PA 66, PA 69, PA 6,10, PA 6,12, PA 6,13, PA 6/6,36, PA 6T/6, PA 12,12, PA 13,13, PA 6T, PA MXD6, PA 6/66, PA 6/12 and copolyamides of these.

5. The method according to claim 1 , wherein component (B) is selected from the group consisting of PA 6I/6T, PA 6I and PA 6/3T.

6. The method according to claim 1 , wherein component (B) comprises at least 3% by weight of PA 6I/6T, based on the total weight of component (B).

7. The method according to claim 1 , wherein the sinter powder (SP) comprises in the range from 35% to 96.95% by weight of component (A), in the range from 3% to 45% by weight of component (B), in the range from 0.05% to 20% by weight of component (C), in the range from 0% to 10% by weight of component (D), in the range from 0% to 44.95% by weight of component (E) and in the range from 0% to 60% by weight of component (F), based in each case on the total weight of the sinter powder (SP).

8. The method according to claim 1 , wherein component (D) is selected from the group consisting of antinucleating agents, stabilizers, conductive additives, end group functionalizers, dyes and color pigments.

9. The method according to claim 1 , wherein component (E) is selected from the group consisting of carbon nanotubes, carbon fibers, boron fibers, glass fibers, glass beads, silica fibers, ceramic fibers, basalt fibers, aluminosilicates, aramid fibers and polyester fibers.

10. The method according to claim 1 , wherein the component (F) is based on magnesium and/or aluminum.

11. A method of producing a sinter powder (SP) according to claim 1 , comprising the steps of
a) providing the following components
(A) at least one semicrystalline polyamide,
(B) at least one amorphous polyamide,
(C) at least one polyhydric alcohol,
(D) optionally at least one additive,
(E) optionally at least one reinforcer and
(F) optionally at least one mineral flame retardant,

b) grinding the mixture obtained in step a) to obtain the sinter powder (SP).

12. A sinter powder (SP) obtainable by the process according to claim 11 .

13. The use of a sinter powder (SP) comprising the following components
(A) at least one semicrystalline polyamide,
(B) at least one amorphous polyamide,
(C) at least one polyhydric alcohol,
(D) optionally at least one additive,
(E) optionally at least one reinforcer and
(F) optionally at least one mineral flame retardant,
in a sintering process.

14. A shaped body obtainable by a process according to claim 1 .

15. A sinter powder comprising the following components
(A) at least one semicrystalline polyamide,
(B) at least one amorphous polyamide,
(C) at least one polyhydric alcohol,
(D) optionally at least one additive,
(E) optionally at least one reinforcer and
(F) optionally at least one mineral flame retardant.

16. The sinter powder (SP) according to claim 15 , wherein the sinter powder has a median particle size (D50) in the range from 40 to 80 μm.

Assignees

• Basf Se

Inventors

• Gabriel Claus
• Wagner Sebastian
• Herle Natalie Beatrice Janine
• Meier Thomas

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2201/02

  Flame or fire retardant/resistant · CPC title

• C08L77/06

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• B29K2995/0041

  Crystalline · CPC title

• B29K2995/0039

  Amorphous · CPC title