Method for producing super absorber particles

Patent metadata

Field	Value
Publication number	US-12084527-B2
Application number	US-201916968192-A
Country	US
Kind code	B2
Filing date	Feb 11, 2019
Priority date	Feb 22, 2018
Publication date	Sep 10, 2024
Grant date	Sep 10, 2024

Abstract

A process for producing superabsorbent particles, comprising drying of a polymer gel, removal of incompletely dried polymer particles, comminution of the polymer particles removed, recycling of the comminuted polymer particles and storage of the recycled polymer particles.

First claim

The invention claimed is:

1. A process for producing superabsorbent particles by polymerizing a monomer solution or suspension comprising
a) at least one ethylenically unsaturated monomer which bears an acid group and optionally is at least partly neutralized,
b) at least one crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a), and
e) optionally one or more water-soluble polymer,

to provide a polymer gel comprising
i) drying the polymer gel to produce a dried polymer gel,
ii) classifying the dried polymer gel from step i) to obtain at least one fraction of incompletely dried polymer particles and at least one fraction of dried polymer particles, and
iii) comminuting the incompletely dried polymer particles from step ii),
which comprises recycling the comminuted polymer particles from step iii) into the dried polymer gel before step ii) or into the dried polymer particles after step ii) and iv) storing together in a vessel for a period of at least 5 minutes,
wherein the vessel used for storage is thermally insulated and/or trace heated.

2. The process according to claim 1 , wherein the comminuted polymer particles from step iii) are recycled into the dried polymer gel before step ii) and stored together with the dried polymer gel before step ii) in a vessel for a period of at least 5 minutes.

3. The process according to claim 2 , wherein the dried polymer particles from step ii) are ground by means of at least one multistage roll mill and classified by means of at least one tumbler screening machine.

4. The process according to claim 1 , wherein the comminuted polymer particles from step iii) are recycled into the dried polymer particles after step ii) and stored together with the dried polymer particles after step ii) in a vessel for a period of at least 5 minutes.

5. The process according to claim 4 , wherein the stored polymer particles are ground by means of at least one multistage roll mill and classified by means of at least one tumbler screening machine.

6. The process according to claim 3 , wherein the ground and classified polymer particles are thermally surface postcrosslinked.

7. The process according to claim 1 , wherein the storage period in the vessel is from 30 to 120 minutes.

8. The process according to claim 1 , wherein the dried polymer particles obtained in step ii) have a moisture content of less than 5% by weight.

9. The process according to claim 1 , wherein the incompletely dried polymer particles obtained in step ii) have a moisture content at least 10% by weight higher than the dried polymer particles obtained in step ii).

10. The process according to claim 1 , wherein the incompletely dried polymer particles obtained in step ii) have a particle size of at least 8 mm.

11. The process according to claim 1 , wherein the incompletely dried polymer particles are comminuted in step iii) to a particle size of less than 8 mm.

12. The process according to claim 1 , wherein the incompletely dried polymer particles are comminuted in step iii) by means of a mill with sharp beaters or blades and a screen as grinding space boundary.

13. The process according to claim 1 , wherein the polymer particles have a temperature in the range from 60 to 100° C. during the storage in the vessel.

14. The process according to claim 1 , wherein ethylenically unsaturated monomer bearing an acid group is acrylic acid.

15. The process according to claim 5 , wherein the ground and classified polymer particles are thermally surface postcrosslinked.

16. A process for producing superabsorbent particles by polymerizing a monomer solution or suspension comprising
a) at least one ethylenically unsaturated monomer which bears an acid group and optionally is at least partly neutralized,
b) at least one crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a) and
e) optionally one or more water-soluble polymer to provide a polymer gel,
comprising
i) drying the polymer gel to produce a dried polymer gel,
ii) classifying the dried polymer gel from step i) to obtain at least one fraction of incompletely dried polymer particles and at least one fraction of dried polymer particles and
iii) comminuting the incompletely dried polymer particles from step ii),
which comprises recycling the comminuted polymer particles from step iii) into the dried polymer gel before step ii) or into the dried polymer particles after step ii) and (iv) storing them together in a vessel for a period of at least 5 minutes, wherein the comminuted polymer particles from step iii) are recycled into the dried polymer gel before step ii) and iv) storing together with the dried polymer gel before step ii) in a vessel for a period of at least 5 minutes.

17. The process according to claim 16 , wherein the dried polymer particles from step ii) are ground by at least one multistage roll mill and classified by at least one tumbler screening machine.

18. A process for producing superabsorbent particles by polymerizing a monomer solution or suspension comprising
a) at least one ethylenically unsaturated monomer which bears an acid group and optionally is at least partly neutralized,
b) at least one crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a) and
e) optionally one or more water-soluble polymers to provide a polymer gel,
comprising
i) drying the polymer gel to produce a dried polymer gel,
ii) classifying the dried polymer gel from step i) to obtain at least one fraction of incompletely dried polymer particles and at least one fraction of dried polymer particles and
iii) comminuting the incompletely dried polymer particles from step ii),
which comprises recycling the comminuted polymer particles from step iii) into the dried polymer gel before step ii) or into the dried polymer particles after step ii) and iv) storing them together in a vessel for a period of at least 5 minutes, wherein the incompletely dried polymer particles are comminuted in step iii) by a mill with sharp beaters or blades and a screen as grinding space boundary.

19. A process for producing superabsorbent particles by polymerizing a monomer solution or suspension comprising
a) at least one ethylenically unsaturated monomer which bears an acid group and optionally is at least partly neutralized,
b) at least one crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a) and
e) optionally one or more water-soluble polymers to provide a polymer gel,
comprising
i) drying the polymer gel to produce a dried polymer gel,
ii) classifying the dried polymer gel from step i) to obtain at least one fraction of incompletely dried polymer particles and at least one fraction of dried polymer particles and
iii comminuting the incompletely dried polymer particles from step ii),
which comprises recycling the comminuted polymer particles from step iii) into the dried polymer gel before step ii) or into the dried polymer particles after step ii) and iv) storing them together in a vessel for a period of at least 5 minutes, wherein the polymer particles have a temperature in the range from 60 to 100° C. during the storage in the vessel.

Assignees

• Basf Se

Inventors

• Pfeiffer Thomas
• Weismantel Matthias
• Schröder Jürgen
• Possemiers Karl
• Krueger Marco
• Funk Ruediger

Classifications

• C08J2333/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• C08J2300/14

  Water soluble or water swellable polymers, e.g. aqueous gels · CPC title

• C08J3/245

  Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking · CPC title

• C08J3/12

  Powdering or granulating · CPC title

• C08F6/008 Primary

  Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes · CPC title