Swellable fertilizer granules containing elemental sulfur with increased oxidation rates

Patent metadata

Field	Value
Publication number	US-12084396-B2
Application number	US-202217843828-A
Country	US
Kind code	B2
Filing date	Jun 17, 2022
Priority date	May 23, 2017
Publication date	Sep 10, 2024
Grant date	Sep 10, 2024

Abstract

Fertilizer granules containing elemental sulfur and a hydrogel which expands or swells in the soil to more readily disperse the elemental sulfur surface throughout the soil, which increases the elemental sulfur surface area available for oxidation, and ultimately uptake of sulfur by the plant. The elemental sulfur and hydrogel can be added to a fertilizer composition as either an exterior coating or co-granulated with the base fertilizer composition.

First claim

What is claimed is:

1. A fertilizer product containing swellable sulfur-containing granules, each granule comprising:
a base fertilizer composition;
a source of elemental sulfur in an amount from about 0.1 to about 20 weight percent of the granule; and
a hydrogel,
wherein the source of elemental sulfur and the hydrogel are co-granulated with the base fertilizer composition, and wherein the granules are configured to expand upon introduction to a soil environment to increase a surface area of the elemental sulfur exposed to the soil environment.

2. The product of claim 1 , wherein the hydrogel is present in an amount of from about 0.1 weight percent to about 20 weight percent of the granule.

3. The product of claim 2 , wherein the hydrogel is present in an amount of from about 1 weight percent to about 10 weight percent of the granule.

4. The product of claim 3 , wherein the hydrogel is present in an amount of about 5 weight percent of the granule.

5. The product of claim 1 , wherein the elemental sulfur is present in an amount of from about 1 weight percent to about 10 weight percent of the granule.

6. The product of claim 5 , wherein the elemental sulfur is present in an amount of about 5 weight percent of the granule.

7. The product of claim 1 , wherein the base fertilizer composition is selected from the group consisting of MAP, DAP, triple super phosphate, urea, MOP, and combinations thereof.

8. The product of claim 7 , wherein the base fertilizer composition comprises MAP.

9. The product of claim 1 , wherein a rate of oxidation of the elemental sulfur of the granule is greater than a rate of oxidation of elemental sulfur contained with a granule without hydrogel.

10. The product of claim 1 , wherein the hydrogel is selected from the group consisting of bentonite or other water-absorbent clays, psyllium husk, corn starch, carrageenan gum, rice starch, sodium polyacrylate, glucose, calcium alginate, inulin, chitosan, carboxymethycellulose, fumed silica, guar gum, Xanthan gum, bean gum, gum arabic, and combinations thereof.

11. The product of claim 1 , wherein the base fertilizer composition comprises a primary nutrient, and nutrients selected from the group consisting of boron (B), zinc (Zn), manganese (Mn), molybdenum (Mo), nickel (Ni), copper (Cu), iron (Fe), chlorine (Cl), sulfur in its oxidized sulfate form (SO 4 ), magnesium (Mg), calcium (Ca), and combinations thereof.

Assignees

• Mosaic Co

Inventors

• Mclaughlin Michael
• Degryse Jozefien
• Baird Roslyn
• da Silva Rodrigo Coqui

Classifications

• C05B19/00

  Granulation or pelletisation of phosphatic fertilisers, other than slag (granulating apparatus B01J2/00; granulating slag C04B) · CPC title

• C05B7/00

  Fertilisers based essentially on alkali or ammonium orthophosphates (C05B11/00 takes precedence) · CPC title

• C05G3/40 Primary

  for affecting fertiliser dosage or release rate; for affecting solubility · CPC title

• C05B1/00

  Superphosphates, i.e. fertilisers produced by reacting rock or bone phosphates with sulfuric or phosphoric acid in such amounts and concentrations as to yield solid products directly · CPC title

• C05D9/02

  containing trace elements · CPC title