FCC catalyst prepared by a process involving more than one silica material

Patent metadata

Field	Value
Publication number	US-12083501-B2
Application number	US-202217821827-A
Country	US
Kind code	B2
Filing date	Aug 24, 2022
Priority date	Jan 12, 2018
Publication date	Sep 10, 2024
Grant date	Sep 10, 2024

Abstract

Process for the preparation of a catalyst and a catalyst comprising more than one silica is provided herein. Thus, in one embodiment, the invention provides a particulate FCC catalyst comprising about 5 to about 60 wt % one or more zeolites, about 10 to about 45 wt % quasicrystalline boehmite (QCB), about 0 to about 35 wt % microcrystalline boehmite (MCB), greater than about 0 to about 15 wt % silica from sodium stabilized colloidal silica, greater than about 0 to about 30 wt % silica from ammonia stabilized or lower sodium colloidal silica, and the balance clay and the process for making the same. This process results in attrition resistant catalysts with good performance.

First claim

The invention claimed is:

1. An FCC catalyst composition comprising about 5 to about 60 wt % one or more zeolites, about 10 to about 45 wt % quasicrystalline boehmite, about 0 to about 35 wt % microcrystalline boehmite, greater than 0 wt % to about 15 wt % silica from sodium stabilized colloidal silica, greater than 0 wt % to about 30 wt % silica from ammonia stabilized or lower sodium colloidal silica, and the balance clay.

2. The FCC Catalyst of claim 1 with greater than 0.5 wt % to about 10 wt % silica from sodium stabilized colloidal silica.

3. The FCC Catalyst of claim 2 with greater than 1 wt % to about 8 wt % silica from sodium stabilized colloidal silica.

4. The FCC Catalyst of claim 1 with greater than 1 wt % to about 25 wt % silica from ammonia stabilized or lower sodium colloidal silica.

5. The FCC Catalyst of claim 4 with greater than 5 wt % to about 20 wt % silica from ammonia stabilized or lower sodium colloidal silica.

6. A process for producing more liquid components from a hydrocarbon feedstock, said process comprising the steps of:
a. providing an FCC catalyst composition of claim 1 ;
contacting the FCC catalyst composition of claim 1 with the hydrocarbon feedstock, at one or more temperatures in the range of about 400 to about 650° C., with a dwell time in the range of about 0.5 to about 12 seconds; such that propylene is formed with a conversion efficiency in the range of about 4 to about 20 wt %, based upon the weight of the hydrocarbon feedstock.

7. An FCC catalyst made from process comprising:
a. Adding clay, boehmite, and a first sodium stabilized colloidal silica to form a slurry;
b. Digesting the slurry with a monoprotic acid to a pH of less than 4;
c. Adding one or more zeolites to the slurry;
d. Adding a second silica that is either an ammonia stabilized or sodium stabilized colloidal silica, wherein the sodium content is less than the first sodium stabilized colloidal silica, at any time during or after steps (a)— (c) but before step (e);
e. Mixing the slurry and then destabilizing the slurry by raising the pH to above 4.0;
f. Shaping and collecting the resulting FCC Catalyst
wherein the catalyst comprises about 5 to about 60 wt % one or more zeolites, about 10 to about 45 wt % quasicrystalline boehmite, about 0 to about 35 wt % microcrystalline boehmite, greater than 0 to about 15 wt % of the first silica, greater than 0 to about 30 wt % of the second silica, and the balance clay.

8. The FCC catalyst of claim 7 further comprising adding greater than 0.5 wt % to about 10 wt % of the first sodium stabilized colloidal silica.

9. The FCC catalyst of claim 7 further comprising adding greater than 1 wt % to about 25 wt % of the second silica.

10. The FCC catalyst of claim 7 further comprising adding greater than 5 wt % to about 20 wt % of the second silica.

Assignees

• Albemarle Corp
• Ketjen Llc

Inventors

• Sabahi Amir
• Loebl Andrew
• Gavalda Sandra
• Francis Julie
• Iyyamperumal Eswaramoorthi
• Li Min
• Marcinkova Andrea

Classifications

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• C10G2300/70

  Catalyst aspects · CPC title

• C10G11/18

  according to the "fluidised-bed" technique · CPC title

• C10G11/05

  Crystalline alumino-silicates, e.g. molecular sieves · CPC title

• B01J37/04

  Mixing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title