Process for producing superabsorbents

US12083496B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-12083496-B2
Application numberUS-201917046033-A
CountryUS
Kind codeB2
Filing dateApr 9, 2019
Priority dateApr 20, 2018
Publication dateSep 10, 2024
Grant dateSep 10, 2024

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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  6. CPC / IPC classifications

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  7. Citations and related patents

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Abstract

Official abstract text for this publication.

The invention relates to a process for producing long-term color stable superabsorbent polymer particles, comprising polymerization of a monomer solution, wherein the monomer solution comprises at least 0.01% by weight of 1-hydroxyethane-1,1-diphosphonic acid or a salt thereof and at least 0.01% by weight of 2-hydroxy-2-sulfonatoacetic acid or a salt thereof.

First claim

Opening claim text (preview).

The invention claimed is: 1. A process for producing long-term color stable superabsorbent polymer particles, comprising polymerizing a monomer solution comprising a) partly neutralized acrylic acid, b) at least one crosslinker, c) at least one initiator, d) 0.1 to 0.6% by weight of 1-hydroxyethane-1,1-diphosphonic acid or a salt thereof based on the acrylic acid prior to neutralization, and e) 0.05 to 0.5% by weight of 2-hydroxy-2-sulfonatoacetic acid or a salt thereof based on the acrylic acid prior to neutralization, drying the resulting polymer gel, optionally grinding and classifying the resulting dried polymer gel, and optionally thermally post-crosslinking and cooling the resulting polymer particles. 2. The process according to claim 1 , wherein a degree of neutralization of the partly neutralized acrylic acid is from 50 to 85 mol %. 3. The process according to claim 1 , wherein the superabsorbent polymer particles are thermally post-crosslinked. 4. The process according to claim 1 wherein the resulting polymer particles have a Hunter 60 value (HC60) after 28 days of aging at 60° C. and a relative humidity of 86% of at least 47. 5. The process according to claim 1 wherein the resulting polymer particles have a Hunter 60 value (HC60) after 28 days of aging at 60° C. and a relative humidity of 86% of at least 55.

Assignees

Inventors

Classifications

  • leading to a crosslinking, either explicitly or inherently · CPC title

  • as molar percentages · CPC title

  • Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

  • Chemical treatments not covered by groups B01J20/3007 - B01J20/3078 · CPC title

  • Milling, crushing or grinding · CPC title

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What does patent US12083496B2 cover?
The invention relates to a process for producing long-term color stable superabsorbent polymer particles, comprising polymerization of a monomer solution, wherein the monomer solution comprises at least 0.01% by weight of 1-hydroxyethane-1,1-diphosphonic acid or a salt thereof and at least 0.01% by weight of 2-hydroxy-2-sulfonatoacetic acid or a salt thereof.
Who is the assignee on this patent?
Basf Se
What technology area does this patent fall under?
Primary CPC classification B01J20/267. Mapped technology areas include Operations & Transport.
When was this patent published?
Publication date Tue Sep 10 2024 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 2 related publications on this page (citations in our corpus or others sharing the same primary CPC).