Selective adsorption of halocarbon impurities containing cl, br and i in fluorocarbons or hydrofluorocarbons using adsorbent supported metal oxide

Patent metadata

Field	Value
Publication number	US-12083493-B2
Application number	US-202117192421-A
Country	US
Kind code	B2
Filing date	Mar 4, 2021
Priority date	Mar 4, 2021
Publication date	Sep 10, 2024
Grant date	Sep 10, 2024

Abstract

Methods for purification of a fluorocarbon or hydrofluorocarbon containing at least one undesired halocarbon impurities comprise flowing the fluorocarbon or hydrofluorocarbon through at least one adsorbent beds to selectively adsorb the at least one undesired halocarbon impurities through physical adsorption and/or chemical adsorption, wherein the at least one adsorbent beds contain a metal oxide supported on an adsorbent in an inert atmosphere.

First claim

We claim:

1. A process for purification of a fluorocarbon or hydrofluorocarbon containing at least one undesired halocarbon impurities, comprising:
flowing the fluorocarbon or hydrofluorocarbon through at least one adsorbent beds to selectively adsorb the at least one undesired halocarbon impurities through physical adsorption and/or chemical adsorption, wherein the at least one adsorbent beds contain a metal oxide MgO supported on an adsorbent in an inert atmosphere; and
regenerating the at least one adsorbent beds after the selective adsorption at a temperature ranging from 500° C. to 1000° C. with continuously flowing a purge gas through the at least one adsorbent beds, wherein the purge gas is either pure H 2 or H 2 in balance an inert gas selected from He, N 2 , Ar, Xe or Kr.

2. The process of claim 1 , further comprising:
distilling an outlet stream of the at least one adsorption beds to obtain a purified fluorocarbon or hydrofluorocarbon.

3. The process of claim 1 , wherein the at least one undesired halocarbon impurities are Cl-containing, Br-containing, I-containing, or combinations thereof halocarbons.

4. The process of claim 3 , wherein the at least one undesired halocarbon impurities are chlorofluorocarbons (CFC) and/or hydrochlorofluorocarbons (HCFC).

5. The process of claim 1 , wherein the adsorbent is silica, alumina or molecular sieves.

6. The process of claim 1 , wherein a flow rate of the fluorocarbon or hydrofluorocarbon into the at least one adsorbent beds in vapor phase ranges from 0.5 standard liter per minute (SLM) to 500 standard liter per minute (SLM).

7. The process of claim 1 , wherein a temperature of the at least one adsorbent beds ranges from −50° C. to 150° C.

8. The process of claim 2 , wherein a concentration of impurities in the purified fluorocarbon or hydrofluorocarbon is less than 1000 ppm.

9. A process for purification of a fluorocarbon or hydrofluorocarbon containing at least one undesired halocarbon impurities, comprising:
flowing the fluorocarbon or hydrofluorocarbon through at least one adsorbent beds to selectively adsorb the at least one undesired halocarbon impurities through physical adsorption and/or chemical adsorption, wherein the at least one adsorbent beds contain a metal oxide MgO supported on an adsorbent in an inert atmosphere;
regenerating the at least one adsorbent beds after the selective adsorption at a temperature ranging from 500° C. to 1000° C. with a purge gas containing either pure H 2 or H 2 in balance an inert gas selected from He, N 2 , Ar, Xe or Kr; and
distilling an outlet stream of the at least one adsorption beds to obtain a purified fluorocarbon or hydrofluorocarbon.

10. The process of claim 9 , wherein a concentration of impurities in the purified fluorocarbon or hydrofluorocarbon is less than 1000 ppm.

11. The process of claim 9 , wherein the at least one undesired halocarbon impurities are Cl-containing, Br-containing, I-containing, or combinations thereof halocarbons.

Assignees

• Air Liquide American

Inventors

• Doraiswamy Anup
• Stafford Nathan

Classifications

• B01J20/3458

  in the gas phase · CPC title

• B01D2259/40086

  by using a purge gas (B01D2259/4009 takes precedence) · CPC title

• B01D2257/2066

  Fluorine · CPC title

• B01D2257/2064

  Chlorine · CPC title

• B01D2256/26

  Halogens or halogen compounds · CPC title