Partially cured coated sheet

Patent metadata

Field	Value
Publication number	US-12077690-B2
Application number	US-202117923533-A
Country	US
Kind code	B2
Filing date	May 6, 2021
Priority date	May 8, 2020
Publication date	Sep 3, 2024
Grant date	Sep 3, 2024

Abstract

A sheet includes a support layer and a coating layer on a side of the support layer. The coating layer is partially cured. The coating layer has carbon-carbon double bonds. The relative amount of carbon-carbon double bonds is higher at the surface of the coating layer than at the contact surface of the coating layer with the support layer. Methods are disclosed to manufacture such sheets; and to produce a decorative panel using such sheets.

First claim

The invention claimed is:

1. A sheet, comprising:
a support layer,
a coating layer on a side of the support layer,
wherein the coating layer is partially cured,
wherein the coating layer comprises carbon-carbon double bonds,
wherein the relative amount of carbon-carbon double bonds is higher at the surface of the coating layer than at the contact surface of the coating layer with the support layer;
optionally wherein the coating layer comprises a hindered amine light stabilizer and/or a UV-absorber;
wherein the coating layer comprises one or more than one type of thermo initiator.

2. The sheet as in claim 1 , wherein the support layer comprises a decorative print.

3. The sheet as in claim 1 , wherein the double bond conversion rate at the surface is between 35% and 80%.

4. The sheet as in claim 1 , wherein the support layer comprises a printed sheet of paper,
wherein the sheet of paper is a melamine impregnated paper, or wherein the sheet of paper is an acrylate impregnated paper.

5. The sheet as in claim 4 , wherein the printed sheet of paper comprises at one or at both sides a glue layer or an adhesion promoting layer.

6. The sheet as in claim 1 , wherein the support layer comprises a plastic film,
wherein the plastic film is a printed film or wherein the plastic film is a clear film.

7. The sheet as in claim 1 , wherein the coating layer of the sheet is not tacky.

8. The sheet as in claim 1 , wherein at least part of the thermo-initiators have a one hour half-life temperature higher than 90° C.

9. The sheet as in claim 1 , wherein the thermo-initiators comprise a first group of thermo-initiators and a second group of thermo-initiators,
wherein the first group of thermo-initiators provides between 10% by weight and 50% by weight of the combination of the first group of thermo-initiators and the second group of thermo-initiators,
wherein the second group of thermo-initiators provides between 50% by weight and 90% by weight of the combination of the first group of thermo-initiators and the second group of thermo-initiators;
wherein the thermo-initiators of the first group of thermo-initiators have a one hour half-life temperature which is at least 10° C. lower than the thermo-initiators of the second group of thermo-initiators.

10. The sheet as in claim 1 , wherein the relative amount of carbon-carbon double bonds is more than 15% higher at the surface of the coating layer than at the contact of the coating layer with the support layer.

11. The sheet as in claim 1 , wherein a continuous gradient is present in the relative amount of carbon-carbon bonds throughout the coating layer from the surface of the coating layer to the contact of the coating layer with the support layer.

12. The sheet as in claim 1 , wherein the coating layer comprises one or more than one of acrylate, methacrylate or unsaturated polyester.

13. The sheet as in claim 1 , wherein the coating layer comprises aluminum oxide particles modified via silanization, wherein acrylic or methacrylic functional groups are provided on the aluminum oxide particles by means of the silanization.

14. The sheet as in claim 1 , wherein the coating layer comprises at least two layers of which a top layer providing the surface of the coating layer,
wherein the top layer after full curing of the coating layer provides a harder coating than the layer of the coating layer below the top layer.

15. A method to manufacture the sheet of claim 1 , wherein the method comprises the steps of:
providing a support layer,
applying a coating on the support layer, wherein the coating comprises:
oligomers and unsaturated polyester,
one or more than one photo-initiator in a combined amount of photo-initiator between 0.05 and 3 percent by weight of the coating,
one or more than one thermo-initiator in an amount of 0.1-3 percent by weight;
optionally a plasticizer;
optionally acrylate monomer;
optionally a hindered amine light stabilizer and/or a UV-absorber;
optionally particles that provide scratch resistance and/or taber resistance;
optionally a diluent;

partially curing the coating by means of UV-radiation, thereby obtaining the sheet of claim 1 .

16. The method as in claim 15 , wherein in partially curing the coating, the conversion rate of the double carbon-carbon bonds is lower at the surface of the coating layer than at the contact of the coating layer with the support layer.

17. A sheet, comprising:
a support layer,
a coating layer on a side of the support layer,
wherein the coating layer is partially cured,
wherein the coating layer comprises carbon-carbon double bonds,
wherein the relative amount of carbon-carbon double bonds is higher at the surface of the coating layer than at the contact surface of the coating layer with the support layer;
optionally wherein the coating layer comprises a hindered amine light stabilizer and/or a UV-absorber;
wherein the coating layer comprises at least two layers of which a top layer providing the surface of the coating layer,
wherein the top layer after full curing of the coating layer provides a harder coating than the layer of the coating layer below the top layer;
wherein the top layer comprises particles selected to provide scratch resistance to the coating layer,
wherein the second layer of the coating layer also comprises particles selected to provide scratch resistance to the coating layer,
wherein the second layer of the coating layer contacts the top layer;
wherein said particles in the second layer differ from the particles in the top layer,
wherein said particles in the top layer are smaller than said particles in the second layer.

18. The sheet as in claim 1 , wherein the sheet comprises a topcoat provided onto the coating layer,
wherein the topcoat will after final curing provide a higher hardness than the surface of the coating layer.

Assignees

• Flooring Ind Ltd Sarl
• Unilin Bv

Inventors

• Clement Benjamin
• Ledegen Sam
• Seynaeve Marijn

Classifications

• C09J2433/006

  in the substrate · CPC title

• C09J2400/283

  in the substrate · CPC title

• C09D135/02

  Homopolymers or copolymers of esters (C09D135/06, C09D135/08 take precedence) · CPC title

• C09D133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title

• C09D4/00

  Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16} · CPC title