Use of bonding resin

Patent metadata

Field	Value
Publication number	US-12077682-B2
Application number	US-202017610856-A
Country	US
Kind code	B2
Filing date	May 13, 2020
Priority date	May 15, 2019
Publication date	Sep 3, 2024
Grant date	Sep 3, 2024

Abstract

The present invention relates to the use of a bonding resin prepared by providing an aqueous solution comprising at least one biobased product selected from tannin, starch, soy protein, glycerol, chitin, pectin, dextrose or other carbohydrates, or a mixture thereof and mixing the aqueous solution with one or more of certain crosslinkers such as ethers, and optionally one or more additives. The bonding resin is used in the manufacture of laminates, mineral wool insulation or wood products, such as engineered wood products, such as plywood, oriented strandboard (OSB), laminated veneer lumber (LVL), medium density fiberboards (MDF), high density fiberboards (HDF) or particle boards. Preferably, the bonding resin does not comprise lignin.

First claim

The invention claimed is:

1. A method of preparing a bonding resin by:
providing an aqueous solution comprising at least one biobased product selected from a group consisting of tannin, starch, soy protein, glycerol, chitin, pectin, dextrose or other carbohydrates, and mixtures thereof;
mixing the aqueous solution with one or more of glycerol diglycidyl ether, diglycerol polyglycidyl ether, polyglycerol diglycidyl ether, polyglycerol polyglycidyl ether, glycerol triglycidyl ether, sorbitol polyglycidyl ether, alkoxylated glycerol polyglycidyl ether, trimethylolpropane triglycidyl ether, trimethylolpropane diglycidyl ether, polyoxypropylene glycol diglycidylether, polyoxypropylene glycol triglycidyl ether, diglycidylether of cyclohexane dimethanol, resorcinol diglycidyl ether, isosorbide diglycidyl ether, pentaerythritol tetraglycidyl ether, ethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether having 2-9 ethylene glycol units, propylene glycol diglycidyl ether having 1-5 propylene glycol units, and/or diglycidyl ether of terminal diol having a linear carbon chain of 3-6 carbon atoms, or a crosslinker selected from diglycidyl-, triglycidyl- or polyglycidyl-ether of a carbohydrate, diglycidyl-, triglycidyl- or polyglycidyl-ester of a carbohydrate, diglycidyl-ether or diglycidyl ester of salicylic acid, vanillic acid, or 4-hydroxybenzoic acid, an epoxidized or glycidyl substituted plant-based phenolic compound or epoxidized plant-based oil, tris(4-hydroxyphenyl) methane triglycidyl ether, N,N-bis(2,3-epoxypropyl)aniline, p-(2,3-epoxypropoxy-N,N-bis(2,3-epoxypropyl)aniline, diglycidyl ether of bis-hydroxymethylfuran, and a crosslinker having functional groups selected from diglycidyl amide, triglycidyl amide, polyglycidyl amide, diglycidyl ester, triglycidyl ester, polyglycidyl ester, diglycidyl azide, triglycidyl azide, polyglycidyl azide, diglycidyl methacrylate, triglycidyl methacrylate and polyglycidyl methacrylate.

2. The method of claim 1 , wherein
the aqueous solution is mixed with one or more of glycerol diglycidyl ether, diglycerol polyglycidyl ether, polyglycerol diglycidyl ether, polyglycerol polyglycidyl ether, glycerol triglycidyl ether, sorbitol polyglycidyl ether, alkoxylated glycerol polyglycidyl ether, trimethylolpropane triglycidyl ether, trimethylolpropane diglycidyl ether, polyoxypropylene glycol diglycidylether, polyoxypropylene glycol triglycidyl ether, diglycidylether of cyclohexane dimethanol, resorcinol diglycidyl ether, isosorbide diglycidyl ether, pentaerythritol tetraglycidyl ether, ethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether having 2-9 ethylene glycol units, propylene glycol diglycidyl ether having 1-5 propylene glycol units, and/or diglycidyl ether of terminal diol having a linear carbon chain of 3-6 carbon atoms.

3. The method according to claim 2 , wherein the aqueous solution is mixed with polyglycerol polyglycidyl ether.

4. The method according to claim 1 , wherein the aqueous solution comprising at least one biobased product is an alkali solution.

5. The method according to claim 1 , wherein a weight ratio between the at least one biobased product, calculated on a basis of dry biobased product, and a total amount of ether is from 1:10 to 10:1.

6. The method according to claim 1 , wherein the aqueous solution is further mixed with urea, or a solvent, or both.

7. The method according to claim 6 , wherein the solvent comprises glycerol, ethylene glycol, polyethylene glycol, propylene glycol, polypropylene glycol, sorbitol, any terminal diol having a linear carbon chain of 3-6 carbon atoms, or mixtures thereof.

8. The method according to claim 1 , wherein the biobased product is selected from a group consisting of tannin, starch, soy protein, glycerol, chitin, pectin, dextrose, and mixtures thereof.

9. The method according to claim 1 , further comprising:
providing the bonding resin to a surface in preparation of a laminate, mineral wool insulation, wood product, oriented strandboard (OSB), laminated veneer lumber (LVL), medium density fiberboards (MDF), high density fiberboards (HDF), particle board, parquet flooring, curved plywood, veneered particleboards, or veneered MDF, and
curing the bonding resin to form an adhesive by exposing the surface to pressure.

10. The method according to claim 1 , wherein the aqueous solution is further mixed with one or more additives.

11. The method of claim 9 , wherein the bonding resin is cured to form an adhesive by exposing the surface to pressure and heating.

12. A method for manufacturing a wood product comprising:
preparing a bonding resin by
providing an aqueous solution comprising at least one biobased product selected from a group consisting of tannin, starch, soy protein, glycerol, chitin, pectin, dextrose or other carbohydrates, and mixtures thereof, and
mixing the aqueous solution with one or more of glycerol diglycidyl ether, polyglycerol diglycidyl ether, polyglycerol polyglycidyl ether, glycerol triglycidyl ether, sorbitol polyglycidyl ether, alkoxylated glycerol polyglycidyl ether, trimethylolpropane triglycidyl ether, trimethylolpropane diglycidyl ether, polyoxypropylene glycol diglycidylether, polyoxypropylene glycol triglycidyl ether, diglycidylether of cyclohexane dimethanol, resorcinol diglycidyl ether, isosorbide diglycidyl ether, pentaerythritol tetraglycidyl ether, ethylene glycol diglycidyl ether, polyethylene glycol diglycidyl ether having 2-9 ethylene glycol units, propylene glycol diglycidyl ether having 1-5 propylene glycol units, and/or diglycidyl ether of terminal diol having a linear carbon chain of 3-6 carbon atoms, or a crosslinker selected from diglycidyl-, triglycidyl- or polyglycidyl-ether of a carbohydrate, diglycidyl-, triglycidyl- or polyglycidyl-ester of a carbohydrate, diglycidyl-ether or diglycidyl ester of salicylic acid, vanillic acid, or 4-hydroxybenzoic acid, an epoxidized or glycidyl substituted plant-based phenolic compound or epoxidized plant-based oil, tris(4-hydroxyphenyl) methane triglycidyl ether, N,N-bis(2,3-epoxypropyl)aniline, p-(2,3-epoxypropoxy-N,N-bis(2,3-epoxypropyl)aniline, diglycidyl ether of bis-hydroxymethylfuran, and a crosslinker having functional groups selected from diglycidyl amide, triglycidyl amide, polyglycidyl amide, diglycidyl ester, triglycidyl ester, polyglycidyl ester, diglycidyl azide, triglycidyl azide, polyglycidyl azide, diglycidyl methacrylate, triglycidyl methacrylate and polyglycidyl methacrylate;

providing the bonding resin to a surface in preparation of the wood product, and curing the bonding resin to form an adhesive by exposing the surface to pressure.

13. The method according to claim 12 , wherein the aqueous solution is further mixed with one or more additives.

14. The method according to claim 12 , wherein the bonding resin is cured to form an adhesive by exposing the surface to pressure and heating.

Assignees

• Stora Enso Oyj

Inventors

• Nasli Bakir Ben
• Zafar Ashar
• Ekström Jesper

Classifications

• C09J189/00

  Adhesives based on proteins; Adhesives based on derivatives thereof · CPC title

• C09J163/00 Primary

  Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins · CPC title

• C09J105/08

  Chitin; Chondroitin sulfate; Hyaluronic acid; Derivatives thereof · CPC title

• C09J105/06 Primary

  Pectin; Derivatives thereof · CPC title

• B32B21/042

  of wood (B32B21/13 takes precedence) · CPC title