System and method for preparing epoxy chloropropane

Patent metadata

Field	Value
Publication number	US-12077516-B2
Application number	US-202118269109-A
Country	US
Kind code	B2
Filing date	Dec 24, 2021
Priority date	Dec 25, 2020
Publication date	Sep 3, 2024
Grant date	Sep 3, 2024

Abstract

A system and method for preparing epoxy chloropropane is provided in that by coupling three stages of high gravity reactors, the product epoxy chloropropane and water vapor are distilled from a reaction system in form of an azeotrope by adopting a water vapor steam stripping method. Further, by combining the azeotrope with the multiples stages of high gravity reactors, the gas phase mass transfer and the liquid phase mass transfer of the azeotrope are improved aiming at the features of the azeotrope in the reaction system, thus making the overall conversion rate higher. In addition, by combining steam stripping and high gravity, dichloropropanol and alkali solution are rapidly mixed for mass transfer, and the product epoxy chloropropane is rapidly distilled from the reaction system in the form of the azeotrope, such that the reaction proceeds continuously towards the direction of producing epoxy chloropropane, thus significantly improving the conversion rate.

First claim

The invention claimed is:

1. A system for preparing epoxy chloropropane, comprising:
a first high gravity reactor, a liquid inlet of the first high gravity reactor being communicated with a liquid inlet pipeline of raw materials dichloropropanol and alkali solution;
a second high gravity reactor, a gas inlet of the second high gravity reactor being communicated with a water vapor pipeline, a gas outlet of the second high gravity reactor being communicated with a gas inlet of the first high gravity reactor;
a liquid circulation tank, an inlet of the liquid circulation tank being communicated with a liquid outlet of the first high gravity reactor, an outlet of the liquid circulation tank being respectively communicated with the liquid inlet of the first high gravity reactor and a liquid inlet of the second high gravity reactor; and
a third high gravity reactor, a gas inlet of the third high gravity being communicated with a gas outlet of the first high gravity reactor, a liquid outlet of the third high gravity being communicated with the liquid inlets of the first high gravity reactor and the second high gravity reactor, a gas outlet of the third high gravity reactor being communicated with a recovery device, a liquid inlet of the third high gravity reactor being communicated with a liquid outlet of the recovery device, wherein
a liquid outlet of the second high gravity reactor is communicated with an inlet of a chloride salt solution storage tank.

2. The system according to claim 1 , wherein the system further comprises:
a first valve located on a pipeline between the outlet of the liquid circulation tank and the liquid inlet of the first high gravity reactor; and
a second valve located on a pipeline between the outlet of the liquid circulation tank and the liquid inlet of the second high gravity reactor.

3. The system according to claim 2 , wherein the system further comprises:
a valve controller coupled with at least one of the first valve or the second valve and configured to control the opening of the at least one of the first valve or the second valve.

4. The system according to claim 3 , wherein the system further comprises:
a detector configured to detect flow rate at the liquid inlet pipeline of raw materials dichloropropanol and alkali solution; and
a processor configured to determine the opening of the at least one of the first valve or the second valve according to the flow rate.

5. The system according to claim 1 , wherein the recovery device comprises:
a first condenser and a second condenser in series, a gas inlet of the first condenser being communicated with a gas outlet of the third high gravity reactor; and
a two-phase separator communicated with liquid outlets of the first condenser and the second condenser, a liquid outlet of the two-phase separator being communicated with the liquid inlet of the third high gravity reactor.

6. The system according to claim 1 , wherein the second high gravity reactor and the third high gravity reactor are rotating packed beds, and the first high gravity reactor is a rotor-stator reactor.

7. The system according to claim 5 , wherein the two-phase separator comprises a separation chamber and a baffle provided in the separation chamber, the baffle divides the separation chamber into two communicated sub-chambers, one sub-chamber is communicated with the third high gravity reactor, and the other sub-chamber is communicated with a storage tank.

8. The system according to claim 7 , wherein the baffle is movable.

9. The system according to claim 1 , wherein the second high gravity reactor and the third high gravity reactor are rotating packed beds, and an oleophobic packing is provided in the rotating packed beds.

10. A method for preparing epoxy chloropropane, comprising:
preparing epoxy chloropropane by using the system according to claim 1 .

Assignees

• Quzhou Juhua Polyamide Fibre Llc
• Univ Beijing Chem Tech
• Juhua group co ltd

Inventors

• Zhang Liangliang
• Zhou Liyang
• Chu Guangwen
• Xia bibo
• Chen Jianfeng
• Jiang Yutu
• Tong Jihong
• Sun Baochang
• Mao Wei
• Zheng Yanchun

Classifications

• C07D301/26

  Y being hydrogen · CPC title

• C07D303/08 Primary

  with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals · CPC title

• C07D301/32 Primary

  Separation; Purification · CPC title