Method for preparing reduced graphene oxide-magnesium nanocrystal composite

Patent metadata

Field	Value
Publication number	US-12077439-B2
Application number	US-202117505760-A
Country	US
Kind code	B2
Filing date	Oct 20, 2021
Priority date	Nov 13, 2020
Publication date	Sep 3, 2024
Grant date	Sep 3, 2024

Abstract

Disclosed is a method for preparing a reduced graphene oxide-magnesium nanocrystal composite. The method includes contacting graphene oxide with a first reducing agent to prepare a reduced graphene oxide, and co-reducing the reduced graphene oxide and a precursor of magnesium in the presence of a second reducing agent to prepare a reduced graphene oxide-magnesium nanocrystal composite, wherein by adjusting the amount of the first reducing agent in contact with the graphene oxide, the size of the magnesium nanocrystals in the composite may be controlled.

First claim

What is claimed is:

1. A method for preparing a reduced graphene oxide-magnesium nanocrystal composite, comprising:
contacting graphene oxide with a first reducing agent to prepare a reduced graphene oxide; and
co-reducing the reduced graphene oxide and a precursor of magnesium in the presence of a second reducing agent to prepare a reduced graphene oxide-magnesium nanocrystal composite,
wherein by adjusting the amount of the first reducing agent in contact with the graphene oxide, the size of the magnesium nanocrystals in the composite is controlled.

2. The method of claim 1 , wherein the magnesium nanocrystals are encapsulated in a sheet of reduced graphene oxide in the reduced graphene oxide-magnesium nanocrystal composites.

3. The method of claim 1 , wherein the first reducing agent is NaBH 4 , ascorbic acid, hydrazine hydrate, dimethyl hydrazine, hydroiodic acid, or a combination thereof.

4. The method of claim 1 , wherein the second reducing agent is lithium naphthalenide, sodium naphthalenide, potassium naphthalenide, or a combination thereof.

5. The method of claim 1 , wherein a weight ratio of the graphene oxide and the first reducing agent is about 1:1 to about 1:20.

6. The method of claim 1 , wherein the precursor of magnesium is bis(cyclopentadienyl) magnesium, magnesium chloride, di-n-butyl magnesium, or a combination thereof.

7. The method of claim 1 , wherein a size of the magnesium nanocrystals is less than or equal to about 500 nm.

8. The method of claim 1 , wherein a size of the magnesium nanocrystals is greater than or equal to about 1 nm and less than or equal to about 200 nm.

9. The method of claim 1 , wherein a size of the magnesium nanocrystals is greater than or equal to about 1 nm and less than or equal to about 100 nm.

10. The method of claim 1 , wherein hydrogen absorption activation energy of the magnesium nanocrystals is more than or equal to 65 KJ·mol −1 and less than or equal to about 120 KJ·mol −1 .

11. The method of claim 1 , wherein a hydrogen desorption induction period of the magnesium nanocrystals is less than or equal to about 0.5 hours.

12. A reduced graphene oxide-magnesium nanocrystal composite prepared through the method of claim 1 .

Assignees

• Korea Advanced Inst Sci & Tech

Inventors

• Cho Eun Seon
• Han Dong Ju

Classifications

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• C01P2006/90

  Other properties not specified above · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title