Method for washing ion exchange resin and method for preparing bisphenol A

Patent metadata

Field	Value
Publication number	US-12076717-B2
Application number	US-201916634787-A
Country	US
Kind code	B2
Filing date	Jan 22, 2019
Priority date	Feb 9, 2018
Publication date	Sep 3, 2024
Grant date	Sep 3, 2024

Abstract

A method of washing an ion exchange resin, including washing an ion exchange resin with deionized water (DI water) one or more times to prepare a washed ion exchange resin; and storing the washed ion exchange resin in dionized water. A method for producing bisphenol A using the method of washing an ion exchange resin. The resulting bisphenol A has improved purity, thermal stability, color, and the like.

First claim

The invention claimed is:

1. A method of washing an ion exchange resin, the method comprising:
washing the ion exchange resin with deionized water (DI water) one or more times until a pH of the deionized water discharged after the washing is 6.2 to 7.0 to prepare a washed ion exchange resin; and
storing the washed ion exchange resin in the deionized water, wherein a temperature of the storing of the washed ion exchange resin is 50° C. to 60° C. and a time of the storing of the washed ion exchange resin is 6 hours to 20 hours, and an amount of the deionized water to which the washed ion exchange resin is added is at a weight ratio of 1.6 times to 1.8 times based on a weight of the ion exchange resin,
wherein the washing of the ion exchange resin and the storing of the washed ion exchange resin are performed repeatedly while replacing the deionized water until a concentration of an acidic effluent of the deionized water discharged immediately after the storing of the washed ion exchange resin is 0.5 ppm or less, and
wherein the acidic effluent includes at least one selected from the group consisting of sulfonic acid, phenol sulfonic acid, sulfobenzoic acid, formyl benzenesulfonic acid, acetyl benzenesulfonic acid, and a sulfonic acid group-containing organic acid.

2. The method of claim 1 , wherein the ion exchange resin is a cation exchange resin.

3. A method of producing bisphenol A, the method comprising:
reacting phenol and acetone in the presence of the ion exchange resin washed with the method according to claim 1 to obtain a reaction product; and
crystallizing and solid-liquid separating the reaction product to obtain an adduct including bisphenol A.

4. The method of claim 3 , wherein the adduct has a platinum-cobalt color of 50 or less as measured by a platinum-cobalt visual comparison method.

5. The method of claim 1 , further comprising, after the storing of the washed ion exchange resin in the deionized water, storing the ion exchange resin in phenol for 1 hour or more, followed by dehydrating and drying the washed ion exchange resin.

6. The method of claim 1 , wherein a pH of deionized water discharged after the storing of the washed ion exchange resin is 4.18 to 4.29.

7. The method of claim 1 , wherein the acidic effluent includes at least one selected from the group consisting of phenol sulfonic acid, sulfobenzoic acid, formyl benzenesulfonic acid, acetyl benzenesulfonic acid, and a sulfonic acid group-containing organic acid.

8. The method of claim 1 , wherein the concentration of the acidic effluent is 0.1 ppm to 0.5 ppm.

9. The method of claim 1 , wherein the concentration of the acidic effluent is 0.1 ppm to 0.4 ppm.

10. The method of claim 1 , wherein the concentration of the acidic effluent is 0.1 ppm to 0.3 ppm.

11. The method of claim 1 , wherein the concentration of the acidic effluent is 0.4 ppm to 0.5 ppm.

12. The method of claim 1 , wherein the concentration of the acidic effluent is 0.3 ppm to 0.5 ppm.

13. The method of claim 1 , wherein the concentration of the acidic effluent is 0.3 ppm to 0.4 ppm.

Assignees

• Lg Chemical Ltd

Inventors

• Lee Sung Ho
• Lee Sang Beom
• Shin Joon Ho
• Jeong In Yong
• Kang Min Suk

Classifications

• C07C37/84

  by crystallisation · CPC title

• C07C39/16

  Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes · CPC title

• C07C37/82

  by solid-liquid treatment; by chemisorption · CPC title

• C07C37/20

  using aldehydes or ketones · CPC title

• B01J39/04

  Processes using organic exchangers · CPC title