Capture of fluorinated carbon compounds

Patent metadata

Field	Value
Publication number	US-12076705-B2
Application number	US-202017429217-A
Country	US
Kind code	B2
Filing date	Feb 7, 2020
Priority date	Feb 8, 2019
Publication date	Sep 3, 2024
Grant date	Sep 3, 2024

Abstract

The present invention describes a method of capturing a fluorinated carbon compound located within a liquid, the method comprising contacting the fluorinated carbon compound with a block copolymer having a backbone comprising a hydrophilic block and a fluoropolyether block, wherein the fluorinated carbon compound binds to and is captured by the block copolymer.

First claim

The invention claimed is:

1. A method of capturing a fluorinated carbon compound located within a liquid, the method comprising contacting the fluorinated carbon compound with a block copolymer having a backbone comprising a hydrophilic block and a fluoropolyether block such that the fluorinated carbon compound binds to and is captured by the block copolymer;
removing the fluorinated carbon compound from the liquid by separating from the liquid the block copolymer having the fluorinated carbon compound bound thereto; and
separating the fluorinated carbon compound from the block copolymer using an organic solvent and/or heat.

2. The method according to claim 1 , wherein the fluoropolyether block presents polyether functionality in the block copolymer backbone.

3. The method according to claim 1 , wherein the fluoropolyether block presents polyether functionality pendant to the block copolymer backbone.

4. The method according to claim 1 , wherein the hydrophilic block presents hydrophilic functionality in the block copolymer backbone.

5. The method according to claim 1 , wherein the hydrophilic block presents hydrophilic functionality pendant to the block copolymer backbone.

6. The method according to claim 1 , wherein the fluoropolyether block is a perfluoropolyether block.

7. The method according to claim 1 , wherein the liquid is an aqueous liquid.

8. The method according to claim 7 , wherein the aqueous liquid is waste water.

9. The method according to claim 1 , wherein the liquid is a blood product.

10. The method according to claim 1 , wherein the hydrophilic block comprises a polyoxyalkylene moiety.

11. The method according to claim 10 , wherein the polyoxyalkylene moiety comprises an oxyalkylene group of formula: —O(CR X R Y ) i , where R X and R Y are each independently selected from hydrogen and optionally substituted alkyl, and i is an integer ranging from 1 to 10.

12. The method according to claim 1 , wherein the fluoropolyether block comprises a moiety selected from —(C p F 2p O)—, —(CF(Z)O)—, —(CF(Z)C p F 2p O)—, —(C p F 2p CF(Z)O)—, —CF 2 CF(Z)O)—, or a combination thereof, where p is an integer ranging from 1 to 10, and where Z is selected from a fluoroalkyl group, a fluoroether group, a fluoropolyether group, or a fluoroalkoxy group.

13. The method according to claim 12 , wherein Z is selected from a perfluoroalkyl group, a perfluoroether group, a perfluoropolyether group, or a perfluoroalkoxy group.

14. The method according to claim 1 , wherein the fluoropolyether block comprises a moiety selected from C 3 F 7 O(CF(CF 3 )CF 2 O) n CF(CF 3 )—, C 3 F 7 O(CF 2 CF 2 CF 2 O) n CF 2 CF 2 —, and CF 3 O(C 2 F 4 O) n CF 2 —, where n has an average value of 1 to 50, for example 3 to 30, 3 to 15, or 3 to 10.

15. The method according to claim 1 , wherein the block copolymer has a number average molecular weight ranging from about 1500 to about 110,000 g/mol.

16. The method according to claim 1 , wherein the hydrophilic block has a number average molecular weight ranging from 1000 about to about 100,000 g/mol.

17. The method according to claim 1 , wherein the hydrophilic block has a number average molecular weight ranging from about 500 to about 10,000 g/mol.

18. The method according to claim 1 , wherein the block copolymer is covalently bound to a solid substrate.

19. The method according to claim 1 , wherein the block copolymer presents in the form of an aggregate of two or more block copolymer chains.

20. The method of claim 1 , wherein the block copolymer comprises a structure of Formula (I), (II) or (III):

where-in formula (I), n is an integer ranging from 1 to about 30, m is an integer ranging from 1 to about 1000, x is an integer ranging from 1 to about 100 and y is an integer ranging from 1 to about 1000; in formula (II) a is an integer ranging from 1 to about 40, b is an integer ranging from 1 to about 100 and c is an integer ranging from 1 to about 1000; in formula (III) j is an integer ranging from 1 to about 1000 and k is an integer ranging from 1 to about 100; and wherein formulas (I), (II) and (III) * represents a connection point to the block co-polymer.

21. The method according to claim 1 , wherein the liquid having the fluorinated carbon compound located therein is obtained by a process comprising contacting a liquid with solid matter comprising fluorinated carbon compound.

Assignees

• Univ Queensland

Inventors

• Whittaker Andrew
• Zhang Cheng
• Tan Xiao

Classifications

• C08F290/062

  Polyethers · CPC title

• C02F2101/363

  PCB's; PCP's · CPC title

• C02F2101/14

  Fluorine or fluorine-containing compounds · CPC title

• C02F1/583

  by removing fluoride or fluorine compounds · CPC title

• C02F1/285 Primary

  using synthetic organic sorbents · CPC title