EPR spectrometer with at least one pole piece made at least partially of a function material

Patent metadata

Field	Value
Publication number	US-12072401-B2
Application number	US-202117537935-A
Country	US
Kind code	B2
Filing date	Nov 30, 2021
Priority date	Dec 22, 2020
Publication date	Aug 27, 2024
Grant date	Aug 27, 2024

Abstract

An electron paramagnetic resonance (EPR) spectrometer includes a magnet system comprising at least one magnet and at least one pole piece for producing a magnetic field along a pole axis in a field of view in front of the at least one pole piece. A probe head comprising a microwave resonator and at least one modulation coil or rapid scan coil produces an additional, time-varying magnetic field aligned along the pole axis. The probe head is arranged in the field of view, and a respective modulation coil or rapid scan coil is arranged between the microwave resonator and a respective pole piece. For each pole piece, at least a part of said pole piece is made of a function material having an electric conductivity σ f of 10 4 S/m or less, and having a saturation magnetic flux density BS f of 0.2 T or more.

First claim

The invention claimed is:

1. An electron paramagnetic resonance (EPR) spectrometer comprising:
a magnet system comprising at least one magnet and at least one pole piece for producing a magnetic field in a field of view in front of the at least one pole piece, said magnetic field being generated along a pole axis; and
a probe head comprising a microwave resonator and at least one modulation coil or rapid scan coil for producing an additional, time-varying magnetic field aligned along the pole axis that has a frequency between 5 KHz and 200 KHz in an EPR measurement, wherein the probe head is arranged in the field of view, and wherein a respective modulation coil or rapid scan coil is arranged between the microwave resonator and a respective pole piece;

wherein
for each pole piece having a modulation coil or rapid scan coil arranged between said pole piece and the microwave resonator, at least a first part of said pole piece facing said modulation coil or rapid scan coil is made of a function material having an electric conductivity σ f of 10 4 S/m or less, and having a saturation magnetic flux density BS f of 0.2 T or more and each modulation coil or rapid scan coil is fixed to the pole piece it faces; and

for a distance DPC along the pole axis between a respective pole piece and a modulation coil or rapid scan coil it faces, the following applies: 0≤DPC≤2.0 mm.

2. An EPR spectrometer according to claim 1 , wherein of is 10 3 S/m or less, and that BS f is 0.5 T or more.

3. An EPR spectrometer according to claim 1 , wherein the function material is isotropic.

4. An EPR spectrometer according to claim 1 , wherein the function material comprises particles of ferromagnetic or ferrimagnetic material dispersed in an electrically insulating matrix material.

5. An EPR spectrometer according to claim 4 , wherein the function material comprises soft magnetic particles of a ferrite or a metal or a metal alloy dispersed in a polymer matrix material.

6. An EPR spectrometer according to claim 1 wherein, for each pole piece having a modulation coil or rapid scan coil arranged between said pole piece and the microwave resonator, said pole piece is completely made from the function material.

7. An EPR spectrometer according to claim 1 wherein, for each pole piece having a modulation coil or rapid scan coil arranged between said pole piece and the microwave resonator, the first part of said pole piece facing the modulation coil or rapid scan coil is made from the function material, and a remaining part of the pole piece is made from a different material.

8. An EPR spectrometer according to claim 7 , wherein said different material is a metallic material.

9. An EPR spectrometer according to claim 7 , wherein the first part of the pole piece has a thickness T, measured along the pole axis, with T≥0.5 mm, and/or with T≤12.0 mm.

10. An EPR spectrometer according to claim 7 , wherein the first part of the pole piece at least partially overlaps with the complete modulation coil or rapid scan coil in a plane perpendicular to the pole axis.

11. An EPR spectrometer according to claim 7 , wherein the first part of the pole piece extends beyond the modulation coil or rapid scan coil in the plane perpendicular to the pole axis.

12. An EPR spectrometer according to claim 7 wherein the first part of the pole piece is an insert held by press fit in a frame structure of the remaining part of the pole piece.

13. An EPR spectrometer according to claim 7 wherein the first part of the pole piece is glued onto the remaining part of the pole piece.

14. An EPR spectrometer according to claim 7 , wherein the remaining part of the pole piece, but not the first part of the pole piece, comprises one of a plurality of openings through which a respective screw projects, with the screw being screwed into a yoke structure or a permanent magnet of the magnet system.

15. An EPR spectrometer according to claim 1 , wherein the EPR spectrometer comprises a pair of mutually opposing pole pieces and the field of view has a width WAG along the pole axis, with 10 mm≤WAG≤100 mm.

16. An EPR spectrometer according to claim 1 , wherein said pole piece is one of a pair of pole pieces.

17. Use of an EPR spectrometer according to claim 1 , wherein a sample is arranged in the microwave resonator, wherein the magnet system generates a magnetic field in the field of view along the pole axis, and wherein the at least one modulation coil or rapid scan coil generates a time-varying, additional magnetic field in the field of view along the pole axis.

Assignees

• Bruker Biospin Gmbh

Inventors

• Prisecaru Ion
• Haenichen Lukas

Classifications

• G01R33/3806

  Open magnet assemblies for improved access to the sample, e.g. C-type or U-type magnets · CPC title

• H01F7/202

  Electromagnets for high magnetic field strength (for superconducting electromagnets H01F6/00; for transformers or inductances without a magnetic core H01F30/08) · CPC title

• G01R33/60 Primary

  using electron paramagnetic resonance (G01R33/24, G01R33/62 take precedence) · CPC title

• G01R33/383 Primary

  using permanent magnets · CPC title