Non-white roofing granules and methods of making same

Patent metadata

Field	Value
Publication number	US-12071765-B2
Application number	US-202118028745-A
Country	US
Kind code	B2
Filing date	Sep 7, 2021
Priority date	Oct 6, 2020
Publication date	Aug 27, 2024
Grant date	Aug 27, 2024

Abstract

A plurality of non-white roofing granules is provided. The roofing granules include a plurality of particles including mineral fines and a calcia-based cement binder; and a non-white pigment-containing coating disposed on at least a portion of exterior surfaces of the particles. Methods of making the roofing granules are also provided. One method includes: mixing material including mineral fines and a calcia-based cement binder to provide agglomerates; curing the agglomerates to provide particles; and coating at least a portion of exterior surfaces of the particles with a non-white pigment-containing coating. Another method of making the roofing granules includes: providing an aqueous dispersion in a tool having cavities, the aqueous dispersion including mineral fines and a calcia-based cement binder; curing the aqueous dispersion in the tool to provide particles; and coating at least a portion of exterior surfaces of the particles with a non-white pigment-containing coating. The roofing granules exhibit an intrinsic total solar reflectance greater than 0.3. Often, the roofing granules contain by-product mineral fines.

First claim

What is claimed is:

1. A plurality of non-white roofing granules comprising:
a) a plurality of particles comprising mineral fines and a calcia-based cement binder, wherein the mineral fines comprise igneous or metamorphic rock, wherein the calcia-based cement binder comprises Portland cement; and
b) a non-white pigment-containing coating disposed on at least a portion of exterior surfaces of the plurality of particles.

2. The plurality of non-white roofing granules of claim 1 , wherein the non-white pigment-containing coating is disposed on greater than 50% of the exterior surfaces of the plurality of particles.

3. The plurality of non-white roofing granules of claim 1 , wherein the calcia-based cement binder further comprises a calcium silicate, a calcium phosphate, a calcium aluminate, or a combination thereof.

4. The plurality of non-white roofing granules of claim 1 , wherein the mineral fines comprise at least one of nepheline syenite, dacite, rhyolite, andesite, basalt, granite, diabase, or diorite.

5. The plurality of non-white roofing granules of claim 1 , wherein at least a portion of the plurality of non-white roofing granules are free of any coating that comprises titania.

6. The plurality of non-white roofing granules of claim 1 , wherein each non-white roofing granule comprises 50 to 80 percent by weight of the mineral fines, based on the total weight of each non-white roofing granule.

7. The plurality of non-white roofing granules of claim 1 , wherein each non-white roofing granule comprises 5 to 40 percent by weight of the calcia-based cement binder, based on the total weight of each non-white roofing granule.

8. The plurality of non-white roofing granules of claim 1 , wherein each non-white roofing granule collectively comprises at least 80 percent by weight collectively of the mineral fines and the calcia-based cement binder.

9. The plurality of non-white roofing granules of claim 1 , wherein each of the plurality of particles further comprises a pigment disposed within the particle.

10. The plurality of non-white roofing granules of claim 1 , wherein each of the plurality of particles further comprises 0.1 to 10 percent by weight of at least one rheology, durability- and/or aqueous stability-improving additive, based on the total weight of each particle.

11. The plurality of non-white roofing granules of claim 1 , exhibiting an intrinsic total solar reflectance (TSR) of 0.15 or greater, 0.20 or greater, 0.25 or greater, 0.30 or greater, or 0.35 or greater; and 0.60 or less, 0.55 or less, 0.50 or less, 0.45 or less, or 0.40 or less.

12. The plurality of non-white roofing granules of claim 1 , wherein the plurality of non-white roofing granules has an average total pore volume in a range from 0.10 cubic centimeter per gram (cc/g) to 0.40 cc/g.

13. The plurality of non-white roofing granules of claim 1 , exhibiting an average total diffuse reflectance (L*) of less than 60 and an intrinsic total solar reflectance (TSR) of greater than 0.30.

14. The plurality of non-white roofing granules of claim 1 , having particle sizes in a range from 100 micrometers to 5 millimeters, wherein the particles comprise particle sizes in a range from 90 micrometers to 4.9 millimeters.

15. The plurality of non-white roofing granules of claim 1 , wherein the non-white pigment-containing coating comprises a solar-reflective pigment.

16. A method of making the plurality of non-white roofing granules of claim 1 , the method comprising: mixing material comprising the mineral fines and the calcia-based cement binder to provide agglomerates comprising the mineral fines and the calcia-based cement binder; curing the agglomerates to provide a plurality of particles; and coating at least a portion of exterior surfaces of the plurality of particles with a non-white pigment-containing coating.

17. A method of making the plurality of roofing granules of claim 1 , the method comprising: providing an aqueous dispersion in a tool comprising a plurality of cavities, the aqueous dispersion comprising the mineral fines and the calcia-based cement binder; curing the aqueous dispersion in the tool to provide a plurality of particles; and coating at least a portion of exterior surfaces of the plurality of particles with a non-white pigment-containing coating.

Assignees

• 3M Innovative Properties Company

Inventors

• Skorina Taisiya
• Amsden Kristin M
• Budd Kenton D
• Everman Rebecca L A
• Tangeman Jean A

Classifications

• C04B2111/00586

  Roofing materials · CPC title

• C04B18/021

  agglomerated by a mineral binder, e.g. cement · CPC title

• E04D7/005 Primary

  characterised by loose or embedded gravel or granules as an outer protection of the roof covering · CPC title

• C04B20/1059 Primary

  Pigments or precursors thereof · CPC title