Process for the recovery of solvent from solvent-containing cellulosic particles

Patent metadata

Field	Value
Publication number	US-12070701-B2
Application number	US-202017771348-A
Country	US
Kind code	B2
Filing date	Oct 21, 2020
Priority date	Oct 25, 2019
Publication date	Aug 27, 2024
Grant date	Aug 27, 2024

Abstract

A process (100) for the recovery of solvent (1) from solvent-containing cellulosic particles (2) is shown, the process comprising the steps: a) extracting the solvent (1) from the cellulosic particles (2) by means of a liquid extraction medium (3), thereby obtaining a solvent-enriched extraction medium (5), and b) obtaining the recovered solvent (6) from the solvent-enriched extraction medium (5). In order to improve the efficiency of the process, it is proposed that in step a) the solvent (1) is extracted from the cellulosic particles (2) in a continuous flow extraction reactor (4), wherein the extraction medium (3) continuously flows through the extraction reactor (4) to extract the solvent (1) from the cellulosic particles (2).

First claim

What is claimed is:

1. A process for recovering a solvent from solvent-containing cellulosic particles, wherein the solvent is a direct dissolution solvent, comprising the steps:
a) initially extracting the solvent from the solvent-containing cellulosic particles by means of a liquid extraction medium consisting essentially of water, thereby obtaining a solvent-enriched extraction medium, and
b) obtaining a recovered solvent from the solvent-enriched extraction medium,
wherein in step a) the solvent is extracted from the solvent-containing cellulosic particles in a continuous flow extraction reactor, wherein the liquid extraction medium continuously flows through the continuous flow extraction reactor to extract the solvent from the solvent-containing cellulosic particles.

2. The process according to claim 1 , wherein the solvent-containing cellulosic particles are obtained from a production waste of processes for producing regenerated cellulosic molded bodies, optionally from a lyocell spinning dope waste.

3. The process according to claim 2 , wherein the solvent is an amine oxide, optionally NMMO.

4. The process according to claim 1 , wherein the empty continuous flow extraction reactor is filled with the solvent-containing cellulosic particles prior to step a).

5. The process according to claim 1 , wherein the solvent-containing cellulosic particles are contained in an aqueous suspension when filling the empty continuous flow extraction reactor.

6. The process according to claim 5 , wherein excess liquid is removed from the aqueous suspension prior to filling the continuous flow extraction reactor with the aqueous suspension.

7. The process according to claim 6 , wherein the aqueous suspension is filled via a bow-shaped sieve into the continuous flow extraction reactor in order to remove the excess liquid from the aqueous suspension.

8. The process according to claim 1 , wherein the continuous flow extraction reactor has a top inlet and a bottom sieve outlet for the solvent-enriched extraction medium and the liquid extraction medium flows from top to bottom in the continuous flow extraction reactor.

9. The process according to claim 8 , wherein the solvent-enriched extraction medium is obtained from the liquid extraction medium exiting the bottom sieve outlet of the continuous flow extraction reactor.

10. The process according to claim 1 , wherein in step a), the liquid extraction medium continuously flows through the continuous flow extraction reactor, until a content of the solvent in the solvent-enriched extraction medium below a predefined residual value is reached.

11. The process according to claim 10 , wherein after the content of the solvent in the solvent-enriched extraction medium below the predefined residual value is reached, a continuous flow of the liquid extraction medium through the continuous flow extraction reactor is stopped and the continuous flow extraction reactor is emptied.

12. The process according to claim 11 , wherein after emptying the continuous flow extraction reactor, essentially solvent-free cellulosic particles are pressed and/or dried.

13. The process according to claim 1 , wherein the recovered solvent is obtained from the solvent-enriched extraction medium.

Assignees

• Chemiefaser Lenzing Ag

Inventors

• Feiner Roland
• Trinh Thi Huyen Trang
• Sperger Christian

Classifications

• D01F13/02

  of cellulose, cellulose derivatives or proteins {(recovery of sodium sulfate from coagulation baths C01D5/006)} · CPC title

• B01D11/0292

  Treatment of the solvent · CPC title

• Y02P70/62

  related technologies for production or treatment of textile or flexible materials or products thereof, including footwear · CPC title

• C08L1/02

  Cellulose; Modified cellulose · CPC title

• B01D11/0207

  Control systems · CPC title