Bulk metallic glass interconnect for high power density fuel cell

Patent metadata

Field	Value
Publication number	US-12068509-B2
Application number	US-202117235060-A
Country	US
Kind code	B2
Filing date	Apr 20, 2021
Priority date	Apr 21, 2020
Publication date	Aug 20, 2024
Grant date	Aug 20, 2024

Abstract

A solid oxide fuel cell or solid oxide electrolyzer includes a plurality of fuel cell layers stacked along a stacking axis. Each fuel cell layer including a stacked arrangement of elements including a cathode, an anode, an electrolyte located between the anode and the cathode, a support layer positioned at the anode opposite the electrolyte, and a separator plate located at the support layer opposite the anode. The separator plate is configured to contact the cathode of an adjacent fuel cell layer of the plurality of fuel cell layers. The separator plate defines a plurality of anode flow channels configured to deliver a fuel therethrough and a plurality of cathode flow channels configured to deliver an air flow therethrough. The separator plate is formed from a bulk metallic glass material.

First claim

What is claimed is:

1. A solid oxide fuel cell or solid oxide electrolyzer, comprising:
a plurality of fuel cell layers stacked along a stacking axis, each fuel cell layer including a stacked arrangement of elements including:
a cathode;
an anode;
an electrolyte disposed between the anode and the cathode;
a support layer disposed at the anode opposite the electrolyte;
a separator plate disposed at the support layer opposite the anode, the separator plate configured to contact the cathode of an adjacent fuel cell layer of the plurality of fuel cell layers, the separator plate defining a plurality of anode flow channels configured to deliver a fuel therethrough and a plurality of cathode flow channels configured to deliver an air flow therethrough;
wherein the separator plate is formed from a bulk metallic glass material;
wherein the plurality of anode flow channels at least partially overlap the plurality of cathode flow channels in the stacking axis direction of the plurality of fuel cell layers;
wherein the separator plate includes a plurality of curved portions separated by flat support portions, with the support portions interfacing with the support layer and curved portions contacting the cathode of the adjacent fuel cell layer, each curved portion including a first curved surface and a second curved surface spaced apart from the first curved surface along the stacking axis.

2. The solid oxide fuel cell or solid oxide electrolyzer of claim 1 , wherein an electrical conductivity of the separator is attained via crystallization of the bulk metallic glass material.

3. The solid oxide fuel cell or solid oxide electrolyzer of claim 1 , wherein the bulk metallic glass material is corrosion resistant.

4. The solid oxide fuel cell or solid oxide electrolyzer of claim 1 , wherein the separator plate comprises a coating applied to the bulk metallic glass material.

5. The solid oxide fuel cell or solid oxide electrolyzer of claim 1 , wherein the electrolyte is formed from a solid oxide material.

6. The solid oxide fuel cell or solid oxide electrolyzer of claim 1 , wherein the separator plate defines the plurality of anode flow channels at a first side of the separator plate and the plurality of cathode flow channels at a second side of the separator plate opposite the first side.

7. The solid oxide fuel cell or solid oxide electrolyzer of claim 1 , wherein the bulk metallic glass material is one or more of a Fe—Cr—Mo—C—B based bulk metallic glass material, a Zr based bulk metallic glass material, or a bulk metallic glass composite material.

8. A fuel cell layer of a multi-layer fuel cell, comprising:
a cathode;
an anode;
an electrolyte disposed between the anode and the cathode;
a support layer disposed at the anode opposite the electrolyte;
a separator plate disposed at the support layer opposite the anode, the separator plate configured to contact the cathode of an adjacent fuel cell layer, the separator plate defining a plurality of anode flow channels configured to deliver a fuel therethrough and a plurality of cathode flow channels configured to deliver an air flow therethrough;
wherein the separator plate is formed from a bulk metallic glass material;
wherein the plurality of anode flow channels at least partially overlap the plurality of cathode flow channels in the stacking axis direction of the plurality of fuel cell layers;
wherein the separator plate includes a plurality of curved portions separated by flat support portions, with the support portions interfacing with the support layer and curved portions contacting the cathode of the adjacent fuel cell layer, each curved portion including a first curved surface and a second curved surface spaced apart from the first curved surface along the stacking axis.

9. The fuel cell layer of claim 8 , wherein an electrical conductivity of the separator is attained via crystallization of the bulk metallic glass material.

10. The fuel cell layer of claim 8 , wherein the bulk metallic glass material is corrosion resistant.

11. The fuel cell layer of claim 8 , wherein the separator plate comprises a coating applied to the bulk metallic glass material.

12. The fuel cell layer of claim 8 , wherein the separator plate defines the plurality of anode flow channels at a first side of the separator plate and the plurality of cathode flow channels at a second side of the separator plate opposite the first side.

13. The fuel cell layer of claim 8 , wherein the bulk metallic glass material is one or more of a Fe—Cr—Mo—C—B based bulk metallic glass material, a Zr based bulk metallic glass material, or a bulk metallic glass composite material.

14. A method of assembling a multi-layer fuel cell, comprising:
assembling a plurality of fuel cell layers, each fuel cell layer including:
a cathode;
an anode;
an electrolyte disposed between the anode and the cathode;
a support layer disposed at the anode opposite the electrolyte;
a separator plate disposed at the support layer opposite the anode, the separator plate configured to contact the cathode of an adjacent fuel cell layer, the separator plate defining a plurality of anode flow channels configured to deliver a fuel therethrough and a plurality of cathode flow channels configured to deliver an air flow therethrough;
wherein the separator plate is formed from a bulk metallic glass material;
wherein the plurality of anode flow channels at least partially overlap and the plurality of cathode flow channels in the stacking axis direction of the plurality of fuel cell layers;
arranging the plurality of fuel cell layers along a stacking axis;
heating the separator plate to a temperature greater than a glass transition temperature of the bulk metallic glass material;
applying a compressive load to the plurality of fuel cell layers; and
allowing the bulk metallic glass material to thermoplastically flow thereby increasing a contact area of the separator plate to the cathode of the adjacent fuel cell layer;
wherein the separator plate includes a plurality of curved portions separated by flat support portions, with the support portions interfacing with the support layer and curved portions contacting the cathode of the adjacent fuel cell layer, each curved portion including a first curved surface and a second curved surface spaced apart from the first curved surface along the stacking axis.

15. The method of claim 14 , wherein the bulk metallic glass material is one of a Fe—Cr—Mo—C—B based bulk metallic glass material, a Zr based bulk metallic glass material, or a bulk metallic glass composite.

16. The method of claim 14 , wherein the glass transition temperature is below 600 degrees Celsius.

17. The method of claim 14 , wherein thermoplastic flow of the bulk metallic glass material improves a contact area between the separator plate and the support layer.

18. The solid oxide fuel cell or solid oxide electrolyzer of claim 1 , wherein the flow through the plurality of anode flow channels is parallel to the flow through the plurality of cathode flow channels.

Assignees

• Hamilton Sundstrand Corp

Inventors

• Zhu Tianli
• Sheedy Paul
• Sharon John A

Classifications

• Y02E60/50

  Fuel cells · CPC title

• Y02T90/40

  Application of hydrogen technology to transportation, e.g. using fuel cells · CPC title

• H01M2250/20

  Fuel cells in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/1226

  characterised by the supporting layer · CPC title