Polyacrylonitrile (pan) polymers with low polydispersity index (pdi) and carbon fibers made therefrom
US-2015174807-A1 · Jun 25, 2015 · US
US12065762B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12065762-B2 |
| Application number | US-202318217813-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 3, 2023 |
| Priority date | May 10, 2017 |
| Publication date | Aug 20, 2024 |
| Grant date | Aug 20, 2024 |
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A quad-polymer composition includes monomers of (a) acrylonitrile, (a) vinylimidazole, (c) methyl acrylate and (d) either acrylic acid or itaconic acid. Such quad-polymer compositions may be used to form fibers (such as by melt spinning) that may then be annealed, stabilized, and/or carbonized to produce carbon fibers. The quad-polymer composition may be used for supercapacitors, lithium battery electrodes once carbonized, and as synthesized, it may be used for wound healing fibers, fabrics, coatings, and films, and anti-bacterial/anti-microbial fibers, fabrics, coatings and films. The carbon fibers formed from the quad-polymer composition may be used for the fiber composites for automobile, aerospace structures, marine structures, military equipment/parts, sporting goods, robotics, furniture, and electronic parts.
Opening claim text (preview).
The invention claimed is: 1. A method for forming fibers of quad-polymers comprising (a) a first monomer that is acrylonitrile, (b) a second monomer that is selected from a group consisting of 1-vinylimidazole, 4-vinylimidazole, 2-vinylimidazole, and 1-methyl-2-vinylimidazole, (c) a third monomer that is selected from a group consisting of methyl acrylate, ethyl acrylate, butyl acrylate, methyl methacrylate, and tert-butyl acrylate, and (d) a fourth monomer that is an acid and is selected from a group consisting of acrylic acid, itaconic acid, and methacrylic acid, wherein the method includes the steps of: (i) combining the first monomer, the second monomer, the third monomer, and the fourth monomer to form the quad-polymer composition; and (ii) melt-spinning the quad-polymer composition to form fibers of the quad-polymer composition.
Acrylonitrile · CPC title
with carboxylic acids, sulfonic acids or salts thereof · CPC title
from polyacrylonitriles · CPC title
Melt spinning methods {(D01D5/0023 takes precedence)} · CPC title
with nitrogen-containing monomers · CPC title
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