Metal matrix composite material and method of manufacturing same

Patent metadata

Field	Value
Publication number	US-12065722-B2
Application number	US-201916669616-A
Country	US
Kind code	B2
Filing date	Oct 31, 2019
Priority date	Nov 16, 2018
Publication date	Aug 20, 2024
Grant date	Aug 20, 2024

Abstract

A composite material having a grainy appearance, this composite material including a metal matrix which represents, in terms of volume fraction, between 50 and 95% of the grainy composite material, the ceramic particles having a diameter that lies in the range 0.1 to 2 mm and which represent, in terms of volume fraction, between 50 and 5% of the composite material are dispersed in the metal matrix and form the remainder of this grainy composite material. A method for manufacturing a grainy synthetic material.

First claim

The invention claimed is:

1. A sintered composite material having a grainy appearance, the sintered composite material comprising:
ceramic particles in a range of from 5 to 50 vol. %; and
a metal matrix which is in a range of from 50 to 95 vol. % of the sintered composite material, the sintered composite material being a grainy composite material,
wherein the metal matrix is obtained from a metal powder formed by a plurality of particles having a D90 value of a cumulative function of less than 100 μm,
wherein the ceramic particles comprise corundum and having a diameter in a range from 0.1 to 2 mm are dispersed in the metal matrix, provide the sintered composite material with a grainy appearance, and form a remainder of the sintered composite material, and
wherein one or more elements of the metal matrix from metal powder are diffused into the ceramic particles to form infused ceramic particles having a diffused distribution of the one or more elements into the infused ceramic particles.

2. The sintered composite material of claim 1 , wherein the diameter of the ceramic particles lies in the range 0.25 to 0.75 mm.

3. The sintered composite material of claim 1 , wherein the ceramic particles are present in a range of from 5 to 30 vol. % of the sintered composite material, and
wherein the ceramic particles have a diameter in a range of from 0.25 to 0.75 mm.

4. The sintered composite material of claim 1 , wherein the ceramic particles are present in a range of from 10 to 20 vol. % of the sintered composite material, and
wherein the ceramic particles have a diameter in a range of from 0.25 to 0.75 mm.

5. The sintered composite material of claim 1 , wherein the metal matrix is obtained from a metal powder comprising a mixture of a grade 2 titanium powder formed by particles with a D90 value of a cumulative function of less than 25 μm and of the ceramic particles in volume fractions:
15 vol % corundum having a particle size in a range of from 297 μm to 420 μm.

6. The sintered composite material of claim 1 , wherein the metal matrix comprises an austenitic stainless steel, titanium, gold, silver, platinum, palladium, copper, and/or aluminum.

7. The sintered composite material of claim 1 , wherein the ceramic particles further comprise silicon oxide, zirconium oxide, titanium oxide, diamond, silicon carbide, silicon nitride, titanium carbide, titanium boride, and/or zirconium boride.

8. The sintered composite material of claim 1 , wherein the diameter of the ceramic particles is in a range of from 0.2 to 2 mm.

9. The sintered composite material of claim 1 , wherein the ceramic particles further comprise a silicate.

10. The sintered composite material of claim 1 , wherein the metal matrix comprises stainless steel 1.4435 powder formed by particles with a D90 value of a cumulative function of less than 25 μm.

11. The sintered composite material of claim 1 , further comprising:
second ceramic particles that are luminescent inorganic and comprise a rare earth aluminate and/or rare earth silicate.

12. The sintered composite material of claim 1 , wherein the infused ceramic particles comprise chromium and have a pink-red color.

13. The sintered composite material of claim 1 , wherein the infused ceramic particles comprise iron and have a green color.

14. The sintered composite material of claim 1 , wherein the metal matrix is obtained from a metal powder comprising a mixture of a grade 2 titanium powder formed by particles with a D90 value of a cumulative function of less than 25 μm and of the ceramic particles in volume fractions:
15 vol. % corundum having a particle size in a range of from 420 μm to 595 μm.

15. The sintered composite material of claim 1 , wherein the metal matrix is present in a range of from 80 to 90 vol. % of the sintered composite material,
wherein the ceramic particles are present in a range of from 10 to 20 vol. % of the sintered composite material.

16. The sintered composite material of claim 1 , wherein the one or more elements comprise chromium and/or iron.

17. A method for manufacturing the sintered composite material of claim 1 , having a visually grainy appearance, the method comprising:
mixing (a) a powder comprising a plurality of metal particles having a D90 value of a cumulative function of less than 100 μm, with (b) the ceramic particles comprising corundum, having a diameter in a range of from 0.1 to 2 mm, to obtain a feedstock, the metal powder being in a range of from 50 to 95 vol. % of the feedstock;
producing a green body by pressing or by injecting the metal powder particles-ceramic particles mixture into a mold;
subjecting the green body to sintering at a temperature in a range of from 600 to 1,400° C. and for a duration in a range of from 1 h to 4 h to obtain a grey body made of composite material having a visually grainy appearance and comprising a metal matrix which is in a range of from 50 to 95 vol. % of the grey body, and diffusing one or more elements of the metal matrix into the ceramic particles to form infused ceramic particles comprising the one or more elements diffused therein,
wherein the ceramic particles are dispersed and form a remainder of the grey body.

18. The method of claim 17 , wherein, when the metal powder particles are mixed with the ceramic particles to obtain the feedstock, an organic binder is added to the mixture,
wherein the organic binder is in a range of from 2 to 40 vol. % of the feedstock,
wherein the mixture of metal powder particles, ceramic particles, and organic binder are then pressed or injected into the mold, then the organic binder is removed from the green body during at least one debinding.

19. The method of claim 17 , wherein the grey body is machined to reduce the surface roughness.

20. The method of claim 19 , wherein the grey body is ground or sanded.

21. The method of claim 19 , wherein the grey body is polished.

22. The method of claim 19 , further comprising:
subjecting the grey body to chemical or electrochemical etching, thereby revealing different phases composing the composite material, and enhancing contrast between the different phases.

23. The method of claim 19 , further comprising:
subjecting the grey body to an electrode position treatment or to an anodizing treatment.

Assignees

• Swatch Group Res & Dev Ltd

Inventors

• Porret Joel
• Winkler Yves

Classifications

• C22C38/00 Primary

  Ferrous alloys, e.g. steel alloys (cast-iron alloys C22C37/00) · CPC title

• C04B2235/786

  Micrometer sized grains, i.e. from 1 to 100 micron · CPC title

• C04B35/584

  based on silicon nitride · CPC title

• C04B35/58078

  based on zirconium or hafnium borides · CPC title

• C04B35/58071

  based on titanium borides · CPC title