Use of graphene to enhance stability and density control of cement slurries

Patent metadata

Field	Value
Publication number	US-12065377-B2
Application number	US-202217892790-A
Country	US
Kind code	B2
Filing date	Aug 22, 2022
Priority date	Aug 22, 2022
Publication date	Aug 20, 2024
Grant date	Aug 20, 2024

Abstract

A cement slurry including graphene, a cementitious material, and water; the graphene comprises bioderived renewable graphene (BRG). The cement slurry can comprise from about 0.01 to about 20, from about 0.1 to about 15, from about 0.5 to about 5 percent graphene by weight of cementitious material (% graphene bwoc). The cement slurry can have enhanced stability, as evidenced by a uniform density of the slurry and a reduction in free fluid, according to API 10B-2, relative to a same cement slurry absent the graphene.

First claim

What is claimed is:

1. A method of making a cement slurry, the method comprising:
combining graphene with water to provide a mix water, wherein the graphene comprises bioderived renewable graphene (BRG);
combining the mix water with a cementitious material to provide the cement slurry, wherein the cement slurry comprises from about 0.01 to about 20 percent graphene by weight of cementitious material (% graphene bwoc); and
diluting the cement slurry by up to 400% with additional water; and
placing the cement slurry in a workspace, wherein the workspace comprises a wellbore penetrating a subterranean formation, wherein the cement slurry before and after the diluting has enhanced stability, as evidenced by a uniform density of the cement slurry and a reduction in free fluid, as measured according to API 10B-2, relative to a same cement slurry absent the graphene, and wherein:
(1) the BRG comprises nanosheets comprising greater than 90 weight percent carbon, and wherein the nanosheets have a surface area of at least 2000 m 2 /g, a pore volume of at least 3 cc/g, or a combination thereof, or
(2) the BRG is produced by: combining a renewable carbohydrate material with a dehydration solvent to aid hydrolysis;
removing glycosidic linkages and water via chemical and/or thermal activation to provide an intermediate fused carbon material; and
thermochemically activating the intermediate fused carbon material to exfoliate intercalated carbon layers of the intermediate fused carbon material and to initiate chemical bonding of carbon atoms to form the BRG, wherein the BRG comprises a network of sp2 bonded carbon nanosheets, or
(3) both (1) and (2).

2. The method of claim 1 , wherein the cementitious material comprises a cement selected from the group consisting of Type I, IA, II, IIA, III, IIIA, IV, V, VI, VII Portland cements, and combinations thereof.

3. The method of claim 1 , wherein the cementitious material comprises an API grade cement.

4. The method of claim 1 , wherein the BRG comprises graphene derived from a plant.

5. The method of claim 1 , comprising (2), wherein the dehydration solvent comprises water, ethylene glycol, ethanol, or a combination thereof.

6. The method of claim 1 , comprising (2), wherein the chemical activation comprises activation with sodium hydroxide, hydrochloric acid, phosphoric acid, phosphorous acid, nitric acid, or a combination thereof.

7. The method of claim 1 , comprising (2), wherein removing glycosidic linkages is effected in the presence of a catalyst selected from yeast, aluminum-nickel alloy, cobalt, B 2 H 6 , zinc, copper, or a combination thereof.

8. The method of claim 1 , comprising (2), wherein removing glycosidic linkages comprises exposing a mixture of the renewable carbohydrate material, a chemical selected from hydrazine, LiAlH 4 , B 2 H 6 , NaBH 4 , or a combination thereof, and optionally a catalyst to a temperature in a range of from about 45° C. to about 1050° C., in air or inert atmosphere to aid formation of the intermediate fused carbon material, wherein the intermediate fused carbon material comprises a fused carbon network with a sheet-like morphology.

9. The method of claim 1 , wherein the thermochemically activating comprising heating to a temperature in a range of from about 500° C. to about 1500° C., in an inert gas containing hydrogen gas.

10. The method of claim 9 , wherein the thermochemically activating further comprises treating the intermediate fused carbon material with a chemical selected from hydrazine, LiAlH 4 , B 2 H 6 , NaBH 4 , or a combination thereof.

11. The method of claim 1 , comprising (2), wherein thermochemically activating comprises direct heating of the intermediate fused carbon material to exfoliate and remove water from the intermediate fused carbon material to form the BRG.

12. The method of claim 1 , wherein the graphene maintains thixotropic behavior and flowability of the cement slurry during the placing.

13. The method of claim 1 , wherein a thixotropic rate of the cement slurry, measured according to API 10B-2, divided by ten, is less than a thixotropic rate of the same cement slurry absent the graphene.

Assignees

• Halliburton Energy Services Inc

Inventors

• Lewis Samuel J
• Pisklak Thomas Jason
• Pineda Claudia

Classifications

• C04B40/0046

  characterised by their processing, e.g. sequence of mixing the ingredients when preparing the premixtures · CPC title

• E21B33/13

  Methods or devices for cementing, for plugging holes, crevices or the like · CPC title

• C09K8/467

  containing additives for specific purposes · CPC title

• C04B2201/20

  for the density · CPC title

• C04B28/04

  Portland cements · CPC title