Static mixing device and method for mixing phosgene and an organic amine

Patent metadata

Field	Value
Publication number	US-12064733-B2
Application number	US-201917257083-A
Country	US
Kind code	B2
Filing date	Jul 3, 2019
Priority date	Jul 30, 2018
Publication date	Aug 20, 2024
Grant date	Aug 20, 2024

Abstract

Phosgene is mixed with an organic polyamine to produce polyisocyanate compounds. A phosgene flow is established in a conduit (15), and the organic polyamine is injected into the phosgene flow. A constricted region (4) of the conduit (15) resides downstream of the point of the polyamine injection. The presence of the constricted region (4) reduces by-product formation.

First claim

What is claimed is:

1. A method for mixing phosgene with an organic polyamine comprising;
establishing an axially directed phosgene flow through a conduit having an outer sidewall;
injecting the organic polyamine into the conduit through multiple circumferentially aligned jets, each such jet having a hydrodynamic diameter D j and each having a location on a wall of the conduit, to establish multiple organic polyamine streams into the axially directed phosgene flow; wherein the conduit has a cross-sectional area A at the location of the one or more jets;
then passing the phosgene and the organic polyamine through a constricted region of the conduit that has a cross-sectional area less than A, wherein the constricted region is produced by a circumferential projection having a curved parabolic, elliptical, arc or hyperbolic leading edge that aligns with flow streamlines located on an internal surface of the outer sidewall of the conduit perpendicular to the axially directed phosgene flow and has a smallest cross-sectional area that is 50 to 95% of cross-sectional area A and wherein the constricted region begins downstream of the multiple jets at a distance equal to 0.01 to 3 times the hydrodynamic diameter D j , reaches a minimum cross-sectional area at a distance equal to 1 to 3 times the hydrodynamic diameter Dj downstream of the multiple jets and extends downstream of the multiple jets to a distance that is no greater than 8 times the diameter hydrodynamic D j ; and
thereafter passing the phosgene and the organic polyamine into a region having a cross-sectional area at least 2 times as large as cross-sectional area A.

2. The method of claim 1 wherein the conduit has an annular cross-section.

3. The method of claim 2 wherein the conduit has a cross-sectional width of 4 to 10 mm at the location of the jets and the jets each have a diameter of 3 to 7 mm.

4. A static mixing device comprising:
a) a conduit defined by an outer sidewall and optionally an inner sidewall, the conduit having a longitudinal axis, an inlet end for introducing a first fluid and an outlet end for removing a reaction product stream, the conduit defining a fluid flow path;
b) a plurality of circumferentially-aligned jets each having a location on a sidewall of the conduit between said inlet and outlet ends of the conduit, each jet providing a fluid flow path through the outer sidewall and into the conduit and each such jet having a hydraulic diameter D j ; wherein the conduit has a cross-sectional area A at the location of the jets;
c) a constricted region of the conduit, the constricted region being produced by a circumferential projection having a parabolic, elliptical, arc or hyperbolic leading edge that aligns with flow streamlines located on an internal surface of the outer sidewall of the conduit perpendicular to the axially directed phosgene flow and being further characterized in having a cross-sectional area less than A and being located downstream of the circumferentially-aligned jets and upstream of the outlet end of the conduit, wherein the constricted region has a smallest cross-sectional area that is 50 to 95% of cross-sectional area A and the constricted region begins downstream of the multiple jets at a distance equal to 0.01 to 3 times the diameter D j , reaches a minimum cross-sectional area at a distance equal to 1 to 3 times the hydrodynamic diameter D j downstream of the multiple jets and extends downstream of the jets to a distance that is no greater than 8 times the diameter D j ; and
d) a region, downstream of and in fluid communication with the constricted region of the conduit, which has a cross-sectional area of at least 2 times A.

Assignees

• Dow Global Technologies Llc

Inventors

• Gillis Paul A
• Yuan Quan

Classifications

• B01F25/31423 Primary

  with a plurality of perforations in the circumferential direction only and covering the whole circumference · CPC title

• B01F25/4336

  Mixers with a diverging cross-section · CPC title

• C07C263/10 Primary

  by reaction of amines with carbonyl halides, e.g. with phosgene · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• B01J19/2405

  provoking a turbulent flow of the reactants, such as in cyclones, or having a high Reynolds-number · CPC title