Method for determining degree of wetting by using low current test

Patent metadata

Field	Value
Publication number	US-12062773-B2
Application number	US-202017623510-A
Country	US
Kind code	B2
Filing date	Jul 2, 2020
Priority date	Jul 2, 2019
Publication date	Aug 13, 2024
Grant date	Aug 13, 2024

Abstract

Provided is a method for determining the wetting degree of a lithium ion battery cell using a low current test. The wetting degree determination method according to the present disclosure includes a) obtaining, as a reference charge profile, a charge profile recorded while charging a reference battery cell having undergone receiving an electrode assembly and an electrolyte solution in a case, assembling and pre-aging with a low current of 0.01 C-rate or less, b) measuring and recording a charge profile while charging another battery cell having undergone receiving an electrode assembly and an electrolyte solution in a case, assembling and pre-aging with a low current of 0.01 C-rate or less in the same way as the reference battery cell, and c) determining the wetting degree of another battery cell relative to the reference battery cell by comparative analysis of the reference charge profile and the measured charge profile.

First claim

What is claimed is:

1. A wetting degree determination method, comprising:
a) obtaining, as a reference charge profile, a charge profile recorded while charging a reference battery cell having undergone receiving an electrode assembly and an electrolyte solution in a case, assembling and pre-aging with a low current of 0.01 C-rate or less;
b) measuring and recording a charge profile while charging a second battery cell having undergone receiving an electrode assembly and an electrolyte solution in a case, assembling and pre-aging with a low current of 0.01 C-rate or less in a same way as the reference battery cell; and
c) determining the wetting degree of the second battery cell relative to the reference battery cell by comparative analysis of the reference charge profile and the measured charge profile.

2. The wetting degree determination method according to claim 1 , wherein charging in the step of recording the charge profile in a) and b) comprises charging with a constant current until a cut-off voltage.

3. The wetting degree determination method according to claim 1 , wherein the charge profile is a graph showing a change in battery cell voltage as a function of charging time.

4. The wetting degree determination method according to claim 3 , wherein the comparative analysis in c) comprises determining based on the time required to reach a cut-off voltage or a slope difference of the charge profile.

5. The wetting degree determination method according to claim 2 , wherein the cut-off voltage is 2.0V or less.

6. The wetting degree determination method according to claim 1 , wherein recording the measured charge profile while charging with the low current of 0.01 C-rate or less forms a part of a formation process which is an initial charging step for the battery cell.

7. The wetting degree determination method according to claim 1 , wherein the second battery cell is assembled and pre-aged in the same way as the reference battery cell, and b) and c) are performed to test all battery cells in a production line.

8. The wetting degree determination method according to claim 1 , wherein the reference battery cell and the second battery cell are assembled in a same line, and the charge profile is recorded by charging the reference battery cell and the second battery cell simultaneously in a same charger/discharger.

9. The wetting degree determination method according to claim 1 , wherein specifications for determining the wetting degree as a function of pre-aging condition are obtained by assembling the second battery cell in the same way as the reference battery cell and pre-aging in a different condition.

10. The wetting degree determination method according to claim 9 , wherein the pre-aging is performed between 2 hours and 48 hours.

11. A wetting degree determination method, comprising:
pre-aging a reference battery with a current of 0.01 C-rate or less for 2 to 48 hours;
injecting the reference battery with an electrolyte solution;
obtaining a reference charge profile by charging the reference battery with a constant current between 0 and 0.01 C-rate;
pre-aging a second battery with a current of 0.01 C-rate or less for 2 to 48 hours;
injecting the second battery with an electrolyte solution;
obtaining a charge profile by charging the second battery with a constant current between 0 and 0.01 C-rate; and
determining a wetting degree of the second battery relative to the reference battery by comparative analysis of the reference charge profile and the charge profile.

12. The wetting degree determination method according to claim 11 , wherein the obtaining the reference charge profile and the obtaining the charge profile are performed until a cut-off voltage.

13. The wetting degree determination method according to claim 12 , wherein the cut-off voltage is 2.0V or less.

14. The wetting degree determination method according to claim 12 , wherein the charge profile includes a graph showing a change in a battery cell voltage as a function of charging time.

15. The wetting degree determination method according to claim 14 , wherein the comparative analysis comprises determining based on the time required to reach the cut-off voltage or a slope difference of the charge profile.

16. The wetting degree determination method according to claim 11 , wherein the second battery is determined as a poor battery when the time to reach the cut-off voltage is 5% more than an average time.

17. The wetting degree determination method according to claim 11 , wherein the second battery is determined as a poor battery when the slope difference of the charge profile is 5% more than an average slope.

18. The wetting degree determination method according to claim 11 , wherein the reference battery and the second battery are assembled in a same line, and the charge profile is recorded by charging the reference battery and the second battery simultaneously in a same charger/discharger.

19. The wetting degree determination method according to claim 18 , wherein the pre-aging is performed under room temperature and atmospheric pressure condition.

20. The wetting degree determination method according to claim 11 , wherein specifications for determining the wetting degree as a function of pre-aging condition are obtained by assembling the second battery in the same way as the reference battery and pre-aging in a different condition.

Assignees

• Lg Energy Solution Ltd

Inventors

• Ko Myung-Hoon
• Kim Jee-Ho
• Lee Yong-Tae
• Park Pil-Kyu

Classifications

• H01M10/446 Primary

  Initial charging measures · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/0447 Primary

  of complete cells or cells stacks · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/058

  Construction or manufacture · CPC title