Water soluble fibers with post process modifications and articles containing same

Patent metadata

Field	Value
Publication number	US-12060658-B2
Application number	US-202117466279-A
Country	US
Kind code	B2
Filing date	Sep 3, 2021
Priority date	Sep 4, 2020
Publication date	Aug 13, 2024
Grant date	Aug 13, 2024

Abstract

Methods of treating fibers comprising a polymer including at least one of a vinyl acetate moiety or a vinyl alcohol moiety, and resulting fibers or the products comprising the resulting fibers are disclosed. In an example embodiment, a fiber having a surface region and an interior region, includes a polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety chemically modified with a modification agent. The fiber has a transverse cross-section including the interior region comprising the polymer having a first degree of modification and the surface region comprising the polymer having a second degree of modification greater than the first degree of modification.

First claim

What is claimed is:

1. A post-process modified, water-soluble fiber having a surface region and an interior region, the fiber comprising:
a polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety chemically modified after fiber formation with a modification agent,
the fiber having a transverse cross-section including the interior region comprising the polymer having a first degree of modification and the surface region comprising the polymer having a second degree of modification greater than the first degree of modification.

2. The fiber according to claim 1 , wherein the transverse cross-section of the fiber has an increasing gradient in a degree of modification of the polymer from the interior region to the surface region.

3. The fiber according to claim 1 , wherein the polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety without modification comprises a polyvinyl alcohol homopolymer, a polyvinyl acetate homopolymer, a polyvinyl alcohol copolymer, or any combination thereof.

4. A post-process modified fiber having a surface region and an interior region, the fiber comprising:
a polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety chemically modified after fiber formation with a modification agent,
the fiber having a transverse cross-section including the interior region comprising the polymer having a first degree of modification and the surface region comprising the polymer having a second degree of modification greater than the first degree of modification,
wherein the polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety without modification comprises a polyvinyl acetate homopolymer, a polyvinyl alcohol copolymer comprising a copolymer of vinyl acetate and vinyl alcohol, or any combination thereof.

5. The fiber according to claim 4 , wherein the polyvinyl alcohol copolymer comprises an anionic modification.

6. The fiber according to claim 5 , wherein the anionic modification comprises a carboxylate, a sulfonate, or a combination thereof.

7. A post-process modified fiber having a surface region and an interior region, the fiber comprising:
a polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety chemically modified after fiber formation with a modification agent, wherein the polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety chemically modified with the modification agent is chemically bonded with a moiety of the modification agent,
the fiber having a transverse cross-section including the interior region comprising the polymer having a first degree of modification and the surface region comprising the polymer having a second degree of modification greater than the first degree of modification.

8. The fiber according to claim 7 , wherein the modification agent comprises an anhydride, and the modification agent moiety comprises a carboxyl acid from the anhydride or a salt thereof.

9. The fiber according to claim 7 , wherein the anhydride is selected from acetic anhydride, propionic anhydride, isobutyric anhydride, maleic anhydride, phthalic anhydride, glutaric anhydride, itaconic anhydride, citraconic anhydride, glutaconic anhydride, or any combination thereof.

10. The fiber according to claim 7 , wherein the polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety before modification is a copolymer of vinyl acetate and vinyl alcohol having a degree of hydrolysis in a range of from about 79% to about 99%, and the modification agent comprises maleic anhydride.

11. The fiber according to claim 1 , further comprising an additional polymer.

12. The fiber according to claim 11 , wherein the additional polymer is selected from the group consisting of a polyvinyl alcohol, a polyvinyl acetate, a polyacrylate, a water-soluble acrylate copolymer, a polyvinyl pyrrolidone, a polyethylenimine, a pullulan, a guar gum, a gum Acacia, a xanthan gum, a carrageenan, a starch, a modified starch, a polyalkylene oxide, a polyacrylamide, a polyacrylic acid, a cellulose, a cellulose ether, a cellulose ester, a cellulose amide, a polycarboxylic acid, a polyaminoacid, a polyamide, a gelatin, a dextrin, copolymers of the foregoing, and any combination of any of the foregoing additional polymers or copolymers.

13. The fiber according to claim 1 , wherein the fiber has a dissolution time of less than 200 seconds in water at about 23° C.

14. A post-process modified, water-soluble fiber having a longitudinal axis and a transverse cross-section perpendicular to the longitudinal axis, the fiber further having a core-sheath structure along at least a portion of the longitudinal axis, the fiber comprising:
a core region comprising a polymer comprising at least one of a vinyl acetate moiety and a vinyl alcohol moiety chemically modified after fiber formation with a modification agent and having a first degree of modification, and
a sheath region comprising the polymer comprising at least one of a vinyl acetate moiety and a vinyl alcohol moiety chemically modified after fiber formation with the modification agent and having a second degree of modification greater than the first degree of modification.

15. The fiber according to claim 14 , further comprising an intermediate region disposed between the core region and the sheath region, the intermediate region comprising the polymer comprising at least one of a vinyl acetate moiety and a vinyl alcohol moiety chemically modified with the modification agent and having a third degree of modification greater than the first degree of modification and less than the second degree of modification.

16. The fiber according to claim 15 , comprising a plurality of intermediate regions disposed between the core region and the sheath region, such that the transverse cross-section of the fiber has a gradient in the degree of modification from the core region to the sheath region.

17. The fiber according to claim 14 , wherein the transverse cross-section of the fiber has a first mean radius and the sheath region has a second mean radius of 0.5% to 12% of the first mean radius.

18. The fiber according to claim 15 , wherein the polymer in the core region, the polymer in the sheath region, and optionally the polymer in the intermediate region have an equal degree of polymerization.

19. The fiber according to claim 14 , wherein the polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety without modification comprises a polyvinyl alcohol homopolymer, a polyvinyl acetate homopolymer, a polyvinyl alcohol copolymer, or any combination thereof.

20. The fiber according to claim 19 , wherein the polyvinyl alcohol copolymer is a copolymer of vinyl acetate and vinyl alcohol.

21. The fiber according to claim 14 , wherein the polymer comprising at least one of a vinyl acetate moiety or a vinyl alcohol moiety chemically modified with the modification agent is chemically bonded with a moiety of the modification agent.

22. The fiber according to claim 14 , wherein the modification agent comprises an anhydride.

23. The fiber according to claim 22 , wherein the anhydride is selected from acetic anhydride, propionic anhydride, isobutyric anhydride, maleic anhydride, phthalic anhydride, glutaric anhydride, itaconic anhydride, citraconic anhydride, glutaconic anhydride, or any combination thereof.

24. A nonwoven web comprising the mo

Assignees

• Monosol Llc

Inventors

• Zeese Nicholas
• Knight Jonathon
• Goetz Richard
• Bridewell Victoria
• Shuey Alyssa

Classifications

• Y10T428/2967

  Synthetic resin or polymer · CPC title

• D10B2509/02

  Bandages, dressings or absorbent pads · CPC title

• D10B2505/10

  Packaging, e.g. bags · CPC title

• D06M2101/24

  Polymers or copolymers of alkenylalcohols or esters thereof; Polymers or copolymers of alkenylethers, acetals or ketones · CPC title

• D06M13/203

  Unsaturated carboxylic acids; Anhydrides, halides or salts thereof · CPC title