Method for producing a PGM collector alloy

Patent metadata

Field	Value
Publication number	US-12060624-B2
Application number	US-202017433552-A
Country	US
Kind code	B2
Filing date	Jan 16, 2020
Priority date	Mar 26, 2019
Publication date	Aug 13, 2024
Grant date	Aug 13, 2024

Abstract

A method for producing a PGM collector alloy comprising the steps of:(1) providing (a) copper and/or silver, (b) material, which is to be processed melt-metallurgically, in the form of at least one sodium and/or potassium aluminosilicate support equipped with at least one PGM, and (c) at least one compound selected from the group consisting of iron oxides, calcium oxide, magnesium oxide, calcium carbonate, magnesium carbonate, sodium carbonate, and potassium carbonate,(2) joint melting of the materials provided in step (1) at a temperature in the range of 1250 to <1450° C. by maintaining a 100:40 to 100:20 weight ratio of the materials provided in sub-steps (1b) and (1c), and a 35:65 to 80:20 weight ratio of copper and/or silver: PGM by forming a melt comprising two phases of different density,(3) separating the upper phase of low density of molten slag from the lower phase of high density of molten PGM collector alloy by utilizing the density difference,(4) allowing the melting phases separated from one another to cool down and solidify, and(5) collecting the solidified PGM collector alloy.

First claim

The invention claimed is:

1. A method for producing a platinum group metal (PGM) collector alloy comprising the steps of:
(1) providing (a) copper and/or silver, (b) a material, which is to be processed melt-metallurgically, in the form of at least one sodium aluminosilicate support and/or potassium aluminosilicate support equipped with at least one PGM, and (c) at least one compound selected from the group consisting of iron oxides, calcium oxide, magnesium oxide, calcium carbonate, magnesium carbonate, sodium carbonate, and potassium carbonate,
(2) joint melting of the materials provided in step (1) at a temperature in the range of 1250 to <1450° C. by maintaining a 100:40 to 100:20 weight ratio of the materials provided in sub-steps (1b) and (1c), and a 35:65 to 80:20 weight ratio of copper and/or silver: PGM by forming a melt comprising two phases of different density,
(3) separating the two phases, the two phases being a first upper phase of molten slag from a second lower phase of molten PGM collector alloy, by utilizing the density difference therebetween where the density of the first upper phase is lower than the density of the second lower phase,
(4) allowing the separated upper and lower phases to cool down and solidify, and
(5) collecting the solidified PGM collector alloy.

2. The method of claim 1 , wherein the material, which is to be processed melt-metallurgically, provided in sub-step (1b) is a PGM-containing heterogenous catalyst with the at least one sodium aluminosilicate support and/or potassium aluminosilicate support.

3. The method of claim 2 , wherein the PGM content of the material provided in sub-step (1b) lies in the range of 0.01 to 10% by weight.

4. The method of claim 2 , wherein a reducing agent is provided in a sub-step (1d) and is added in step (2).

5. The method of claim 2 , wherein at least one material, which is to be melt-metallurgically processed, other than the material provided in sub-step (1b), is provided in a sub-step (1e), and is melted in step (2) together with the material provided in sub-step (1b).

6. The method claim 2 , wherein the two phases form at a ratio, which adds up to 100 parts by weight, in the range of 10 to 80 parts by weight of PGM collector alloy: 20 to 90 parts by weight of slag.

7. The method of claim 1 , wherein the PGM content of the material provided in sub-step (1b) lies in the range of 0.01 to 10% by weight.

8. The method of claim 7 , wherein a reducing agent is provided in a sub-step (1d) and is added in step (2).

9. The method of claim 7 , wherein at least one material, which is to be melt-metallurgically processed, other than the material provided in sub-step (1b), is provided in a sub-step (1e), and is melted in step (2) together with the material provided in sub-step (1b).

10. The method claim 7 , wherein the two phases form at a ratio, which adds up to 100 parts by weight, in the range of 10 to 80 parts by weight of PGM collector alloy: 20 to 90 parts by weight of slag.

11. The method of claim 1 , wherein a reducing agent is provided in a sub-step (1d) and is added in step (2).

12. The method of claim 11 , wherein at least one material, which is to be melt-metallurgically processed, other than the material provided in sub-step (1b), is provided in a sub-step (1e), and is melted in step (2) together with the material provided in sub-step (1b).

13. The method claim 11 , wherein the two phases form at a ratio, which adds up to 100 parts by weight, in the range of 10 to 80 parts by weight of PGM collector alloy: 20 to 90 parts by weight of slag.

14. The method of claim 1 , wherein at least one material, which is to be melt-metallurgically processed, other than the material provided in sub-step (1b), is provided in a sub-step (1e), and is melted in step (2) together with the material provided in sub-step (1b).

15. The method of claim 14 , wherein the material provided in sub-step (1e) accounts for a quantity of >0 to <30% by weight, based on the sum of the materials, which are to be melt-metallurgically processed, provided in sub-steps (1b) and (1e).

16. The method claim 1 , wherein the two phases form at a ratio, which adds up to 100 parts by weight, in the range of 10 to 80 parts by weight of PGM collector alloy: 20 to 90 parts by weight of slag.

17. The method of claim 1 , wherein the material provided in sub-step (1b) is completely homogeneously processed melt-metallurgically.

Assignees

• Heraeus Deutschland Gmbh & Co Kg

Inventors

• Dittrich Regina
• Bauer-Siebenlist Bernhard
• Winkler Holger

Classifications

• C22B9/10

  with refining or fluxing agents; Use of materials therefor, {e.g. slagging or scorifying agents}(C22B9/18 takes precedence){(C22B9/006 takes precedence)} · CPC title

• C22B7/004

  separating two or more metals by melting out (liquation), i.e. heating above the temperature of the lower melting metal component(s); by fractional crystallisation (controlled freezing) · CPC title

• Y02P10/20

  Recycling · CPC title

• C22B5/10

  by solid carbonaceous reducing agents · CPC title

• C22B11/026 Primary

  from spent catalysts · CPC title