Nitrogen-free and low-nitrogen crosslinking additives for cold-cure flexible slabstock foam having improved compression and aging properties

Patent metadata

Field	Value
Publication number	US-12060451-B2
Application number	US-202117367456-A
Country	US
Kind code	B2
Filing date	Jul 5, 2021
Priority date	Jul 16, 2020
Publication date	Aug 13, 2024
Grant date	Aug 13, 2024

Abstract

Process for producing cold-cure flexible slabstock PU foams by reaction of at least one polyol component and at least one isocyanate component in the presence of water and at least one catalyst and at least one crosslinker, wherein no nitrogen-containing crosslinkers having an expanded OH number above 1000 mg KOH/g are employed in a total amount >0.5 parts by weight, preferably >0.1 parts by weight, based on 100 parts by weight of polyol.

First claim

The invention claimed is:

1. A process for producing cold-cure flexible slabstock PU foams, comprising: reacting at least one polyol component and at least one isocyanate component in the presence of water and at least one tin catalyst,
wherein nitrogen-containing crosslinkers having an expanded OH number above 1000 mg KOH/g are employed in a total amount of less than or equal to 0.5 parts by weight, based on 100 parts by weight of the at least one polyol component, wherein nitrogen-containing crosslinkers in the context of the present invention have a nitrogen content of >0.5% by weight, measured by Kjeldahl analysis, and
wherein at least two nitrogen-free or low-nitrogen crosslinkers having a nitrogen content of ≤0.5% by weight, measured by Kjeldahl analysis, are employed in a total amount ≥0.1 parts by weight, based on 100 parts by weight of the at least one polyol component,
wherein not more than 4 parts by weight of water per 100 parts by weight of the at least one polyol component are employed and wherein, based on the total weight of the at least one polyol component, >50% by weight of cold-cure flexible foam ether polyols having molar masses of >1500 g/mol per OH group are employed and wherein all the crosslinkers employed have a functionality of isocyanate-reactive groups of ≥3,
wherein isocyanates suitable as the least one isocyanate component include all isocyanates containing at least two isocyanate groups, wherein the isocyanate index is >95 and ≤115, wherein less than 2 parts by weight polyester ether having an OH number of 55 to 57 mg KOH/g per 100 parts by weight of the at least one polyol component is employed, and
wherein the at least two nitrogen-free or low-nitrogen containing crosslinkers having a nitrogen content of ≤0.5% by weight are provided as a mixture comprising a combination of (i) maltitol and (ii) at least one of diglycerol and triglycerol, or a combination of 40 to 60% by weight of sorbitol and/or maltitol and 15 to 30% by weight of diglycerol and/or triglycerol and 15 to 35% by weight water.

2. The process according to claim 1 , wherein the at least two nitrogen-free or low-nitrogen crosslinkers having a nitrogen content of ≤0.5% by weight is provided as a mixture comprising 40 to 60% by weight sorbitol, 15 to 30% by weight diglycerol or triglycerol, and 15 to 35% by weight water.

3. The process according to claim 1 , wherein at least 50% by weight of the at least one polyol component has a functionality of 2.5 to 4, number-average molecular weights determined by gel permeation chromatography in the range from 4500 to 8000 g/mol and comprise >50%, of primary hydroxyl groups.

4. The process according to claim 1 , wherein cold-cure foam polymer polyols are employed.

5. A cold-cure flexible slabstock PU foam, obtained by a process according to claim 1 .

6. A cold-cure flexible slabstock PU foam according to claim 5 , wherein based on its starting volume the PU foam body has been compressed by at least 20%, and is kept in compressed form by an auxiliary means for at least 20 hours.

7. A mattress or cushion comprising the cold-cure flexible slabstock PU foam according to claim 5 .

8. The process according to claim 1 , wherein the at least two nitrogen-free or low-nitrogen crosslinkers having a nitrogen content of ≤0.5% by weight comprise (i) maltitol and (ii) diglycerol or triglycerol.

9. The process according to claim 1 , wherein nitrogen-containing crosslinkers having an expanded OH number above 1000 mg KOH/g are employed in a total amount of less than or equal to 0.1 parts by weight based on 100 parts by weight of the at least one polyol component.

10. The process according to claim 1 , wherein at least two nitrogen-free or low-nitrogen crosslinkers having a nitrogen content of ≤0.5% by weight, measured by Kjeldahl analysis, are employed in a total amount ≥0.2 to 3 parts by weight relative to 100 parts by weight of the at least one polyol component.

11. The process according to claim 1 , wherein the at least two nitrogen-free or low-nitrogen crosslinkers having a nitrogen content of ≤0.5% by weight, measured by Kjeldahl analysis, are employed in a total amount ≥0.5 to 2 parts by weight relative to 100 parts by weight of the at least one polyol component.

12. The process according to claim 1 , wherein at least 50% by weight of the at least one polyol component has a functionality of 2.5 to 4, number-average molecular weight determined by gel permeation chromatography in the range from 4500 to 8000 g/mol and comprises from 70 to 95% of primary hydroxyl groups.

13. The cold-cure flexible slabstock PU foam according to claim 5 , wherein based on its starting volume the PU foam body has been compressed by at least 30%, and is kept in compressed form by an auxiliary means for at least 20 hours.

14. The cold-cure flexible slabstock PU foam according to claim 5 , wherein based on its starting volume the PU foam body has been compressed by at least 40%, and is kept in compressed form by an auxiliary means for at least 20 hours.

15. The process according to claim 1 , wherein prior to reacting the at least two nitrogen-free or low-nitrogen containing crosslinkers having a nitrogen content of ≤0.5% by weight are provided as a mixture comprising 40 to 60% by weight of sorbitol and/or maltitol and 15-30% by weight of diglycerol and/or triglycerol and 15-35% by weight water.

16. The process according to claim 1 , wherein the at least two nitrogen-free or low-nitrogen containing crosslinkers comprise triglycerol.

17. The process according to claim 1 , wherein the at least two nitrogen-free or low-nitrogen containing crosslinkers comprise diglycerol.

Assignees

• Evonik Operations Gmbh

Inventors

• Modro Harald
• Feldmann Kai-Oliver
• Vidakovic Mladen
• Landers Rüdiger
• Hermann Daniela

Classifications

• C08G2101/00

  Manufacture of cellular products · CPC title

• C08G18/3206

  aliphatic · CPC title

• B01J23/14

  of germanium, tin or lead · CPC title

• A47C27/14

  with foamed material inlays · CPC title

• C08G2110/0083

  prepared using water as the sole blowing agent · CPC title