Systems and processes for transferring heat using molten salt during hydrocarbon upgrading

Patent metadata

Field	Value
Publication number	US-12059663-B2
Application number	US-201917271721-A
Country	US
Kind code	B2
Filing date	Aug 20, 2019
Priority date	Aug 31, 2018
Publication date	Aug 13, 2024
Grant date	Aug 13, 2024

Abstract

A reactor system for thermally treating a hydrocarbon-containing stream includes a pressure containment vessel having an interior chamber defined by a first end, a second end, and at least one sidewall extending from the first end to the second end. A heat transfer medium converts electrical current to heat is positioned within the interior chamber of the pressure containment vessel, and the heat transfer medium has a first end face, a second end face, and channels extending between the first end face and the second end face. A heat sink reservoir includes molten salt, and at least one of a heater or heat exchanger is fluidly coupled to the heat transfer medium and thermally coupled to the heat sink reservoir.

First claim

The invention claimed is:

1. A reactor system for thermally treating a hydrocarbon-containing stream comprising:
a heat sink reservoir comprising molten salt;
a pressure containment vessel comprising:
an interior chamber defined by a first end, a second end, and at least one sidewall extending from the first end to the second end,
a heat transfer medium that converts electrical current to heat and is positioned within the interior chamber of the pressure containment vessel, wherein the heat transfer medium comprises:
a first end face;
a second end face; and
channels extending between the first end face and the second end face, and

a heat exchanger positioned within the interior chamber of the pressure containment vessel and downstream from the heat transfer medium, wherein the heat exchanger:
is fluidly coupled to the heat transfer medium;
is thermally coupled to the heat sink reservoir;
is configured to house the molten salt; and
is configured to transfer heat to the molten salt; and

a heater positioned upstream from the heat transfer medium, wherein the heater:
is fluidly coupled to the heat transfer medium,
is thermally coupled to the heat sink reservoir,
is configured to house the molten salt, and
is configured to transfer heat from the molten salt.

2. The reactor system of claim 1 , wherein the molten salt is selected from the group consisting of lithium fluoride (LiF), beryllium fluoride (BeF 2 ), zirconium tetrafluoride (ZrF 4 ), sodium fluoride (NaF), rubidium fluoride (RbF), potassium fluoride (KF), potassium carbonate (K 2 CO 3 ), lithium carbonate (Li 2 CO 3 ), sodium carbonate (Na 2 CO 3 ), and combinations thereof.

3. The reactor system of claim 1 , wherein the molten salt has a heat capacity from 1.65 J/g K to 2.10 J/g K.

4. The reactor system of claim 1 , wherein a pressure of the interior chamber of the pressure containment vessel can be modified without heating any of the first end of the pressure containment vessel, the second end of the pressure containment vessel, the at least one sidewall of the pressure containment vessel, and the heat transfer medium.

5. The reactor system of claim 1 , wherein the heat transfer medium is formed from a material selected from the group consisting of ceramics, metals, and graphite.

6. The reactor system of claim 1 , wherein the heat transfer medium comprises silicon carbide.

7. The reactor system of claim 1 , wherein the heat transfer medium has a total power of from 5 to 50 kW.

8. The reactor system of claim 1 , wherein:
the heat transfer medium has a combined first end face, second end face, and channels surface area of from 650 to 750 mm 2 ; and
the heat transfer medium has a total surface area of from 0.08 to 0.2 m 2 per kilogram per hour of fluid flow at a velocity of from 20 to 200 m/s.

9. The reactor system of claim 1 , wherein:
the heat transfer medium comprises from 50 to 70 heating elements; and
the heat transfer medium produces from 10 to 1000 kW per heating element.

10. The reactor system of claim 1 , wherein the molten salt has a heat capacity from 1.80 J/g K to 1.95 J/g K.

11. A process for thermally treating a hydrocarbon-containing stream comprising:
introducing the hydrocarbon-containing stream to a heater, wherein the heater houses molten salt, and the molten salt is at a first temperature;
heating the hydrocarbon-containing stream at the heater by transferring heat from the molten salt to the hydrocarbon-containing stream, thereby decreasing a temperature of the molten salt to a third temperature;
transferring the molten salt at the third temperature to a heat sink reservoir comprising a supply of the molten salt;
introducing the hydrocarbon-containing stream into channels of a heat transfer medium positioned downstream from the heater, wherein the heat transfer medium is positioned within an interior chamber of a pressure containment vessel, the heat transfer medium comprising a first end face, a second end face, and the channels extending between the first end face and the second end face;
supplying electrical current to the heat transfer medium positioned within the interior chamber, the interior chamber defined by a first end, a second end, and at least one sidewall extending from the first end to the second end;
converting the electrical current to heat, thereby heating the hydrocarbon-containing stream within the channels of the heat transfer medium;
converting the hydrocarbon-containing stream to an effluent within the channels of the heat transfer medium;
removing the effluent from the channels of the heat transfer medium;
introducing the effluent into a heat exchanger positioned downstream from the heat transfer medium within the interior chamber, wherein the heat exchanger houses molten salt, and the molten salt is at the first temperature;
transferring heat from the effluent to the molten salt and increasing a temperature of the molten salt to a second temperature; and
transferring the molten salt at the second temperature to the heat sink reservoir comprising the supply of molten salt.

12. The process of claim 11 , wherein a difference in temperature between a temperature of molten salt entering the heat exchanger and a temperature of effluent entering the heat exchanger is from 200° C. to 400° C.

13. The process of claim 11 , wherein a difference in temperature between a temperature of the hydrocarbon-containing stream and a temperature of the molten salt within the heater is from 5° C. to 30° C.

14. The process of claim 11 , wherein a temperature of the supply of molten salt is approximately the same as the first temperature.

15. The process of claim 11 , wherein the second temperature is greater than the first temperature.

16. The process of claim 11 , wherein the third temperature is less than the first temperature.

Assignees

• Dow Global Technologies Llc

Inventors

• Biesheuvel Cornelis
• Kamperman Wim M

Classifications

• C10G2300/4006

  Temperature · CPC title

• C10G9/00

  Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils · CPC title

• B01J2219/2401

  Reactors comprising multiple separate flow channels · CPC title

• B01J2219/00135

  Electric resistance heaters · CPC title

• B01J2219/00076

  with heat exchange elements inside the reactor · CPC title