Lithium ion battery materials recycling method

Patent metadata

Field	Value
Publication number	US-12057559-B2
Application number	US-201917287466-A
Country	US
Kind code	B2
Filing date	Oct 22, 2019
Priority date	Oct 26, 2018
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

Disclosed herein is a method of recovering lithium or sodium from an active material of a lithium or sodium ion battery. In a preferred embodiment, the method comprises a redox-targeting reaction of a used active material LiFeP04 with a redox mediator [Fe(CN) 6 ] 3− in a tank to produce lithium ions, circulating the reacted redox solution into a cell to regenerate said redox mediator and enabling said lithium ions to migrate through a membrane towards a cathode wherein said lithium ions are captured as LiOH through an electrochemical reaction.

First claim

The invention claimed is:

1. A method of recovering lithium or sodium from an active material of a lithium or sodium ion battery, respectively, the method comprising:
(a) providing an active material comprising lithium or sodium ions;
(b) adding the active material to a redox mediator solution that comprises a solvent and a redox mediator to form a redox solution comprising lithium or sodium ions in a first tank;
(c) moving the redox solution from the first tank to a redox flow cell comprising a cathode compartment, having a cathode electrode, and an anode compartment, having an anode electrode, separated by an ion selective membrane, where the cathode electrode and anode electrode are attached to a power supply and
the redox solution is subjected to an electrochemical reaction on the anode electrode, where the electrochemical reaction on the anode:
regenerates the redox mediator, which is then returned to the first tank; and enables transport of the lithium ions through the ion selective membrane into the cathode compartment, which comprises an aqueous catholyte solution as that is obtained from a second tank comprising said aqueous catholyte solution;
(d) capturing the lithium ions in the cathode compartment through an electrochemical reaction on the cathode electrode as LiOH and transferring the resulting aqueous LiOH catholyte solution to a second tank, wherein:
steps (c) and (d) can be repeated until the active material is consumed.

2. The method according to claim 1 , wherein active material is a cathodic and/or anodic active material.

3. The method according to claim 2 , wherein the cathodic active material is still attached to a cathode electrode of a dismantled sodium- or lithium-ion battery or is provided free from the cathode electrode.

4. The method according to claim 2 , wherein the cathodic active material is selected from one or more of NaFePO 4 , NaCoO 2 , more particularly, Li x FePO 4 , Li x NiCoMnO 2 , Li x CoO 2 , Li x FePO 4 , Li x NiO 0.33 Co 0.33 Al 0.33 O 2 , Li x Mn 2 O 4 , Li x Ni 0.5 Mn 1.5 O 4 , and Li x CoO 2 , where 0<x≤ 1.

5. The method according to claim 4 , wherein the cathodic active material is Li x FePO 4 .

6. The method according to claim 1 , wherein the redox mediator is selected from one or more of the group consisting of ferricyanide (M 3 Fe(CN) 6 ), ferrocyanide (M 4 Fe(CN) 6 ), ferrocene (C 10 H 10 Fe) and derivatives thereof, iodide (MI) and bromide (MBr), where in each case M is independently selected from the group consisting of Li, Na, K and NH 4 .

7. The method according to claim 6 , wherein the redox mediator is selected from one or more of the group consisting of ferricyanide (M 3 Fe(CN) 6 ), ferrocyanide (M 4 Fe(CN) 6 ), iodide (MI), and bromide (MBr), where in each case M is independently selected from the group consisting of Li, Na, K and NH 4 .

8. The method according to claim 6 , wherein the derivative of ferrocene is di(ethylsulfonic lithium) ferrocene (C 14 H 16 FeS 2 O 6 Li 2 ).

9. The method according to claim 6 , wherein the total concentration of the redox mediator present in the solvent is from 0.05 M to 1.5 M.

10. The method according to claim 2 , wherein the solvent is pure water.

11. The method according to claim 1 , wherein the aqueous catholyte solution is initially selected from one of water, water comprising oxygen, water comprising air, water comprising oxygen and CO 2 , or water comprising air and CO 2 .

12. The method according to claim 1 , wherein after steps (b) and (c) have been completed, the aqueous catholyte solution is an aqueous LiOH solution, an aqueous LiOH solution comprising oxygen, an aqueous LiOH solution comprising air, an aqueous LiOH solution comprising oxygen and CO 2 with Li 2 CO 3 precipitate, or an aqueous LiOH solution comprising air and CO 2 with Li 2 CO 3 precipitate.

13. The method according to claim 2 , wherein the anodic active material is still attached to an anode electrode of a dismantled lithium-ion battery or is provided free from the anode electrode.

14. The method according to claim 2 , wherein the anode active material is selected from one or more of Li 4 Ti 5 O 12 , Graphite, Silicon, Hard carbon.

Assignees

• Nat Univ Singapore

Inventors

• Wang Qing
• Yu Juezhi

Classifications

• C25B1/16

  Hydroxides (by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34) · CPC title

• C25B15/087

  Recycling of electrolyte to electrochemical cell · CPC title

• Y02E60/50

  Fuel cells · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• C25B9/19

  with diaphragms · CPC title