Preactive oxygen modification to form peripheral seal for vacuum insulated glazing (VIG) unit

Patent metadata

Field	Value
Publication number	US-12054983-B2
Application number	US-201917260835-A
Country	US
Kind code	B2
Filing date	Jun 21, 2019
Priority date	Jul 23, 2018
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

A method of manufacturing a vacuum insulated glazing (VIG) unit, the method comprising disposing a sealing composition around a periphery of first and second substantially parallel glass panes to define a cavity and form a pre-sealed VIG unit; flowing gas comprising a reactive oxygen species into the cavity; heating the sealing composition to a first temperature; and heating the sealing composition to a second temperature to form the peripheral seal and a sealed cavity between the first and second glass panes.

First claim

The invention claimed is:

1. A method of manufacturing a vacuum insulated glazing (VIG) unit, the method comprising:
disposing a sealing composition around a periphery of first and second substantially parallel glass panes to define a cavity and form a pre-sealed VIG unit, wherein the sealing composition comprises a glass frit and a binder;
flowing a gas comprising a reactive oxygen species into the cavity while heating the sealing composition to a first temperature, wherein the first temperature is a burnout temperature at which the binder in the sealing composition is burned off; and;
heating the sealing composition to a second temperature to form a peripheral hermetic seal and a sealed cavity between the first and second glass panes, wherein the second temperature is a melting temperature of the glass frit.

2. The method of claim 1 , wherein the second temperature is
at least 20° C. less than a second temperature that is necessary to form a comparable peripheral hermetic seal using the sealing composition, wherein the comparable peripheral hermetic seal is prepared without flowing the gas comprising the reactive oxygen species into the cavity while heating at the first temperature.

3. The method of claim 1 , wherein
the first temperature is from 150° ° C. to 360° C.; and
the second temperature is from 300° ° C. to 550° C.

4. The method of claim 1 , wherein the gas comprising the reactive oxygen species is flowed into the cavity before the sealing composition reaches a temperature of 250° C.

5. The method of claim 1 , further comprising holding the sealing composition at the first temperature from 10 minutes to 90 minutes under the flow of the gas comprising the reactive oxygen species.

6. The method of claim 1 , wherein the gas comprising the reactive oxygen species comprises a mixture of ozone and a second gas.

7. The method of claim 1 , further comprising flowing the gas comprising the reactive oxygen species into the cavity through an evacuation port on an outer surface of the first or the second glass pane.

8. The method of claim 1 , wherein the sealing composition comprises at least one of:
a metal or a metal alloy; or
less than 0.1 wt % of lead, wherein amount is based on total weight of the sealing composition.

9. The method of claim 1 , wherein the sealing composition comprises about 70 wt % of a combination of an organic binder, inorganic fillers, and solvents, wherein amount is based on total weight of the sealing composition.

10. The method of claim 1 , wherein the glass frit is a glass frit powder, wherein the glass frit powder comprises one or more of vanadium oxide, barium oxide, zinc oxide, bismuth oxide, aluminum oxide, silicon oxide, silver chloride, silver oxide, boron oxide, yttrium oxide, tin fluoride, tin oxide, strontium oxide, copper chloride, copper oxide, cerium oxide, indium oxide, magnesium oxide, chromium oxide, iron oxide, cobalt oxide, sodium oxide, manganese oxide, titanium oxide, germanium oxide, thallium oxide, tellurium oxide, tantalum oxide, molybdenum oxide, niobium oxide, tellurium oxide, an alloy thereof, or a combination thereof.

11. The method of claim 1 , wherein the sealing composition comprises two different glass frit materials, wherein each glass frit material has a different thermal expansion coefficient (CTE).

12. The method of claim 1 , wherein the sealing composition comprises a glass frit powder, wherein the sealing composition comprises 80 to 99 wt % of the glass frit powder and 0.001 to 20 wt % of the binder, wherein amounts are based on total weight of the sealing composition.

13. The method of claim 1 , further comprising disposing a plurality of pillars between the first and second glass panes.

14. The method of claim 1 , wherein at least one of the first and the second glass panes is a tempered glass pane.

15. The method of claim 1 , further comprising discontinuing the flow of the gas comprising the reactive oxygen species before heating the sealing composition to the second temperature.

16. The method of claim 1 , wherein the sealing composition is heated to the second temperature in the presence of substantially no reactive oxygen species to form the peripheral seal.

17. The method of claim 1 , further comprising baking the vacuum insulated glazing (VIG) unit at a third temperature subsequent to forming the peripheral seal.

18. The method of claim 17 , wherein the third temperature is at least 200° C.

Assignees

• Vkr Holding As

Inventors

• De Rycke Thibault
• Nielsen Karsten Hansgaard
• Johnsen Simon
• Andersen Søren Vejling

Classifications

• E06B3/6775

  Evacuating or filling the gap during assembly · CPC title

• E06B3/6733 Primary

  by applying, e.g. extruding, a ribbon of hardenable material on or between the panes · CPC title

• E06B3/6612

  Evacuated glazing units · CPC title

• Y02B80/22

  Glazing, e.g. vaccum glazing · CPC title

• Y02A30/249

  Glazing, e.g. vacuum glazing · CPC title