Two-stage process with thermal conversion

Patent metadata

Field	Value
Publication number	US-12054674-B2
Application number	US-202218083650-A
Country	US
Kind code	B2
Filing date	Dec 19, 2022
Priority date	Dec 23, 2021
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

The disclosure relates to a process for converting lignin ( 10 ) to renewable product ( 80 ), wherein the process comprises the following steps; mixing ( 100 ) lignin ( 10 ) with aqueous solution ( 20 ) to obtain a mixture ( 30 ); heating ( 110 ) the mixture ( 30 ) of step (a) to a temperature between 290 and 350° C., under a pressure from 70 to 165 bar, to obtain a first product mix ( 40 ); separating aqueous phase ( 53 ) and oil phase ( 50 ), and optionally gas ( 51 ) and solids ( 52 ), of the first product mix ( 40 ) of step (b); and heating ( 130 ) the oil phase ( 50 ) of step (c) and solvent ( 60 ) to obtain a second product mix ( 70 ). The second product mix ( 70 ) can be used as such, it can be directed to separation ( 140 ) or it can be upgraded. The obtained liquid renewable product is suitable as chemicals, fuel, fuel components or feedstock for fuel production.

First claim

The invention claimed is:

1. A process for converting lignin ( 10 ) to renewable product ( 80 ), characterized in that the process comprises the following steps,
(a) mixing ( 100 ) lignin ( 10 ) with aqueous solution ( 20 ), at atmospheric conditions or at a temperature lower than 100° C., for 1-60 minutes to obtain a mixture ( 30 );
(b) heating ( 110 ) the mixture ( 30 ) of step (a) at a temperature between 290 and 350° C., under a pressure from 70 to 165 bar, to obtain a first product mix ( 40 );
(c) separating ( 120 ) aqueous phase ( 53 ) and oil phase ( 50 ), and optionally gas ( 51 ) and/or solids ( 52 ), of the first product mix ( 40 ) of step (b); and
(d) heating ( 130 ) the oil phase ( 50 ) of step (c) and solvent ( 60 ) at a temperature between 360° C. to 450° C., under a pressure from 1 to 120 bar.

2. The process according to claim 1 , characterized in that the aqueous solution ( 20 ) in step (a) is water or recirculated aqueous phase ( 53 ).

3. The process according to claim 1 , characterized in that the amount of lignin feedstock is 2-50 wt % of the total amount of lignin and aqueous solution by weight.

4. The process according to claim 1 , characterized in that said solvent ( 60 ) in step (d) is renewable hydrocarbons, oxygen containing hydrocarbons or mixtures thereof.

5. The process according to claim 1 , characterized in that the oil phase to solvent ratio in step (d) is from 1:5 to 1.5:1 by weight.

6. The process according to claim 1 , characterized in that the pH of the aqueous phase ( 53 ) is below pH 9.

7. The process according to claim 1 , characterized in that lignin ( 10 ) is kraft lignin separated from black liquor and the lignin comprises less than 10 wt % of impurities or residues from the black liquor.

8. The process according to claim 1 , characterized in that the lignin ( 10 ) comprises 15-98 wt % organics; 0.1-15 wt % ash; and/or 1.5-80 wt % water.

9. The process according to claim 1 , characterized in that the lignin ( 10 ) comprises below 40 wt %, oxygen daf (dry-ash-free).

10. The process according to claim 1 , characterized in that step (d) ( 130 ) is followed by a step (e) ( 140 ) comprising separating aqueous phase ( 83 ), oil phase ( 80 ) and optionally gas ( 81 ) and/or solids ( 82 ) of the second product mix ( 70 ) of step (d) ( 130 ).

11. The process according to claim 10 , characterized in that the oil phase ( 50 , 80 ) comprises below 25 wt % oxygen.

12. The process according to claim 1 , characterized in that step (d) ( 130 ) is followed by fractionation ( 200 ) to obtain a light fraction ( 90 ) and a heavy fraction ( 91 ) and optionally a bottom residue fraction ( 92 ) and/or a gaseous fraction.

13. The process according to claim 10 , characterized in that step (e) ( 140 ) is followed by fractionation ( 200 ) to obtain a light fraction ( 90 ) and a heavy fraction ( 91 ) and optionally a bottom residue fraction ( 92 ) and/or a gaseous fraction.

14. The process according to claim 12 , characterized in that the light fraction ( 90 ), or part of it, is recirculated to step (d) ( 130 ) as solvent ( 60 ).

15. The process according to claim 1 , characterized in that heating ( 110 ) the mixture ( 30 ) of step (a) is performed at a temperature from 300° C. and 340° C., and/or at a pressure from 90 bar to 140 bar.

16. The process according to claim 1 , characterized in that the heating ( 130 ) the oil phase ( 50 ) of step (c) is performed at a temperature from 370° C. to 410° C. and/or at a pressure from 1 to 100 bar.

17. The process according to claim 1 , characterized in that the heating of step (b) ( 110 ) is performed for 3-60 minutes and/or of step (d) ( 130 ) is performed for 5-30 minutes.

18. The process according to claim 1 , characterized in that heat from one or more product streams is used to heat up feed streams.

19. A renewable product comprising the light fraction ( 90 ) of claim 12 .

20. The process according to claim 1 , characterized in that the amount of lignin feedstock is 5-25 wt % of the total amount of lignin and aqueous solution by weight.

21. The process according to claim 1 , characterized in that said solvent ( 60 ) in step (d) is crude tall oil.

22. The process according to claim 1 , characterized in that the pH of the aqueous phase ( 53 ) is 4 to 8.

23. The process according to claim 1 , characterized in that lignin ( 10 ) is kraft lignin separated from black liquor and the lignin comprises less than 1 wt % of impurities or residues from the black liquor.

24. The process according to claim 1 , characterized in that the lignin ( 10 ) comprises 30-70% organics; 0.1-1% ash; and/or 1.5-70 wt % water.

25. The process according to claim 1 , characterized in that the lignin ( 10 ) comprises 20 to 36 wt % oxygen daf (dry-ash-free).

26. The process according to claim 10 , characterized in that the oil phase ( 50 , 80 ) comprises below 20 wt % oxygen.

Assignees

• Upm Kymmene Corp

Inventors

• Gutierrez Andrea
• Westerhof Roel
• Kersten Sascha
• Heesink Bert
• Jokela Pekka

Classifications

• C10L2290/06

  Heat exchange, direct or indirect · CPC title

• C10L2270/026

  for diesel engines, e.g. automobiles, stationary, marine · CPC title

• C10L2200/0469

  Renewables or materials of biological origin · CPC title

• C10L1/08

  for compression ignition · CPC title

• C10G2400/08

  Jet fuel · CPC title