Ethylene-vinyl alcohol copolymer, method for producing same, and use thereof

Patent metadata

Field	Value
Publication number	US-12054645-B2
Application number	US-201917047855-A
Country	US
Kind code	B2
Filing date	Apr 16, 2019
Priority date	Apr 17, 2018
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

An ethylene-vinyl alcohol copolymer may have an ethylene unit content of 1 mol % or more and less than 20 mol %, a viscosity-average polymerization degree of 200 to 5000 and a saponification degree of 80 to 99.7 mol %. A block character of ethylene units in the ethylene-vinyl alcohol copolymer may be 0.90 to 0.99. Such an ethylene-vinyl alcohol copolymer may have excellent high-speed coating ability and water-resistant adhesiveness, particularly when being used as an adhesive.

First claim

The invention claimed is:

1. An ethylene-vinyl alcohol copolymer, comprising:
ethylene units in a content range of from 1 to less than 20 mol. %;
wherein the ethylene-vinyl alcohol copolymer has a viscosity-average polymerization degree in a range of from 200 to 5000,
wherein the ethylene-vinyl alcohol copolymer has a saponification degree in a range of from 80 to 99.7 mol %, and
wherein of the ethylene units in the ethylene-vinyl alcohol copolymer have a block character in a range of from 0.90 to 0.99.

2. An ethylene-vinyl alcohol copolymer composition, comprising:
the ethylene-vinyl alcohol copolymer of claim 1 ; and
a compound having a conjugated double bond with a molecular weight of 1000 or less,
wherein the compound is present in a range of from 0.000001 to 0.01 parts by mass, based on 100 parts by mass of the ethylene-vinyl alcohol copolymer.

3. An aqueous solution, comprising:
the ethylene-vinyl alcohol copolymer of claim 1 .

4. An adhesive, comprising:
the aqueous solution of claim 3 .

5. The adhesive of claim 4 , further comprising:
an inorganic filler.

6. The adhesive of claim 5 , wherein the inorganic filler is present in a range of from 20 to 500 parts by mass, based on 100 parts by mass of the ethylene-vinyl alcohol copolymer.

7. A method for producing the ethylene-vinyl alcohol copolymer of claim 1 , the method comprising:
(a) contacting a solution comprising a vinyl ester with an ethylene comprising gas while stirring the solution with a wide paddle blade in a polymerization tank such that an agitation power Pv per unit volume is in a range of from 0.5 to 10 kW/m 3 and a Froude number Fr is in a range of from 0.05 to 0.2, to produce an ethylene-vinyl ester copolymer.

8. The method of claim 7 , further comprising, in production of the ethylene-vinyl ester copolymer;
(b) introducing the ethylene comprising gas present in a gas-phase part in the polymerization tank, into a heat exchanger;
(c) feeding the vinyl ester to the heat exchanger;
(d) contacting the vinyl ester with the ethylene comprising gas in the heat exchanger; and
(e) discharging the vinyl ester in which ethylene is dissolved, from the heat exchanger and introducing the vinyl ester into the polymerization tank,
wherein the polymerization tank is connected to the heat exchanger via a pipe.

9. An adhesive, consisting of:
the aqueous solution of claim 3 .

10. An adhesive, consisting of:
the aqueous solution of claim 3 ;
at least one inorganic filler.

11. The ethylene-vinyl alcohol copolymer of claim 1 , wherein the ethylene-vinyl alcohol copolymer has a viscosity-average polymerization degree in a range of from 2300 to 5000.

12. The ethylene-vinyl alcohol copolymer of claim 1 , comprising the ethylene units in a content range of from 1 to 15 mol. %.

13. The ethylene-vinyl alcohol copolymer of claim 1 , comprising the ethylene units in a content range of from 2 to 15 mol. %.

14. The ethylene-vinyl alcohol copolymer of claim 1 , comprising the ethylene units in a content range of from 1 to 10 mol. %.

15. The ethylene-vinyl alcohol copolymer of claim 1 , comprising the ethylene units in a content range of from 1 to 8.5 mol. %.

16. The ethylene-vinyl alcohol copolymer of claim 1 , wherein the ethylene-vinyl alcohol copolymer has a saponification degree in a range of from 82 to 99.5 mol %.

17. The ethylene-vinyl alcohol copolymer of claim 1 , wherein the ethylene-vinyl alcohol copolymer has a saponification degree in a range of from 85 to 98.5 mol %.

18. The ethylene-vinyl alcohol copolymer of claim 1 , wherein the ethylene units in the ethylene-vinyl alcohol copolymer have a block character in a range of from 0.93 to 0.99.

19. The ethylene-vinyl alcohol copolymer of claim 1 , wherein the ethylene units in the ethylene-vinyl alcohol copolymer have a block character in a range of from 0.95 to 0.99.

20. The ethylene-vinyl alcohol copolymer of claim 1 , consisting of, in copolymerized form:
the ethylene;
at least one vinyl ester selected from the group consisting of vinyl formate, vinyl acetate, vinyl propionate, vinyl valerate, vinyl caprate, vinyl laurate, vinyl stearate, vinyl benzoate, vinyl pivalate, vinyl versatate, and a mixture thereof; and
at least one further monomer selected from the group consisting of propylene, n-butene isobutylene, acrylic acid optionally as a salt, acrylate ester, methacrylic acid optionally as a salt, methacrylate ester, acrylamide, N-methylacrylamide, N-ethylacrylamide, N,N-dimethylacrylamide, diacetone acrylamide, acrylamide propanesulfonic acid optionally as a salt, acrylamide propyldimethylamine optionally as a salt, N-methylol acrylamide, methacrylamide, N-methylmethacrylamide, N-ethylmethacrylamide, methacrylamide propanesulfonic acid optionally as a salt, methacrylamide propyldimethylamine optionally as a salt, N-methylol methacrylamide, methyl vinyl ether, ethyl vinyl ether, n-propyl vinyl ether, i-propyl vinyl ether, n-butyl vinyl ether, i-butyl vinyl ether, t-butyl vinyl ether, dodecyl vinyl ether, stearyl vinyl ether, acrylonitrile, methacrylonitrile, vinyl chloride, vinyl fluoride, vinylidene chloride, vinylidene fluoride, allyl acetate, allyl chloride, maleic acid, itaconic acid, fumaric acid, vinyltrimethoxysilane, isopropenyl acetate, and a mixture thereof.

Assignees

• Kuraray Co

Inventors

• Tanida Tatsuya
• Morikawa Keisuke
• Katayama Masako

Classifications

• C09J11/04

  inorganic · CPC title

• C08K3/346

  Clay · CPC title

• C08F216/06 Primary

  Polyvinyl alcohol {; Vinyl alcohol} · CPC title

• C09J129/04 Primary

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title

• C08F210/02

  Ethene · CPC title