Materials that resist fouling and methods for identifying same

Patent metadata

Field	Value
Publication number	US-12054639-B2
Application number	US-202217672466-A
Country	US
Kind code	B2
Filing date	Feb 15, 2022
Priority date	Oct 3, 2017
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

In general, the present invention is directed to materials that when in use resist fouling on their surfaces. Such materials may be used in the construction of various process equipment having surfaces exposed to a given fluid that contains a foulant or chemical substance that may deposit on, or adhere to, the surface and thereafter continue to grow on the surface resulting in deteriorated performance of the equipment and process. The materials are specifically selected using a method that takes into account the dielectric spectra of the fluid to which the surface is exposed and the surface itself. It has been unexpectedly found that if the dielectric spectra of the surface and the fluid are matched to within relative agreement, there should be no adhesion of the foulant on the surface. In some embodiments, the dielectric spectra to be matched include the intrinsic indexes of refraction.

First claim

What is claimed is:

1. A coating for a surface of an object to reduce adhesion of a foulant in a fluid in contact with the object, comprising:
an object having a surface and a coating on said surface; and
a fluid comprising a foulant, wherein said fluid is in contact with said coating;
wherein said coating has an index of refraction within 10% of an index of refraction of said fluid in some portion of the complete optical spectrum and wherein said coating reduces an amount of adhesion of the foulant to said surface of the object compared to an amount of adhesion of the foulant to said surface of said object without said coating.

2. The coating of claim 1 , wherein said coating reduces an initial deposition of a monolayer of particles of the foulant on said coating compared to an initial deposition of a monolayer of particles of the foulant on said surface of said object without said coating.

3. The coating of claim 1 , wherein the index of refraction of said coating is within 5% of the index of refraction of said fluid.

4. The coating of claim 1 , wherein the portion of the complete optical spectrum comprises 400-800 nm in a visible spectrum.

5. The coating of claim 1 , wherein the portion of the complete optical spectrum comprises 10-400 nm in a UV spectrum.

6. The coating of claim 1 , wherein said coating comprises a chemical selected from the group consisting of calcite, microcline or albite, olivine, pyrite, fluorite, cryolite, and muscovite.

7. The coating of claim 1 , wherein the index of refraction of said fluid has a range of 1.00 to 1.76 and the index of refraction of said surface has a range of 1.00 to 1.76.

8. The coating of claim 1 , wherein said coating is disposed on said surface of said object.

9. The coating of claim 8 , wherein said coating reduces an initial deposition of a monolayer of particles of the foulant on said coating compared to an initial deposition of a monolayer of particles of the foulant on said surface of said object without said coating.

10. The coating of claim 8 , wherein said fluid comprises water, the foulant comprises silicon dioxide, and said coating comprises a chemical selected from the group consisting of calcite, microcline or albite, olivine, pyrite, fluorite, cryolite, and muscovite.

11. The coating of claim 8 , wherein said object comprises an object used in a geothermal power plant.

12. An object in contact with a fluid having a coating to reduce adhesion of a foulant in the fluid on the surface of the object, comprising:
an object having an outer surface;
a coating disposed on at least a portion of said outer surface of said object; and
a fluid comprising a foulant in contact with said coating disposed on said at least a portion of said outer surface of said object;
wherein said coating has an index of refraction within 10% of an index of refraction of said fluid in some portion of the complete optical spectrum and wherein said coating reduces adhesion of the foulant to said outer surface of said object compared to an amount of adhesion of the foulant to said surface of said object without said coating.

13. The object of claim 12 , wherein said coating reduces an initial deposition of a monolayer of particles of the foulant on said coating.

14. The object of claim 12 , wherein the index of refraction of said coating is within 5% of the index of refraction of said fluid.

15. The object of claim 12 , wherein the portion of the complete optical spectrum comprises 400-800 nm in a visible spectrum.

16. The object of claim 12 , wherein the portion of the complete optical spectrum comprises 10-400 nm in a UV spectrum.

17. The object of claim 12 , wherein said coating comprises a chemical selected from the group consisting of calcite, microcline or albite, olivine, pyrite, fluorite, cryolite, and muscovite.

18. The object of claim 12 , wherein the index of refraction of said fluid has a range of 1.00 to 1.76 and the index of refraction of said surface has a range of 1.00 to 1.76.

19. The coating of claim 12 , wherein said object comprises an object used in a geothermal power plant.

Assignees

• Massachusetts Inst Technology

Inventors

• Short Michael P
• Carlson Max B

Classifications

• C09D5/16

  Antifouling paints; Underwater paints · CPC title

• C09D1/00

  Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances · CPC title

• F24T10/00

  Geothermal collectors · CPC title

• C09D5/00 Primary

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title