Polyurethane coated heat-shrinkable film

Patent metadata

Field	Value
Publication number	US-12054592-B2
Application number	US-201916971117-A
Country	US
Kind code	B2
Filing date	Feb 27, 2019
Priority date	Feb 28, 2018
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

A heat-shrinkable film which includes an ethylene-based polymer multilayer or monolayer film and a coating on an outer surface of the ethylene-based polymer film. The ethylene-based polymer film having a single layer or a multilayer structure formed from a first layer, a second layer, and at least one inner layer between the first and second layers. The coating including polyurethane which is the polymerized reaction product of: a polyol; and an aromatic isocyanate functional prepolymer. Further, a method of unitizing polymer wrapped primary packages is provided. The method includes wrapping one or more of the primary packages with the heat-shrinkable film with the coating disposed proximal the one or more primary packages and applying thermal energy to reduce the dimensions of the heat-shrinkable film to constrain the primary package within the heat-shrinkable film. The coating serving to alleviate sticking between the heat-shrinkable film and the polymer wrapped primary package.

First claim

The invention claimed is:

1. A heat-shrinkable film having a monolayer structure comprising:
(a) a monolayer film comprising from 30 to 60 percent by weight of an ethylene-based polymer, where the ethylene-based polymer has a density of 0.905 to 0.930 g/cm 3 , a melt index (I 2 ) of 0.1 to 0.9 g/10 min when measured according to ASTM D 1238 at 190° C. and 2.16 kg load; and a peak melting point of less than 126° C. as measured using Differential Scanning Calorimetry (DSC);
(b) a coating on an outer surface of the monolayer film comprising:
polyurethane which is the polymerized reaction product of: (a) a hydroxyl terminated polyol; and (b) an aromatic isocyanate functional prepolymer; and
an anti-adhesion package comprising one or more oils, one or more waxes, or both.

2. The heat-shrinkable film of claim 1 , wherein the monolayer film comprises:
from 40 to 60 percent by weight ethylene-based polymer having a density of 0.910 to 0.930 g/cm 3 and a melt index (I 2 ) measured according to ASTM D 1238 of 0.2 to 0.3 g/10 min;
from 20 to 40 percent by weight ethylene-based polymer having a density of 0.910 to 0.930 g/cm 3 and a melt index (I 2 ) of 0.9 to 1.1 g/10 min; and
from 10 to 30 percent by weight ethylene-based polymer having a density of 0.940 to 0.960 g/cm 3 and a melt index (I 2 ) of 0.85 to 1.05 g/10 min.

3. The heat-shrinkable film of claim 1 , wherein the hydroxyl terminated polyol comprises a hydroxyl terminated polyether polyol, a hydroxyl terminated polyester polyol, or combinations thereof.

4. The heat-shrinkable film of claim 1 , wherein the aromatic isocyanate functional prepolymer comprises toluene diisocyanate, methyldiphenyl diisocyanate, or combinations thereof.

5. The heat-shrinkable film of claim 1 , wherein the heat-shrinkable film is a blown film.

6. The heat-shrinkable film of claim 1 , wherein the coating is applied in accordance with a defined pattern of coated and uncoated regions on the outer surface.

7. A packaging assembly comprising:
a plurality of packages, wherein each package comprises a plurality of items bundled together by a primary packaging film comprised of polymeric material, where the primary packaging film is wrapped around the plurality of items to form a primary package; and
a secondary packaging film used to bundle the plurality of packages, wherein the secondary packaging film comprises a heat-shrinkable film comprising
(a) a monolayer film comprising from 30 to 60 percent by weight of an ethylene-based polymer, where the ethylene-based polymer has a density of 0.905 to 0.930 g/cm 3 , a melt index (I 2 ) of 0.1 to 0.9 g/10 min when measured according to ASTM D 1238 at 190° C. and 2.16 kg load; and a peak melting point of less than 126° C. as measured using Differential Scanning Calorimetry (DSC); and
(b) a coating on an outer surface of the monolayer film comprising:
polyurethane which is the polymerized reaction product of:
(a) a hydroxyl terminated polyol; and (b) an aromatic isocyanate functional prepolymer; and  an anti-adhesion package comprising one or more oils, one or more waxes, or both.

8. d) A method of unitizing polymer wrapped primary packages, the method comprising:
wrapping one or more of the primary packages with a heat-shrinkable film; and
applying thermal energy to reduce the dimensions of the heat-shrinkable film to constrain the primary package within the heat-shrinkable film;
wherein the heat-shrinkable film comprises
(a) a monolayer film comprising from 30 to 60 percent by weight of an ethylene-based polymer, where the ethylene-based polymer has a density of 0.905 to 0.930 g/cm 3 , a melt index (I 2 ) of 0.1 to 0.9 g/10 min when measured according to ASTM D 1238 at 190° C. and 2.16 kg load; and a peak melting point of less than 126° C. as measured using Differential Scanning Calorimetry (DSC); and
(b) a coating on an outer surface of the monolayer film comprising:
polyurethane which is the polymerized reaction product of:
(a) a hydroxyl terminated polyol; and (b) an aromatic isocyanate functional prepolymer; and  an anti-adhesion package comprising one or more oils, one or more waxes, or both.

Assignees

• Dow Global Technologies Llc
• Pbb Polisur Srl
• Rohm & Haas

Inventors

• Do Valle Camila
• Casarubias Juan Carlos
• Zanetti Maximiliano
• De Oliveira Marlos Giuntini
• Gomes Jorge Caminero

Classifications

• C08J2375/08

  from polyethers · CPC title

• C08J2375/06

  from polyesters · CPC title

• C08G2150/00

  Compositions for coatings · CPC title

• C08G18/7657

  containing two or more aromatic rings · CPC title

• C08G18/7621

  being toluene diisocyanate including isomer mixtures · CPC title