Method for preparing granular polycarbonate

Patent metadata

Field	Value
Publication number	US-12054583-B2
Application number	US-202017413285-A
Country	US
Kind code	B2
Filing date	Jan 16, 2020
Priority date	Jan 18, 2019
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

A method for preparing granular polycarbonate particles is disclosed herein. In some embodiments, a method for preparing granulated polycarbonate particles includes mixing a polymerization reaction solution comprising polycarbonate and an organic solvent, and an anti-solvent solution comprising water and an anti-solvent to prepare a mixed solution, heating the mixed solution to remove the organic solvent, and drying or filtering the mixed solution to obtain granular polycarbonate particles. The granular polycarbonate particles having excellent physical properties without using a stabilizer or a surfactant can be obtain.

First claim

What is claimed is:

1. A method for preparing granulated polycarbonate particles, comprising:
mixing a polymerization reaction solution comprising polycarbonate and an organic solvent, and an anti-solvent solution consisting of water and an anti-solvent to prepare a mixed solution;
heating the mixed solution to remove the organic solvent; and
drying or filtering the mixed solution to obtain granular polycarbonate particles,
wherein the anti-solvent satisfies all of the following Equations 1 to 3,
11.8<Ra<14.1  [Equation 1]

in Equation 1, Ra is a Hansen Solubility Parameter (HSP) of an anti-solvent for polycarbonate;
−0.88<Δμ<1.95  [Equation 2]

in Equation 2, Δμ is a mixing energy of an anti-solvent and polycarbonate;
Δμ′<4.0  [Equation 3]

in Equation 3, Δμ′ is a mixing energy of the anti-solvent and water,
wherein the anti-solvent comprises one or more of acetonitrile, (e)-2-butenenitrile, 2-hydroxy-2-methylpropanenitrile, 2,2,2-trifluoroethanol, 2-methyl-1-butanol, 2-mercaptoethanol, o-methylhydroxylamine, 2-hydroxy-2-methylpropanenitrile, tert-butyl hydroperoxide, 2-aminopropanol, 1-amino-2-propanol, propionic acid, 2-2′-(methylimino)bis ethanol, 2-chloroethanol, 1,2-diaminoethane, 2-propen-1-ol, 4-methyl-2-pentanol, 2-(2-aminoethyl)aminoethanol, 1-hydroxy-2-propanone, pyruvic acid, n,n-bis(2-hydroxyethyl)ethylamine, 3-amino-1-propanol, 1,1,1-trifluoro-2-propanol, pinacolyl alcohol, propargylic acid), dimethoxy dimethylsilane, 3-methoxy-1-butanol, ethyl hydroperoxide, and n-ethyl-n-hydroxyethanamine.

2. The method according to claim 1 , wherein the anti-solvent is acetonitrile, 2-propen-1-ol, or 2-chloroethanol.

3. The method according to claim 1 , wherein the anti-solvent solution and the polymerization reaction solution are mixed in a weight ratio of 2:8 to 5:5.

4. The method according to claim 1 , wherein the anti-solvent solution includes 5 to 40% by weight of the anti-solvent based on the total weight of the anti-solvent solution.

5. The method according to claim 1 , wherein the organic solvent includes methylene chloride.

6. The method according to claim 1 , wherein the mixed solution is heated to a temperature ranging from 40° C. to 70° C.

7. The method according to claim 1 , wherein the mixed solution is dried at a temperature ranging from 80° C. to 150° C.

8. The method according to claim 1 , wherein the granular polycarbonate particles have a bulk density of 0.40 to 0.70 g/cm 3 in accordance with ASTM D1895.

9. The method according to claim 1 , wherein the granular polycarbonate particles have an average particle size of 0.3 to 10 mm.

10. The method according to claim 1 , wherein, upon heating the mixed solution, the organic solvent contained in the polycarbonate polymerization reaction solution was removed in an amount of 80 to 90% by weight based on the initial weight of the polycarbonate reaction polymerization solution.

11. The method according to claim 1 , wherein a standard deviation of the particle size of the granular polycarbonate particles is 0.26 mm or less.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Hyunju
• Kim Hyeon Hui
• Choe Jae Hoon
• Hong Mooho
• Lee Ki Jae
• Jee Soyeon

Classifications

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• C08J3/12

  Powdering or granulating · CPC title

• C08J3/096

  Nitrogen containing compounds · CPC title

• C08J3/095

  Oxygen containing compounds · CPC title

• C08G64/40

  Post-polymerisation treatment · CPC title