Method and system for preparing xanthate by slurry method

Patent metadata

Field	Value
Publication number	US-12054452-B2
Application number	US-202017005324-A
Country	US
Kind code	B2
Filing date	Aug 28, 2020
Priority date	Aug 7, 2018
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

A method for preparing xanthate by a slurry method includes steps of: adding a mixture of dichloromethane and carbon disulfide as a reaction solvent in a slurry reactor, and then adding alcohol and caustic alkali to react with carbon disulfide under less than 1 atm to remove heat released by the reaction by evaporating the solvent; performing vacuum distillation after the reaction to remove the solvent and water, so as to obtain the xanthate; transporting the xanthate to a granulation equipment for granulating, and then drying in a drying equipment to obtain a product. The method is performed in a system formed by a reaction equipment, a solvent recovery equipment, the granulation equipment, and the drying equipment, wherein a main equipment of the reaction system is a slurry reactor. The method has advantages of high efficiency, low energy consumption, good safety, environmental friendliness, convenient operation and the like.

First claim

What is claimed is:

1. A method for preparing powdered xanthate by a slurry method, comprising steps of:
1) adding dichloromethane and carbon disulfide into a slurry reactor and mixing through stirring, then adding an alcohol and an alkali and stirring for reaction; wherein the alcohol is C 2 -C 12 fatty alcohol selected from the group consisting of ethanol, n-propanol, isopropanol, n-butanol, isobutanol, amyl alcohol, isoamyl alcohol, neopentyl alcohol, n-hexanol, isohexanol, methyl isobutyl carbinol, n-octanol, isooctyl alcohol, and dodecanol; the alkali is selected from sodium hydroxide and potassium hydroxide, in shape of powder, granule or flake;
2) turning on a vacuum pump to adjust a system pressure when a temperature of a reaction system begins to rise, so as to control the temperature of the reaction system and recover a solvent; and
3) injecting hot water or steam into a heating jacket of the slurry reactor after the solvent is recovered, so as to accelerate removal of the solvent and obtain powdered xanthate.

2. The method, as recited in claim 1 , further comprising a step of: transferring the powdered xanthate to a granulation equipment for granulation; drying and dehydrating granules obtained by granulation to obtain granular xanthate.

3. The method, as recited in claim 1 , wherein in the step 1), 2-tert-butoxyethanol is also added.

4. The method, as recited in claim 1 , wherein a molar ratio of the alcohol, the alkali and the carbon disulfide is 1:1-1.05:1-3, and a volume of the dichloromethane is 0.5-5 times a volume of the alcohol.

5. The method, as recited in claim 1 , wherein in the step 2), the system pressure is controlled at −0.01-0.081 MPa; and the temperature of the reaction system is maintained at 10-80° C.

6. The method, as recited in claim 1 , wherein the reaction lasts for 0.5-6h.

Assignees

• Univ Central South

Inventors

• Zhong Hong
• Ma Xin
• Wang Shuai

Classifications

• B03D2203/02

  Ores · CPC title

• B03D2201/02

  Collectors · CPC title

• B03D2201/007

  Modifying reagents for adjusting pH or conductivity · CPC title

• B03D1/14

  Flotation machines (devices for feeding measured quantities of reagents B01J4/02; flotation apparatus for enzymology or microbiology C12M1/09) · CPC title

• B03D1/002 Primary

  Inorganic compounds · CPC title