Resin for production of porous ceramic stereolithography and methods of its use

Patent metadata

Field	Value
Publication number	US-12054437-B2
Application number	US-202117545475-A
Country	US
Kind code	B2
Filing date	Dec 8, 2021
Priority date	Jun 27, 2017
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

A ceramic resin is provided, along with its methods of formation and use. The ceramic resin may include a crosslinkable precursor, a photoinitiator, ceramic particles, and pore forming particles. The ceramic resin may be utilized to form a ceramic casting element, such as via a method that includes forming a layer of the ceramic resin; applying light onto the ceramic resin such that the photoinitiator initiates polymerization of the crosslinkable precursor to form a crosslinked polymeric matrix setting the ceramic particles and the pore forming particles; and thereafter, heating the crosslinked polymeric matrix to a first temperature to burn out the pore forming particles.

First claim

What is claimed is:

1. A ceramic resin, comprising:
a crosslinkable precursor;
a photoinitiator;
ceramic particles, wherein the ceramic particles comprise 50% to 90% by volume of the ceramic resin; and
pore forming particles, wherein the photoinitiator is a UV photoinitiator that is configured to initiate polymerization of the crosslinkable precursor upon exposure to UV light at a temperature below 50° C. to form a crosslinked polymeric matrix setting the ceramic particles and the pore forming particles.

2. The ceramic resin of claim 1 , wherein the pore forming particles comprise 0.1% to 25% by volume of the ceramic resin.

3. The ceramic resin of claim 1 , wherein the pore forming particles comprise 10% to 25% by volume of the ceramic resin.

4. The ceramic resin of claim 1 , wherein the pore forming particles comprise a material that becomes gaseous within a temperature range of 70° C. to 250° C.

5. The ceramic resin of claim 4 , wherein the pore forming particles comprise an organic material that comprises naphthalene, a naphthalene-related compound, an epoxy, an acrylic, cellulose, polyvinyl alcohol, aluminum acetylacetonate, or a mixture thereof.

6. The ceramic resin of claim 1 , wherein the pore forming particles have an average diameter of 1 μm to 100 μm.

7. The ceramic resin of claim 1 , wherein the crosslinkable precursor comprises an acrylic precursor, an epoxy precursor, cellulose, polyvinyl alcohol, or a mixture thereof.

8. The ceramic resin of claim 1 , wherein the crosslinkable precursor comprises 5% to 75% by volume of the ceramic resin.

9. The ceramic resin of claim 1 , wherein the photoinitiator comprises 0.1% to 4% by volume of the ceramic resin.

10. The ceramic resin of claim 1 , wherein the photoinitiator cures the crosslinkable precursor upon exposure to electromagnetic radiation to form the crosslinked polymeric matrix having a burnout temperature that is 250° C. to 500° C.

11. A method of forming a ceramic casting element, the method comprising:
forming a layer of a ceramic resin, wherein the ceramic resin comprises a crosslinkable precursor, a photoinitiator, ceramic particles, and pore forming particles, wherein the ceramic particles comprise 50% to 90% by volume of the ceramic resin, and wherein the photoinitiator is a UV photoinitiator that is configured to initiate polymerization of the crosslinkable precursor upon exposure to UV light at a temperature below 50° C. to form a crosslinked polymeric matrix setting the ceramic particles and the pore forming particles;
applying light onto the ceramic resin such that the photoinitiator initiates polymerization of the crosslinkable precursor to form the crosslinked polymeric matrix setting the ceramic particles and the pore forming particles; and
thereafter, heating the crosslinked polymeric matrix to a first temperature to burn out the pore forming particles.

12. The method of claim 11 , wherein the first temperature is 125° C. to 250° C. such that the pore forming particles vaporize to form voids in the crosslinked polymeric matrix.

13. The method of claim 11 , wherein the pore forming particles comprise an organic material.

14. The method of claim 11 , wherein, after heating the crosslinked polymeric matrix to the first temperature, the crosslinked polymeric matrix has a porosity corresponding to the volume of the pore forming particles within the ceramic resin.

15. The method of claim 11 , further comprising:
after heating the crosslinked polymeric matrix to the first temperature, heating the crosslinked polymeric matrix to a second temperature to burn out the crosslinked polymeric matrix leaving a sintered ceramic core.

16. The method of claim 15 , wherein the second temperature is greater than the first temperature, and wherein the second temperature is 250° C. to 500° C.

17. The method of claim 11 , wherein the crosslinkable precursor comprises 5% to 75% by volume of the ceramic resin.

18. A method of investment casting a component, the method comprising:
casting the component within a ceramic shell that includes the sintered ceramic core of claim 15 .

19. The method of claim 18 , wherein the component is cast by solidifying molten metal in the ceramic shell such that the sintered ceramic core defines voids within the component.

20. The method of claim 18 , further comprising:
removing the ceramic shell and the sintered ceramic core from the component.

Assignees

• Gen Electric

Inventors

• Gold Scott Alan

Classifications

• C08J2333/04

  esters · CPC title

• C08J2201/026

  Crosslinking before of after foaming · CPC title

• C08J2363/00

  Characterised by the use of epoxy resins; Derivatives of epoxy resins · CPC title

• C04B38/062

  the burned-out substance being formed in situ, e.g. by polymerisation of a prepolymer composition containing ceramic powder · CPC title

• C08J9/0066

  Use of inorganic compounding ingredients · CPC title