Activated carbon molded article

Patent metadata

Field	Value
Publication number	US-12054397-B2
Application number	US-201816957412-A
Country	US
Kind code	B2
Filing date	Dec 14, 2018
Priority date	Dec 27, 2017
Publication date	Aug 6, 2024
Grant date	Aug 6, 2024

Abstract

To provide an activated carbon molded article which can satisfactorily adsorb an evaporated fuel emitted from an automobile and can achieve low evaporated fuel emission performance during the long-time parking of an automobile.
An activated carbon molded article having a specific surface area per volume, which is calculated from a specific surface area determined by the BET multipoint method and a packing density determined in accordance with JIS K 1474, of 290 to 520 m 2 /mL, and also having an outer surface area per volume of 1.4 m 2 /L or more.

First claim

The invention claimed is:

1. An activated carbon molded article, having
a pillar structure,
a specific surface area per volume, calculated from a specific surface area determined by a BET multipoint method and a packing density determined in accordance with JIS K 1474, in a range of from 290 to 520 m 2 /mL, and
an outer surface area per volume in a range of from 1.4 m 2 /L or more,
wherein the pillar structure has a pillar axis direction corresponding to a longest dimension of pillar structure,
wherein the pillar structure comprises: (i) a pillar peripheral wall comprising, in an inside thereof, a first hollow part opening at a first end in the pillar axis direction and a second hollow part opening at a second end in the pillar axis direction; and (ii) a partition wall extending from the first to the second hollow part opening, to divide the hollow part into compartments, and
wherein a void-to-wall ratio, of an area of a void space part to an area of a wall part in a pillar cross section, to which the pillar axis direction is orthogonal, is in a range of from 20 to 50%.

2. The article of claw 1 , wherein the pillar structure comprises the partition wall, as a first partition wall and further comprises a second partition wall,
wherein the partition walls are connected to the pillar peripheral wall, and
wherein the partition walls are not connected to each other.

3. The article of claim 1 , comprising one, two, or three of the partition wall, the partition walls each having a first and a second end, and
wherein each of the one, two, or three partition walls is connected, at both ends thereof, to the pills peripheral wall.

4. The article of claim 1 , comprising a plurality of the partition wall, which are connected to each other at a position located on the pillar peripheral wall to form the triangular shape.

5. The article of claim 1 , comprising a plurality of the partition wall, wherein the plurality comprises an inner wall, a first connecting wall, and a second connecting wall.

6. The article of claim 5 , when, in the pillar cross section, the inner wall has a circular shape, an elliptical shape, a triangular shape, or a quadrangular shape.

7. The article of claim 1 , wherein thickness of the partition wall varies in a range of from −5% to +5% of a median thickness of the partition wall.

8. The article of claim 1 , wherein a thickness of the pillar peripheral wall varies in range of from −5% to +5% of a median value of the thickness of the pillar peripheral wall.

9. The article of class 1 , wherein, in the pillar cross section, a difference between a thickness of the partition wall and a thickness of the pillar peripheral wall is 5% or less of a longest outer dimension a of the pillar cross section.

10. The article of claw 1 , wherein cross-sectional shapes of the pillar structure observed in the pillar axis direction are identical to each other.

11. The article of claim 1 , wherein, in the pillar cross section, each thickness of the pillar peripheral wall and each thickness of the partition wall is in a range of from 5 to 35% of a longest outer dimension of the pillar cross section.

12. The article of claim 1 , wherein each thickness of the pillar peripheral wall and each thickness of the partition wall is in a range of from 0.3 to 1.0 mm.

13. The article of claim 1 , wherein a void-to-wall ratio, of an area of a void space part to an area of a wall part in the pillar cross section, is in a range of from 20 to 50%.

14. The article of claim 1 , wherein & longest outer dimension of the pillar cross section is in a range of from 3 to 9 mm.

15. The article of claim 1 , having an average pore diameter, determined by the HK method, in a range of from 2.1 to 2.6 mm.

16. The article of claim 1 , having a butane working capacity, determined in accordance with ASTM D5228, in a range of from 8.0 to 10 g/dL.

17. The article of claim 1 , having a pore volume, determined by the BJH method, is a range of from 0.480 to 0.555 mL/g.

18. The article of claim 1 , comprising a plurality of the partition wall, which are connected to each other at a position located on the pillar peripheral wall to form a quadrangular cross-sectional shape.

19. The article of claim 1 , comprising a plurality of the partition wall, which are connected to each other at a position located on the pillar peripheral wall to form a pentagonal cross-sectional shape.

20. The article of claim 1 , comprising a plurality of the partition wall comprising an inner wall, a first connecting wall, a second connecting wall, and a third Connecting wall.

21. A canister, comprising
the activated carbon molded article of claim 1 .

22. A method for producing the activated carbon molded article of claim 1 , the method comprising:
maxing powdery or granular activated carbon, a lubricant, and a solid diluent that is soluble in an acid together to prepare a mixture;
kneading the mixture with a binder and water to prepare kneaded product, and then molding the kneaded product into a desired shape to prepare a molded article; and
drying the molded article, then washing the dried molded article with the acid to elute and remove at least a portion of the sold diluent to prepare a resultant product, and then drying be resultant product.

Assignees

• Kuraray Co

Inventors

• Yamamoto Takaharu
• Nishita Mitsunori
• Hitomi Mitsunori
• Yamada Takayuki

Classifications

• F02M25/0854

  Details of the absorption canister · CPC title

• C01P2006/16

  Pore diameter · CPC title

• C01P2006/14

  Pore volume · CPC title

• C01P2006/12

  Surface area · CPC title

• C01P2004/12

  with a cylindrical shape · CPC title