Carbon fiber crystal orientation improvement by polymer modification, fiber stretching and oxidation for brake application

Patent metadata

Field	Value
Publication number	US-12049934-B2
Application number	US-201815936195-A
Country	US
Kind code	B2
Filing date	Mar 26, 2018
Priority date	Mar 26, 2018
Publication date	Jul 30, 2024
Grant date	Jul 30, 2024

Abstract

A method of making carbon fiber material according to various embodiments of the present disclosure includes forming a polymer resin to have a polydispersity index (PDI) that is less than approximately 2.5. The method further includes spinning the polymer resin to create an acrylic fiber having an acrylic fiber length. The method further includes oxidizing the acrylic fiber while stretching the acrylic fiber to create an oxidized fiber that has an oxidized fiber length that is at least one of greater than or equal to approximately 100 percent (100%) of the acrylic fiber length. The method further includes carbonizing the oxidized fiber to create a carbon fiber.

First claim

What is claimed is:

1. A method of making carbon fiber material having a carbon fiber crystal orientation of 80% or greater for use in friction disks, the method comprising:
spinning a polymer resin to create an acrylic fiber having an acrylic fiber length, wherein the polymer resin has a polydispersity index (PDI) of less than 2.5 and comprises all polymer chain lengths greater than 5,000 units;
oxidizing the acrylic fiber while stretching the acrylic fiber to create an oxidized fiber that has an oxidized fiber length that is greater than or equal to approximately 100 percent (100%) of the acrylic fiber length;
determining a stabilization degree of the oxidized fiber, wherein the stabilization degree is determined by calculating a cyclization index that is a quotient of a total amount of exothermal heat of the oxidized fiber divided by a total amount of exothermal heat of the acrylic fiber;
responsive to the oxidized fiber having a cyclization index of at least 0.65, carbonizing the oxidized fiber to create a carbon fiber; and
graphitizing the carbon fiber.

2. The method of claim 1 , wherein stretching the acrylic fiber includes stretching the acrylic fiber such that the oxidized fiber length is greater than approximately 100% and less than or equal to approximately 120% of the acrylic fiber length.

3. The method of claim 2 , wherein stretching the acrylic fiber includes stretching the acrylic fiber such that the oxidized fiber length is greater than or equal to approximately 105% and less than or equal to approximately 120% of the acrylic fiber length.

4. The method of claim 1 , wherein the polymer resin has a molecular weight that is greater than approximately 200,000 grams per mole.

5. The method of claim 1 , wherein oxidizing the acrylic fiber includes oxidizing the acrylic fiber to have a cyclization index that is greater than or equal to 0.65.

6. A method of making carbon fiber material for use in friction disks, comprising:
spinning a polymer resin to create an acrylic fiber, wherein the polymer resin has a polydispersity index (PDI) of less than 2.5 and comprises all polymer chain lengths greater than 5,000 units;
oxidizing the acrylic fiber to create an oxidized fiber;
determining a stabilization degree of the oxidized fiber, wherein the stabilization degree is determined by calculating a cyclization index that is a quotient of a total amount of exothermal heat of the oxidized fiber divided by a total amount of exothermal heat of the acrylic fiber;
responsive to the oxidized fiber having a cyclization index of at least 0.65, carbonizing the oxidized fiber to create a carbon fiber; and
graphitizing the carbon fiber, wherein after graphitizing the carbon fiber has a crystal orientation of 80% or greater.

7. The method of claim 6 , wherein a molecular weight of the polymer resin is greater than approximately 200,000 grams per mole.

8. The method of claim 6 , wherein the polymer resin includes polyacrylonitrile.

9. The method of claim 6 , further comprising stretching the acrylic fiber during the oxidizing to cause the oxidized fiber to have an oxidized fiber length that is greater than or equal to approximately 100 percent (100%) of an acrylic fiber length of the acrylic fiber.

10. The method of claim 9 , wherein stretching the acrylic fiber includes stretching the acrylic fiber such that the oxidized fiber length is greater than or equal to approximately 100% and less than or equal to approximately 120% of the acrylic fiber length.

11. The method of claim 10 , wherein stretching the acrylic fiber includes stretching the acrylic fiber such that the oxidized fiber length is greater than or equal to approximately 105% and less than or equal to approximately 120% of the acrylic fiber length.

Assignees

• Goodrich Corp

Inventors

• Lu Weiming
• Linck John

Classifications

• D01F6/18

  from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide · CPC title

• D01F9/22 Primary

  from polyacrylonitriles · CPC title

• F16D2200/0082

  Production methods therefor · CPC title

• F16D2200/0069

  being characterised by their size · CPC title

• F16D2200/0052

  Carbon · CPC title