Acid wash of red mud (bauxite residue)

Patent metadata

Field	Value
Publication number	US-12049409-B2
Application number	US-202117547557-A
Country	US
Kind code	B2
Filing date	Dec 10, 2021
Priority date	Dec 10, 2020
Publication date	Jul 30, 2024
Grant date	Jul 30, 2024

Abstract

Bauxite residue recovery includes mixing a solution of hydrochloric acid (HCL) according to a predetermined concentration, and adding the HCL solution to a quantity of raw red mud recovered from industrial operations as waste material. The highly alkaline property of the bauxite residue, commonly known as red mud is at least partially neutralized from the HCL, and makes the resulting washed red mud more amenable to subsequent uses in various applications in fields such as construction, wastewater treatment, and metal recovery processes. The process recovers washed red mud from the red mud and HCL solution by filtering the raw red mud and HCL solution for generating a stream of leach liquor from the filtrate and the recovered washed red mud from the residue.

First claim

What is claimed is:

1. A method for recovering and recycling bauxite residue to form magnetite, comprising:
mixing an acid wash solution according to a predetermined concentration;
neutralizing a quantity of bauxite residue recovered from industrial operations as waste material by combining and washing the bauxite residue with the acid wash solution;
recovering neutralized bauxite residue from the bauxite residue and the acid wash solution, the neutralized bauxite residue having a pH<7.0;
generating a leach solution including the neutralized bauxite residue and a leach agent, the leach agent having a concentration based on an iron content in the neutralized bauxite residue;
forming a slurry from the leach solution and filtering the slurry to generate a leach liquor and a solid residue of washed bauxite residue;
separating a leach liquor from the slurry;
directing UV (ultraviolet light) at the leach liquor for photochemical reduction;
precipitating the iron in a form of ferrous oxalate via photochemical reduction;
filtering the ferrous oxalate to form a magnetite precursor; and

decomposing the magnetite precursor in an inert atmosphere heated to around 500° C. for around 1 hour to form magnetite.

2. The method of claim 1 , further comprising filtering the bauxite residue from the acid wash solution using filtration for particle sizes between 10 and 1 microns.

3. The method of claim 1 , further comprising:
forming the bauxite residue and the acid wash solution with a pulp density of between 10-15% of the bauxite residue; and
washing the bauxite residue with the acid wash solution for a duration between 10-15 minutes.

4. The method of claim 1 , wherein the bauxite residue has a pH greater than 10.0 and the washed bauxite residue has a pH around 6.0.

5. The method of claim 1 , further comprising:
mixing the acid wash solution using at least one of hydrochloric or sulfuric acid.

6. The method of claim 1 , wherein the leach agent is oxalic acid having a concentration between 1.5 and 2.5 molar, further comprising leaching the slurry at around 95° C. for between 2 and 3 hours.

7. The method of claim 1 , wherein the leach liquor includes titanium at a concentration of at least 400 ppm.

8. The method of claim 1 , wherein the UV light has a wavelength between 250-500 nm.

9. The method of claim 1 , further comprising receiving the bauxite residue as a byproduct of an aluminum production process.

Assignees

• Worcester Polytech Inst

Inventors

• Tanvar Himanshu
• Mishra Brajendra

Classifications

• C01F7/066 Primary

  Treatment of the separated residue · CPC title

• Y02P10/20

  Recycling · CPC title

• C01G49/08

  Ferroso-ferric oxide [Fe3O4] · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01F7/0653 Primary

  characterised by the flocculant added to the slurry (final clarification of the aluminate solution C01F7/47) · CPC title