Corrosion-resistant coolant salt and method for making same

Patent metadata

Field	Value
Publication number	US-12049408-B2
Application number	US-201916571414-A
Country	US
Kind code	B2
Filing date	Sep 16, 2019
Priority date	Sep 14, 2018
Publication date	Jul 30, 2024
Grant date	Jul 30, 2024

Abstract

This document describes a method for reducing the corrosivity of certain magnesium salts. The salt product resulting from the method exhibits reduced corrosion of steels that come into contact with the salt relative to salt compositions that are not so treated. This makes such treated salts more efficient coolant salts as they will require less equipment replacement over time. The method uses magnesium metal to reduce unwanted impurities in the salts the reduced impurities are then removed as either gas or precipitate from the now purified salt. Without being bound to one particular theory, it is believed that the reduction of the level of impurities in the salt results in a salt with substantially reduced corrosiveness to steel.

First claim

What is claimed is:

1. A method for removing at least one impurity from a NaCl—MgCl 2 salt, the method comprising:
combining the NaCl—MgCl 2 salt containing the at least one impurity with solid Mg metal in a vessel at a first temperature to obtain a salt-Mg combination, the first temperature being below a melting point of the solid Mg metal;
heating the salt-Mg combination in the vessel to a second temperature above a melting point of the NaCl—MgCl 2 salt and the melting point of the solid Mg metal to obtain a liquid salt-Mg mixture containing at least one reacted impurity, the second temperature being up to 800° C.;
cooling the liquid salt-Mg mixture in the vessel to a third temperature below the melting point of the solid Mg metal but above the melting point of NaCl—MgCl 2 salt to obtain a) a precipitate containing the at least one reacted impurity and any excess Mg and b) a liquid phase Mg-reduced NaCl—MgCl 2 salt; and
removing the liquid phase Mg-reduced NaCl—MgCl 2 salt from the vessel.

2. The method of claim 1 , wherein the combining comprises:
mixing, in the vessel at the first temperature, solid Mg metal with solid NaCl—MgCl 2 salt to obtain a solid salt and Mg composition, wherein the first temperature is below the melting point of NaCl—MgCl 2 salt.

3. The method of claim 1 , wherein the mixing combining comprises:
mixing, in the vessel at the first temperature, solid Mg metal and a liquid NaCl—MgCl 2 salt to obtain a salt and Mg composition.

4. The method of claim 1 , wherein the combining further comprises:
agitating the salt-Mg combination while maintaining the temperature of the salt-Mg mixture above the melting point of the NaCl—MgCl 2 salt and below the melting point of the solid Mg metal.

5. The method of claim 1 , wherein the at least one impurity includes one or more impurities selected from water, Fe, FeCl 3 , Cr, CrCl 3 , Ni, NiCl 3 , Cu, CuCl 3 , V, VCl 3 , Ti, TiCl 3 , Mn, MnCl 2 , Mo, MoCl 3 , Zn, and ZnCl 2 .

6. The method of claim 1 , further comprising:
obtaining NaCl and MgCl 2 ; and
mixing the NaCl and MgCl 2 to obtain the NaCl—MgCl 2 salt containing at least one impurity.

7. The method of claim 1 further comprising:
determining a reaction threshold;
monitoring a parameter indicative of a reaction between Mg and the at least one impurity; and
maintaining the salt-Mg mixture at the temperature above the melting point of the NaCl—MgCl 2 salt and below the melting point of the Mg metal for a period of time selected based on a comparison of the monitored parameter and the threshold.

8. The method of claim 7 wherein the parameter is generation of HCl from the salt-Mg mixture.

9. The method of claim 7 , wherein the parameter is time spent at the temperature above the melting point of the NaCl—MgCl 2 salt and below the melting point of the Mg metal.

10. The method of claim 1 , wherein the removing the liquid phase Mg-reduced NaCl—MgCl 2 salt from the vessel comprises:
filtering the liquid phase Mg-reduced NaCl—MgCl 2 salt.

11. The method of claim 1 , wherein the removing the liquid phase Mg-reduced NaCl—MgCl 2 salt from the vessel comprises:
separating the precipitate from the liquid phase Mg-reduced NaCl—MgCl 2 salt.

12. The method of claim 4 , wherein heating the salt-Mg combination in the vessel to the second temperature further comprises:
agitating the liquid salt-Mg mixture in the vessel after heating to the second temperature.

13. The method of claim 12 , wherein the agitating comprises:
sparging an inert gas through the liquid salt-Mg mixture in the vessel.

14. The method of claim 1 wherein the NaCl—MgCl 2 salt has less than 100 mg/kg of impurities.

15. The method of claim 1 , wherein the NaCl—MgCl 2 salt has less than 50 mg/kg of impurities.

Assignees

• Terrapower Llc

Inventors

• Kelleher Brian C

Classifications

• C01D3/20 Primary

  by melting · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• C01P2006/80

  Compositional purity · CPC title

• C09K5/12

  Molten materials, i.e. materials solid at room temperature, e.g. metals or salts · CPC title

• C01F5/30 Primary

  Chlorides · CPC title