Embossed effect pigment and method of manufacture of embossed effect pigment

Patent metadata

Field	Value
Publication number	US-12048757-B2
Application number	US-202318110079-A
Country	US
Kind code	B2
Filing date	Feb 15, 2023
Priority date	Oct 18, 2017
Publication date	Jul 30, 2024
Grant date	Jul 30, 2024

Abstract

An embossed effect pigment includes a metallic substrate in platelet form with embossed structure having a periodic pattern with diffractive elements, said substrate having been produced by PVD methods, wherein the substrate has an elemental metal content of 80% to 100% by weight, based on the substrate, and wherein the effect pigment has been treated with a leafing additive for surface modification. A method of manufacture of an embossed effect pigment includes suspending a metallic substrate in in at least one solvent, adding a leafing additive to the suspension including the metallic substrate in the at least one solvent and stirring the suspension including the leafing additive, and separating the embossed effect pigment from the at least one solvent.

First claim

The invention claimed is:

1. An embossed effect pigment comprising a metallic substrate in platelet form with embossed structure having a periodic pattern with diffractive elements, the substrate having been produced by PVD methods, wherein the substrate has an elemental metal content of 80% to 100% by weight, based on the substrate, and wherein the effect pigment has been treated with a leafing additive for surface modification, wherein the leafing additive has the formula:
(R—O) x —P(O)(OR 1 ) (3-x)

wherein x=1 or 2, R is a linear or branched alkyl radical having a carbon chain ranging from C 8 to C 20 and R 1 is H.

2. The embossed effect pigment according to claim 1 , wherein the metallic substrate in platelet form includes aluminum with an embossed structure having 5,000 to 20,000 diffractive elements/cm.

3. The embossed effect pigment according to claim 1 , wherein R is a linear or branched alkyl radical having a carbon chain ranging from C 12 to C 18 .

4. The embossed effect pigment according to claim 1 , wherein the leafing additive includes laurylphosphonic acid (R=12), monocetylphosphoric ester, dicetylphosphoric ester (R=16), or mixtures thereof.

5. The embossed effect pigment according to claim 1 , wherein the substrate contains at least 80 wt-% aluminum.

6. The embossed effect pigment according to claim 1 , wherein R is a linear or branched alkyl radical having a carbon chain ranging from C 12 to C 20 .

7. The embossed effect pigment according to claim 1 , wherein the metallic substrate is a single layered substrate made from aluminum.

8. An embossed effect pigment comprising a metallic substrate in platelet form with embossed structure having a periodic pattern with diffractive elements, the substrate having been produced by PVD methods, wherein the substrate has an elemental metal content of 80% to 100% by weight, based on the substrate, and wherein the effect pigment has been treated with a leafing additive for surface modification, wherein the leafing additive has the formula:
(R—O) x —P(O)(OR 1 ) (3-x)

wherein x=1 or 2, R is a linear or branched alkyl radical having a carbon chain ranging from C 8 to C 20 and R 1 is H,
the embossed effect pigment having been produced by a process comprising:
suspending the metallic substrate in at least one solvent,
adding the leafing additive to the suspension comprising the metallic substrate and the at least one solvent and stirring the suspension including the leafing additive,
separating the embossed effect pigment from the at least one solvent, wherein the amount of the leafing additive on the embossed effect pigment is in a range of 15 to 50 wt. %, based on the metallic substrate.

9. The embossed effect pigment according to claim 8 , wherein adding the leafing additive to the suspension of the metallic substrate in the at least one solvent is conducted at a temperature within a range from 40° C. to 100° C.

10. The embossed effect pigment according to claim 8 , wherein the process further comprises drying the embossed effect pigment treated with the leafing additive that has been separated from the at least one solvent.

11. A method treating an embossed metallic substrate, the substrate being in platelet form with embossed structure having a periodic pattern with diffractive elements, the substrate having been produced by PVD methods, wherein the substrate has an elemental metal content of 80% to 100% by weight, based on the substrate, the method comprising:
suspending the embossed metallic substrate in at least one solvent to form a suspension;
adding a leafing additive to the suspension, wherein the leafing additive has the formula:
(R—O)x-P(O)(OR 1 )(3-x)

wherein x=1 or 2, R is a linear or branched alkyl radical having a carbon chain ranging from C 8 to C 20 and R 1 is H;
stirring the suspension, whereby the embossed metallic substrate undergoes surface modification to result in an embossed effect pigment; and
separating the embossed effect pigment from the at least one solvent;
wherein the amount of the leafing additive on the embossed effect pigment is in the range of 15 to 50 wt. %, based on the weight of the metallic substrate.

12. The method according to claim 11 , wherein the at least one solvent comprises one or more of ethylacetate and butylacetate.

13. The method according to claim 11 , wherein the at least one solvent is butylacetate.

14. The method according to claim 11 , wherein adding the leafing additive to the suspension of the metallic substrate in the at least one solvent is conducted at a temperature within a range from 40° C. to 100° C.

15. The method according to claim 11 , further comprising drying the embossed effect pigment treated with the leafing additive that has been separated from the at least one solvent.

Assignees

• Eckart Gmbh

Inventors

• Schilling Christine
• Gebhard Ann-Katrin
• Schmidt Ulrich
• Struck Oliver

Classifications

• C09C2220/20

  PVD, CVD methods or coating in a gas-phase using a fluidized bed · CPC title

• C09C2210/40

  Embossed layers · CPC title

• C09C2200/1054

  the core consisting of a metal · CPC title

• C09C1/644

  treated with organic compounds, e.g. polymers · CPC title

• C09C1/0066

  consisting of at least one coloured inorganic material · CPC title