Positive electrode active material for secondary battery, preparation method thereof, and positive electrode for secondary battery including same

Patent metadata

Field	Value
Publication number	US-12046750-B2
Application number	US-201917294923-A
Country	US
Kind code	B2
Filing date	Nov 28, 2019
Priority date	Dec 3, 2018
Publication date	Jul 23, 2024
Grant date	Jul 23, 2024

Abstract

The present disclosure relates to a positive electrode active material for a secondary battery, the positive electrode active material being a lithium composite transition metal oxide particle including nickel (Ni) and cobalt (Co) and including at least one of manganese (Mn) and aluminum (Al), wherein the lithium composite transition metal oxide particle includes 60 mol % or greater of the nickel (Ni) in all metals excluding lithium, a doping element is doped on the lithium composite transition metal oxide particle, and the particle intensity of the lithium composite transition metal oxide particle is 210 MPa to 290 MPa.

First claim

The invention claimed is:

1. A positive electrode active material for a secondary battery, the positive electrode active material being a lithium composite transition metal oxide particle including nickel (Ni) and cobalt (Co) and including at least one of manganese (Mn) and aluminum (Al), wherein
the lithium composite transition metal oxide particle includes 60 mol % or greater of the nickel (Ni) in all metals excluding lithium,
a doping element is doped on the lithium composite transition metal oxide particle to 70 mol % or greater of the total number of moles of doping elements in a region corresponding to a distance of 60% to 100% from the center of the lithium composite transition metal oxide particle with respect to the half diameter of the lithium composite transition metal oxide particle, and
the particle strength of the lithium composite transition metal oxide particle is 210 MPa to 290 MPa.

2. The positive electrode active material of claim 1 , wherein the doping element is doped to 6 mol % to 10 mol % with respect to all metals excluding lithium.

3. The positive electrode active material of claim 1 , wherein the doping element comprises at least one selected from the group consisting of P, B, Al, Si, W, Zr, and Ti.

4. The positive electrode active material of claim 1 , wherein the lithium composite transition oxide particle comprises a compound represented by Formula 1 below:
Li p Ni 1-x-y-z CO x M a y M b z O 2   [Formula 1]

wherein in Formula 1, 1.0≤p≤1.5, 0<x≤0.2, 0<y≤0.2, 0.06≤z≤0.1, and 0<x+y+z≤0.4,
M a is at least one selected from the group consisting of Mn and Al, and
M b is at least one selected from the group consisting of P, B, Al, Si, W, Zr, and Ti.

5. The positive electrode active material of claim 1 , wherein the average particle diameter (D 50 ) is 8 μm to 30 μm.

6. The positive electrode active material of claim 1 , wherein the lithium composite transition metal oxide particle has a value of 0.7 to 1, the value obtained by substituting the concentration of the doping element at the surface of the particle and the concentration of the doping element at the center of the particle analyzed by an Energy Dispersive Spectrometer (EDS) into Equation 1 below:
(H s −H c )/H s   [Equation 1]

wherein in Equation 1, H s is the concentration of the doping element at the surface of the particle when the lithium composite transition metal oxide particle is analyzed by an EDS, and H c is the concentration of the doping element at the center of the particle when the lithium composite transition metal oxide particle is analyzed by an EDS.

7. A method for preparing a positive electrode active material for a secondary battery according to claim 1 , the method comprising:
mixing a transition metal hydroxide which includes nickel (Ni) and cobalt (Co) and includes at least one of manganese (Mn) and aluminum (Al), wherein the nickel (Ni) is 60 mol % or greater in all metals, with a lithium compound and subjecting the mixture to primary firing to prepare a lithium composite transition metal oxide particle; and
mixing the lithium composite transition metal oxide particle and a doping source including a doping element and subjecting the mixture to secondary firing to dope the doping element on the lithium composite transition metal oxide particle.

8. The method of claim 7 , wherein the doping source comprises at least one doping element selected from the group consisting of P, B, Al, Si, W, Zr, and Ti.

9. The method of claim 7 , wherein the primary firing is performed for 10-25 hours.

10. The method of claim 7 , wherein the primary firing is performed at 750-1,000° C.

11. The method of claim 7 , wherein the secondary firing is performed for 3-12 hours.

12. The method of claim 7 , wherein the secondary firing is performed at 700-900° C.

13. A positive electrode for a secondary battery, the positive electrode comprising:
a positive electrode current collector; and
a positive electrode active material layer formed on the positive electrode current collector, wherein the positive electrode active material layer includes the positive electrode active material for a secondary battery according to claim 1 .

Assignees

• Lg Energy Solution Ltd

Inventors

• Lho Eun Sol
• Jung Wang Mo
• Kang Min Suk
• Lee Sang Wook
• Baek So Ra
• Wang Wen Xiu

Classifications

• C01G53/82

  Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title