System and method for reducing ore using hydrogen as a reducing agent

Patent metadata

Field	Value
Publication number	US-12043874-B2
Application number	US-202117539381-A
Country	US
Kind code	B2
Filing date	Dec 1, 2021
Priority date	Dec 3, 2020
Publication date	Jul 23, 2024
Grant date	Jul 23, 2024

Abstract

A system for reducing ore includes a hydrogen supply unit configured to supply hydrogen, a furnace configured to reduce the ore using the supplied hydrogen, and a hydrogen recovery unit configured to recover hydrogen from an exhaust gas that is exhausted from the furnace.

First claim

What is claimed is:

1. A system for reducing ore, comprising:
a proton exchange membrane (PEM) electrolyzer configured to supply hydrogen;
a furnace configured to reduce the ore using the supplied hydrogen, the furnace fluidly connected to the PEM electrolyzer; and
a hydrogen recovery unit including a PEM hydrogen pump configured to recover hydrogen from an exhaust gas that is exhausted from the furnace, the hydrogen recovery unit fluidly connected to the furnace,
wherein the hydrogen recovery unit comprises series-parallel coolant flow channels fluidly connecting multiple inlets and outlets.

2. The system of claim 1 , further comprising:
a mixed gas transport line fluidly connected to an outlet of the PEM electrolyzer and to an inlet of the furnace, and configured to transport the supplied hydrogen and the recovered hydrogen to the furnace;
an exhaust line fluidly connected to an outlet of the furnace and to an inlet of the PEM hydrogen pump, and configured to transport the exhaust gas from the furnace to the PEM hydrogen pump; and
a recovered hydrogen line fluidly connected to an outlet of the PEM hydrogen pump and to the mixed gas transport line, and configured to transport the recovered hydrogen from the PEM hydrogen pump to the mixed gas transport line.

3. The system of claim 2 , further comprising a separating unit fluidly connected to the PEM electrolyzer configured to separate oxygen from water in a water/oxygen output stream of the PEM electrolyzer.

4. The system of claim 3 , wherein the separating unit comprises:
a first vessel configured to separate the oxygen from the water in the water/oxygen output stream;
a second vessel containing an air fan or blower configured to dilute the separated oxygen with air;
a venturi having an inlet fluidly connected to the first vessel and an outlet fluidly connected to the second vessel; and
an air return conduit having an inlet fluidly connected to the second vessel and an outlet fluidly connected to a throat of the venturi.

5. The system of claim 4 , wherein the first vessel comprises:
a first tank;
a second tank;
a first fluid connection between the first tank and the second tank located above a water level in the first tank and the second tank, and configured to allow exchange of oxygen between the first tank and the second tank;
a second fluid connection between the first tank and the second tank located below the water level in the first tank and the second tank, and configured to allow exchange of water between the first tank and the second tank;
a recycled water line fluidly connected to the first tank and configured to recycle the water to the PEM electrolyzer; and
a make-up water supply line fluidly connected to the second tank and configured to maintain the water level in the first tank and second tank above a predetermined height.

6. The system of claim 2 , further comprising a heat exchanger fluidly connected to the exhaust line and the mixed gas transport line, and configured to heat the supplied hydrogen and the recovered hydrogen with heat from the exhaust gas.

7. The system of claim 6 , further comprising:
a shift reactor fluidly connected to the exhaust line; and
a water supply line fluidly connected to the shift reactor,
wherein the shift reactor is configured to react carbon monoxide in the exhaust gas with water provided from the water supply line to form hydrogen and carbon dioxide.

8. The system of claim 7 , further comprising a preferential oxidizer fluidly connected to the exhaust line downstream from the shift reactor and configured to preferentially oxidize the carbon monoxide to carbon dioxide in the exhaust gas.

9. The system of claim 8 , wherein the hydrogen pump comprises a plate comprising:
hydrogen inlets;
hydrogen outlets;
hydrogen channels fluidly connecting the hydrogen inlets to the hydrogen outlets;
coolant inlets;
coolant outlets; and
coolant channels fluidly connecting the coolant inlets to the coolant outlets in a series and parallel configuration.

10. The system of claim 1 , wherein the furnace comprises a blast furnace.

11. A system, comprising:
an electrolyzer;
a blast furnace;
a first conduit fluidly connecting a hydrogen outlet of the electrolyzer to the blast furnace; and
a hydrogen recovery unit fluidly connected to the blast furnace configured to recover hydrogen from the blast furnace and recycle the recovered hydrogen to the blast furnace,
wherein the hydrogen recovery unit comprises series-parallel coolant flow channels fluidly connecting multiple inlets and outlets.

12. The system of claim 11 , further comprising:
a second conduit fluidly connecting an oxygen outlet of the electrolyzer to the blast furnace.

Assignees

• Ohmium International Inc

Inventors

• Karuppaiah Chockkalingam
• Ballantine Arne
• Venkatraman Muralidhar

Classifications

• C21B7/002

  Evacuating and treating of exhaust gases · CPC title

• C21B2005/005

  Selection or treatment of the reducing gases · CPC title

• B01D2258/025

  from metallurgy plants · CPC title

• B01D53/326

  in electrochemical cells · CPC title

• B01D2256/16

  Hydrogen · CPC title