Systems and methods for making ceramic powders

Patent metadata

Field	Value
Publication number	US-12043581-B2
Application number	US-202117443603-A
Country	US
Kind code	B2
Filing date	Jul 27, 2021
Priority date	Jul 8, 2016
Publication date	Jul 23, 2024
Grant date	Jul 23, 2024

Abstract

Systems and methods for making ceramic powders configured with consistent, tailored characteristics and/or properties are provided herein. In some embodiments a system for making ceramic powders, includes: a reactor body having a reaction chamber and configured with a heat source to provide a hot zone along the reaction chamber; a sweep gas inlet configured to direct a sweep gas into the reaction chamber and a sweep gas outlet configured to direct an exhaust gas from the reaction chamber; a plurality of containers, within the reactor body, configured to retain at least one preform, wherein each container is configured to permit the sweep gas to flow therethrough, wherein the preform is configured to permit the sweep gas to flow there through, such that the precursor mixture is reacted in the hot zone to form a ceramic powder product having uniform properties.

First claim

We claim:

1. A method for carbothermically producing a ceramic powder, the method comprising:
a) preheating at least one container in a staging zone, wherein the at least one container comprises at least one preform;
(i) wherein the at least one preform comprises a mixture, wherein the mixture comprises a carbon source and at least one of (a) a metal oxide and (b) boric acid; and
(ii) wherein the at least one preform comprises at least one gas channel, wherein the at least one gas channel is a preconfigured aperture that extends from a top portion of the at least one preform to a bottom portion of the at least one preform;

b) moving the at least one container into a reactor body, wherein the reactor body comprises a reaction zone;
c) carbothermically reacting the at least one preform in the reaction zone thereby producing a ceramic powder, wherein the carbothermically reacting comprises reducing, via the carbon of the at least one preform, at least one of the metal oxide and the boric acid of the at least one preform to form the ceramic powder, wherein the ceramic powder comprises ceramic particles, wherein the ceramic particles are selected from the group consisting of boron carbide particles, boron nitride particles, silicon carbide particles, metal carbide particles, metal boride particles, metal nitride particles, and combinations thereof, wherein the metal nitride particles exclude aluminum-containing nitride particles; and
d) moving the at least one container from the reactor body to a receiving zone.

2. The method of claim 1 , comprising flowing, during at least the carbothermically reacting step, a sweep gas into the at least one container.

3. The method of claim 2 , wherein the flowing comprises flowing the sweep gas through the at least one gas channel of the at least one preform.

4. The method of claim 1 , wherein the carbothermically reacting step comprises a reaction time, wherein the reaction time is from 0.5 to 12 hours.

5. The method of claim 1 , wherein the ceramic powder is selected from the group consisting of titanium diboride, boron carbide, boron nitride, zirconium diboride, titanium carbide, silicon carbide, titanium nitride, aluminum carbide, and combinations thereof.

6. The method of claim 1 , wherein the reactor body comprises a reaction chamber, and wherein the at least one gas channel comprises an area fraction of from 0.05 to 0.8 of a cross-sectional area of the reaction chamber.

7. The method of claim 6 , wherein the at least one gas channel comprises an area fraction of from 0.1 to 0.8 of the cross-sectional area of the reaction chamber.

8. The method of claim 6 , wherein the at least one gas channel comprises an area fraction of from 0.2 to 0.8 of the cross-sectional area of the reaction chamber.

9. The method of claim 6 , wherein the at least one gas channel comprises an area fraction of from 0.3 to 0.8 of the cross-sectional area of the reaction chamber.

10. The method of claim 1 , wherein the preconfigured aperture comprises a uniform cross-section.

11. The method of claim 10 , wherein the preconfigured aperture comprises a long-axis, wherein the long-axis is parallel to a gas flow through the at least one preform.

12. The method of claim 1 , wherein the reactor body is vertical.

13. The method of claim 1 , wherein the reactor body is configured at an angle, wherein a first end of the reactor body is at a different height than a second end of the reactor body.

14. The method of claim 1 , wherein the staging zone is configured with a valve such that a pressure differential is introduced throughout the staging zone to remove and/or add gaseous species from the staging zone.

15. The method of claim 14 , wherein the staging zone comprises a heat source configured to preheat the at least one container and the at least one preform.

16. The method of claim 1 , wherein the at least one preform comprises titanium dioxide as the metal oxide.

17. The method of claim 16 , wherein the at least one preform comprises 20-50 wt. % of the titanium dioxide.

18. The method of claim 16 , wherein the preform comprises 30-40 wt. % of the titanium dioxide.

19. The method of claim 16 , wherein the at least one preform comprises 10-35 wt. % of the carbon source.

20. The method of claim 16 , wherein the at least one preform comprises 30-70 wt. % boric acid.

21. The method of claim 1 , wherein the ceramic particles are selected from the group consisting of boron carbide particles, silicon carbide particles, boron nitride particles, metal carbide particles, metal boride particles, and combinations thereof.

22. The method of claim 1 , wherein the ceramic particles are selected from the group consisting of boron carbide particles, silicon carbide particles, metal carbide particles, metal boride particles, and combinations thereof.

Assignees

• Alcoa Usa Corp

Inventors

• Mcmillen James C
• Sworts Lance M
• Mosser Benjamin D
• Shanta Iii Charles Robert

Classifications

• C04B35/6261

  Milling · CPC title

• C04B35/62645

  Thermal treatment of powders or mixtures thereof other than sintering · CPC title

• C04B2235/74

  Physical characteristics · CPC title

• C04B2235/6567

  Treatment time · CPC title

• C04B2235/422

  Carbon · CPC title