Solid electrolyte compositions for electrochemical cells
US-2018159172-A1 · Jun 7, 2018 · US
US12040446B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12040446-B2 |
| Application number | US-201816977492-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 26, 2018 |
| Priority date | Mar 26, 2018 |
| Publication date | Jul 16, 2024 |
| Grant date | Jul 16, 2024 |
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A solid electrolyte material for a solid state battery (10) having the following chemical formula XM2(PS4)3, where P is phosphorus, S is sulfur and X is lithium (Li), sodium (Na), silver (Ag) or magnesium (Mg0.5) and M is titanium (Ti), zirconium (Zr), germanium (Ge), silicon (Si), tin (Sn) or a mixture of X and aluminium (X+Al) and exhibiting peaks in positions of 2θ=13,64° (±1°), 16,48° (±1°) and 22,18° (±1°) in a X-ray diffraction measurement using CuKα line, where IA is the intensity in arbitrary units of the peak at 13,64° (±1°) and IB is the intensity in arbitrary units of a peak at 23,34° (±1°), (IA−IB)/(IA+IB)>0.The disclosure is also related to a solid electrolyte comprising the solid electrolyte material and a solid state battery comprising the solid electrolyte.
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The invention claimed is: 1. A solid electrolyte material for a solid state battery having the following chemical formula XM 2 (PS 4 ) 3 , where P is phosphorus, S is sulfur and X is lithium (Li), sodium (Na), silver (Ag) or magnesium (Mg 0,5 ) and M is a mixture of X and aluminium (X+Al) and exhibiting peaks in positions of 2θ=13,64° (±1°), 16,48° (±1° and 22,18° (±1° in a X-ray diffraction measurement using CuKα line, where I A is the intensity in arbitrary units of the peak at 13,64° (±1° and TB is the intensity in arbitrary units of a peak at 23,34° (±1°, (I A −I B )/(I A +I B )>0. 2. The solid electrolyte material according to claim 1 , exhibiting peaks in position of 2θ=13,64° (±1°), 13,76° (±1°), 14,72° (±1°), 15,36° (±1°), 15,90° (±1°), 16,48° (±1°), 17,42° (±1°), 17,56° (±1°), 18,58° (±1°, and 22,18° (±1° in a X-ray diffraction measurement using CuKα line. 3. The solid electrolyte material according to claim 1 , wherein X is lithium. 4. The solid electrolyte material according to claim 3 , wherein M is a mixture of lithium and aluminium (Li+Al). 5. The solid electrolyte material according to claim 3 , wherein the diffusion coefficient of lithium in the solid electrolyte at −20° C. is greater than or equal to 3,0.10 −12 m 2 /s. 6. A solid electrolyte comprising a solid electrolyte material according to claim 1 . 7. A solid state battery comprising a solid electrolyte according to claim 6 .
inorganic · CPC title
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
Electric properties · CPC title
by peak-intensities or a ratio thereof only · CPC title
Sulfur, selenium, or tellurium compounds of phosphorus · CPC title
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