Refrigerant pipe, heat exchanger, and method for producing refrigerant pipe

Patent metadata

Field	Value
Publication number	US-12038240-B2
Application number	US-201917043413-A
Country	US
Kind code	B2
Filing date	Mar 28, 2019
Priority date	Mar 30, 2018
Publication date	Jul 16, 2024
Grant date	Jul 16, 2024

Abstract

A copper-containing refrigerant pipe having an anticorrosive film, a heat exchanger, and a method for producing the refrigerant pipe are disclosed. The refrigerant pipe includes a pipe body including copper or a copper alloy and an anticorrosive film formed on the outer surface of the pipe body. The anticorrosive film is obtained by applying a coating agent to the outer surface of the pipe body. The coating agent contains one or more anticorrosive agents selected from the group consisting of (A) an organic sulfonate compound, (B) a polyhydric alcohol-organic acid ester compound, and (C) an aliphatic amine compound having 8 to 24 carbon atoms. When the coating agent includes an anticorrosive agent of (C) the aliphatic amine compound having 8 to 24 carbon atoms, (C) the aliphatic amine compound having 8 to 24 carbon atoms is included in an amount of 2.0 wt % or more and 10.0 wt % or less in the coating agent.

First claim

The invention claimed is:

1. An intermediate product of a refrigerant pipe comprising:
a pipe body including copper or a copper alloy; and
an anticorrosive film formed on an outer surface of the pipe body,
wherein the anticorrosive film includes
a volatile metalworking fluid that is capable of being volatilized at 180° C. or higher, and
one or more anticorrosive agents selected from the group consisting of
calcium dinonylnaphthalene sulfonate or an organic sulfonate compound represented by formula (III) below and/or an organic sulfonate compound represented by formula (IV) below, in an amount of 0.1 μg or more and 200.0 μg or less per square centimeter:

wherein R1 to R7 each independently represent hydrogen or an aliphatic hydrocarbon group having 4 to 12 carbon atoms except that R1 to R7 cannot all be hydrogen, and M represents Ca or Zn,

wherein R1 to R7 each independently represent hydrogen or an aliphatic hydrocarbon group having 4 to 12 carbon atoms except that R1 to R7 cannot all be hydrogen, and M represents Ca or Zn.

2. An intermediate product of a refrigerant pipe comprising:
a pipe body including copper or a copper alloy; and
an anticorrosive film formed on an outer surface of the pipe body,
wherein the anticorrosive film is obtained by applying a coating agent to the outer surface of the pipe body, the coating agent containing;
a volatile metalworking fluid that is capable of being volatilized at 180° C. or higher, and
calcium dinonylnaphthalene sulfonate in an amount of 0.1 wt % or more and 8.0 wt % or less.

3. The intermediate product of a refrigerant pipe according to claim 2 , wherein the anticorrosive film is obtained by drying the applied coating agent under conditions where the coating agent has a surface temperature of 60° C. or higher and 200° C. or lower.

4. A heat exchanger comprising:
a heat transfer tube that is the refrigerant pipe according to claim 1 ; and
a heat transfer fin fixed to the heat transfer tube.

5. The heat exchanger according to claim 4 ,
wherein the heat transfer fin is formed of aluminum or an aluminum alloy, and
the anticorrosive agent is not present on an outer surface of the heat transfer fin.

Assignees

• Daikin Ind Ltd

Inventors

• Kanetake Mirei
• Tanaka Yuuji
• Okada Kunihiro
• Ohya Hideo
• Katayama Hideo
• IMAZU Keisuke
• Araki Shouhei

Classifications

• F28F21/084

  from aluminium or aluminium alloys · CPC title

• F28F1/12

  the means being only outside the tubular element · CPC title

• C09D5/086

  Organic or non-macromolecular compounds · CPC title

• C10M141/08

  at least one of them being an organic sulfur-, selenium- or tellurium-containing compound · CPC title

• C10M171/008

  Lubricant compositions compatible with refrigerants · CPC title