Rubber composition comprising a block-copolymer

Patent metadata

Field	Value
Publication number	US-12037437-B2
Application number	US-202217656097-A
Country	US
Kind code	B2
Filing date	Mar 23, 2022
Priority date	May 28, 2021
Publication date	Jul 16, 2024
Grant date	Jul 16, 2024

Abstract

The present invention is directed to a rubber composition comprising an elastomer, a filler, and a block-copolymer. According to the invention, the block-copolymer comprises (i) an elastomer block and (ii) a thermoplastic block comprising a poly alkylacrylate, wherein the alkylacrylate comprises a polycyclic substituent at its single bonded oxygen atom. Moreover, the present invention is directed to a block-copolymer.

First claim

What is claimed is:

1. A rubber composition comprising:
a rubber elastomer;
a filler; and
a block-copolymer comprising an elastomer block and a thermoplastic block comprising a poly alkylacrylate, wherein the poly alkylacrylate contains a single bonded oxygen atom, and wherein the alkylacrylate comprises a polycyclic substituent at the single bonded oxygen atom.

2. The rubber composition of claim 1 wherein at least one of the rubber elastomer and the elastomer block comprises at least one diene-based elastomer.

3. The rubber composition of claim 2 wherein the diene-based elastomer is selected from one or more of styrene butadiene rubber, polybutadiene, solution polymerized styrene butadiene rubber, emulsion polymerized styrene butadiene rubber, natural rubber, synthetic polyisoprene, and isoprene butadiene rubber.

4. The rubber composition of claim 1 wherein at least one of the rubber elastomer and the elastomer block has a functional group which is capable of coupling to one of silica and carbon black.

5. The rubber composition of claim 4 wherein the elastomer block comprises an elastomer chain having a first chain end and a second chain end, with the first chain end connected to the poly alkylacrylate block, and wherein the functional group is located at said second chain end.

6. The rubber composition of claim 1 wherein the poly alkylacrylate has the following structure:

wherein n represents the number of the alkylacrylate monomers in the poly alkylacrylate, wherein R 1 represents the alkyl; and
wherein R 2 represents a polycyclic hydrocarbon material.

7. The rubber composition of claim 6 wherein n is an integer being one or more of larger than 10 and smaller than 2000.

8. The rubber composition of claim 1 wherein the alkyl is one of —CH 3 and —C 2 H 5 .

9. The rubber composition of claim 1 wherein the alkylacrylate has at the single bonded oxygen atom one of:
i) a bicyclic substituent,
ii) a tricyclic substituent,
iii) a hydrocarbon substituent comprising at least seven carbon atoms, with at least five of the carbon atoms cyclically arranged.

10. The rubber composition of claim 1 wherein the poly alkylacrylate is one of: poly(isobornyl methacrylate) and poly(adamantyl methacrylate).

11. The rubber composition of claim 6 wherein the poly alkylacrylate comprises one or more of the following structures:

12. The rubber composition of claim 1 wherein the thermoplastic block consists of the poly alkylacrylate and has one or more of: (i) a number average molecular weight Mn of at least 10,000 g/mol and (ii) at least 10 alkylacrylate monomers.

13. The rubber composition of claim 1 , wherein the thermoplastic block consists of the poly alkylacrylate and has one or more of: (i) a number average molecular weight Mn of at most 150,000 g/mol and (ii) at most 2000 alkylacrylate monomers.

14. The rubber composition of claim 1 , wherein the elastomer block has one or more of: (i) a number average molecular weight Mn of at least 10,000 g/mol and (ii) at least 90 monomers chosen from a list of styrene, butadiene, and isoprene.

15. The rubber composition of claim 1 , wherein the elastomer block has one or more of: (i) a number average molecular weight Mn of at most 450,000 g/mol and (ii) at most 6000 monomers chosen from a list of styrene, butadiene, and isoprene.

16. The rubber composition of claim 1 , wherein the block-copolymer has a first glass transition temperature within a range of −92° C. to −15° C. and a second glass transition temperature within a range of 150° C. to 250° C.

17. The rubber composition of claim 1 , wherein a ratio of (i) a number average molecular weight Mn of the elastomer block and (ii) a number average molecular weight Mn of the thermoplastic block is within a range of 0.1 to 0.95.

18. The rubber composition of claim 1 comprising:
50 phr to 90 phr of the elastomer;
10 phr to 50 phr of the block-copolymer;
20 phr to 200 phr of the filler comprising one or more of: at least one silica and at least one carbon black.

19. An article of manufacture selected from a tire, a power transmission belt, a hose, a track, an air sleeve, and a conveyor belt, wherein the article of manufacture comprises the rubber composition of claim 1 .

20. A block-copolymer comprising
an elastomer block, and
a thermoplastic block comprising a poly alkylacrylate, wherein the poly alkylacrylate contains a single bonded oxygen atom, and wherein the alkylacrylate comprises a polycyclic substituent at the single bonded oxygen atom, and wherein the block-copolymer is a diblock copolymer.

Assignees

• Goodyear Tire & Rubber
• Luxembourg Institute Of Science And Tech

Inventors

• Weydert Marc
• Shaplov Alexander
• Gunaydin Abdullah
• Mugemana Clément

Classifications

• C08L9/06 Primary

  Copolymers with styrene · CPC title

• C08F2438/03

  Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX] · CPC title

• C08F297/02

  using a catalyst of the anionic type · CPC title

• C08F293/005

  using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent · CPC title

• C08L53/00

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title