Apparatus for removing boron, method for removing boron, apparatus for producing pure water and method for producing pure water

Patent metadata

Field	Value
Publication number	US-12037276-B2
Application number	US-202017438011-A
Country	US
Kind code	B2
Filing date	Feb 13, 2020
Priority date	Mar 13, 2019
Publication date	Jul 16, 2024
Grant date	Jul 16, 2024

Abstract

A method for efficiently treating boron from water to be treated, an apparatus for producing pure water, and a method for producing pure water. An apparatus for removing boron includes a low-pressure reverse osmosis membrane apparatus to which is supplied water to be treated, a pH adjustment apparatus to adjust a pH of permeated water from the low-pressure reverse osmosis membrane apparatus to 5.0 to 9.0, a high-pressure reverse osmosis membrane apparatus to which is supplied the water adjusted by the pH adjustment apparatus, and an electrodeionization to which is supplied permeated water from the high-pressure reverse osmosis membrane apparatus.

First claim

The invention claimed is:

1. An apparatus for removing boron, comprising:
a low-pressure reverse osmosis membrane apparatus which is supplied with a water to be treated,
a pH adjustment apparatus configured to adjust a pH of a permeated water from the low-pressure reverse osmosis membrane apparatus to 5.0 to 9.0,
a high-pressure reverse osmosis membrane apparatus which is supplied with an adjustment water that has an adjusted pH from the pH adjustment apparatus,
an electrodeionization apparatus which is supplied with a permeated water from the high-pressure reverse osmosis membrane apparatus,
a pump provided downstream from the pH adjustment apparatus and configured to pump the adjustment water that has the adjusted pH to the high-pressure reverse osmosis membrane apparatus, and
a degassing membrane device positioned downstream of the high-pressure reverse osmosis membrane apparatus and directly upstream of the electrodeionization apparatus,
wherein the pH adjustment apparatus is positioned directly downstream from the low-pressure reverse osmosis membrane apparatus and directly upstream from the pump, and the pump is positioned directly upstream from the high-pressure reverse osmosis membrane apparatus.

2. The apparatus for removing boron according to claim 1 , wherein, after starting with the adjustment water having a sodium concentration of 1200 ppb or more, the permeated water from the high-pressure reverse osmosis membrane apparatus has a conductivity of 2 μs/cm or less and a sodium concentration of 200 ppb or less.

3. The apparatus for removing boron according to claim 1 , wherein, after starting with the permeated water from the high-pressure reverse osmosis membrane apparatus having a boron concentration of 6.8 ppb or greater, a treated water of the electrodeionization apparatus has a boron concentration of 50 ppt or less.

4. An apparatus for producing pure water, comprising:
a low-pressure reverse osmosis membrane apparatus which is supplied with a water to be treated,
a pH adjustment apparatus configured to adjust a pH of a permeated water from the low-pressure reverse osmosis membrane apparatus to 5.0 to 9.0,
a high-pressure reverse osmosis membrane apparatus which is supplied with an adjustment water that has an adjusted pH from the pH adjustment apparatus,
an electrodeionization apparatus which is supplied with a permeated water from the high-pressure reverse osmosis membrane apparatus,
an ultraviolet oxidation apparatus to which is supplied with a water treated by the electrodeionization apparatus,
a cartridge polisher to which is supplied with a water treated by the ultraviolet oxidation apparatus,
a pump provided downstream from the pH adjustment apparatus and configured to pump the adjustment water that has the adjusted pH to the high-pressure reverse osmosis membrane apparatus, and
a degassing membrane device positioned downstream of the high-pressure reverse osmosis membrane apparatus and directly upstream of the electrodeionization apparatus,
wherein the pH adjustment apparatus is positioned directly downstream from the low-pressure reverse osmosis membrane apparatus and directly upstream from the pump, and the pump is positioned directly upstream from the high-pressure reverse osmosis membrane apparatus.

5. The apparatus for producing pure water according to claim 4 , wherein, after starting with the adjustment water having a sodium concentration of 1200 ppb or more, the permeated water from the high-pressure reverse osmosis membrane apparatus has a conductivity of 2 μs/cm or less and a sodium concentration of 200 ppb or less.

6. The apparatus for producing pure water according to claim 4 , wherein, after starting with the permeated water from the high-pressure reverse osmosis membrane apparatus having a boron concentration of 6.8 ppb or greater, the pure water, after treatment by the cartridge polisher, has a boron concentration of 50 ppt or less.

7. A method for removing boron comprising:
(a) supplying a water to be treated to a low-pressure reverse osmosis membrane apparatus,
(b) supplying the permeate water from the low-pressure reverse osmosis membrane apparatus to a pH adjustment apparatus to adjust the pH to 5.0-9.0,
(c) supplying a permeated water that has an adjusted pH from the pH adjustment apparatus to a high-pressure reverse osmosis membrane apparatus via a pump, and treating it, and
(d) supplying the permeated water from the high-pressure reverse osmosis membrane apparatus to a degassing membrane device, and then directly to an electrodeionization apparatus and treating it,
wherein the pH adjustment apparatus is positioned directly downstream from the low-pressure reverse osmosis membrane apparatus and directly upstream from the pump, and the pump is positioned directly upstream from the high-pressure reverse osmosis membrane apparatus.

8. The method according to claim 7 , wherein the permeated water from the high-pressure reverse osmosis membrane apparatus has a conductivity of 2 μs/cm or less, or a sodium concentration of 200 ppb or less, or both.

9. The method according to claim 7 , wherein in the step (d), the treated water having been treated by the electrodeionization apparatus has a boron concentration of 50 ppt or less.

10. A method for producing pure water comprising:
(a) supplying a water to be treated to a low-pressure reverse osmosis membrane apparatus,
(b) supplying the permeate water from the low-pressure reverse osmosis membrane apparatus to a pH adjustment apparatus to adjust the pH to 5.0-9.0,
(c) supplying a permeated water that has an adjusted pH from the pH adjustment apparatus to a high-pressure reverse osmosis membrane apparatus via a pump, and treating it,
(d) supplying the permeated water from the high-pressure reverse osmosis membrane apparatus to a degassing membrane device, and then directly to an electrodeionization apparatus and treating it,
(e) supplying a water from the electrodeionization apparatus to an ultraviolet oxidation apparatus and removing organic substances, and
(f) supplying the water from which the organic substance has been removed to a cartridge polisher, treating the water from which the organic substance—has substances have been removed by ion exchange, and taking out pure water,
wherein the pH adjustment apparatus is positioned directly downstream from the low-pressure reverse osmosis membrane apparatus and directly upstream from the pump, and the pump is positioned directly upstream from the high-pressure reverse osmosis membrane apparatus.

11. The method according to claim 10 , wherein the permeated water from the high-pressure reverse osmosis membrane apparatus has a conductivity of 2 μs/cm or less, or a sodium concentration of 200 ppb or less, or both.

12. The method according to claim 10 , wherein the pure water, after treatment by the cartridge polisher, has a boron concentration of 50 ppt or less.

Assignees

• Organo Corp

Inventors

• Takahashi Kazushige
• Sudo Fumio
• Nakamura Yuki
• Shibasaki Kenji
• Sasaki Keisuke

Classifications

• B01D61/026

  comprising multiple reverse osmosis steps · CPC title

• C02F2301/08

  Multistage treatments, e.g. repetition of the same process step under different conditions · CPC title

• C02F2301/066

  Overpressure, high pressure · CPC title

• C02F2101/30

  Organic compounds · CPC title

• C02F2101/108

  Boron compounds · CPC title