Method for the preparation of friction material, specifically for the manufacture of brake pads and associated brake pads

Patent metadata

Field	Value
Publication number	US-12036696-B2
Application number	US-201917270250-A
Country	US
Kind code	B2
Filing date	Aug 23, 2019
Priority date	Aug 24, 2018
Publication date	Jul 16, 2024
Grant date	Jul 16, 2024

Abstract

Method for creating a brake pad with a block of friction material, in which sodium hydroxide and sodium silicate are dissolved in water, the aqueous solution of sodium hydroxide and sodium silicate is mixed with commercial metakaolin until a wet paste is obtained, the wet paste is formed and dried until a dried geopolymeric aggregate is obtained, the aggregate is ground to a powder, the dried ground aggregate is used as an exclusive or almost-exclusive inorganic geopolymeric binder in a friction material compound and the raw compound is hot-molded under a pressure greater than a water saturation pressure at the molding temperature.

First claim

The invention claimed is:

1. A method for creating a block or layer of friction material without asbestos and insensitive to heat degradation in use, the method comprising:
obtaining a basic aqueous solution, at a pre-fixed pH, of an alkaline silicate and a hydroxide in water through dissolving, in water, an alkaline silicate powder of sodium or potassium;
mixing the aqueous solution of hydroxide and alkaline silicate with a material selected from a group consisting of metakaolin, kaolin, fly ash, and mixtures of thereof until a wet paste is obtained;
forming and drying the wet paste until a dried geopolymer aggregate is obtained, wherein a final moisture content of the dried geopolymer aggregate is less than 30% in weight calculated on the total weight of the geopolymer binder after drying;
grinding the dried geopolymer aggregate to a powder;
mixing the ground dried aggregate as an inorganic binder with inorganic and/or organic and/or metallic fibers, at least one friction modifier or lubricant, and at least one filler or abrasive into a friction material compound to obtain a raw frictional material compound having as binder the ground dried geopolymeric aggregate; and
hot molding between about 40° C. and about 300° ° C. the raw frictional material compound under pressure greater than a water saturation pressure at the molding temperature to obtain a block of friction material having at least 90% geopolymer as binder.

2. The method according to claim 1 , wherein obtaining the basic aqueous solution further comprises:
dissolving in the basic sodium or potassium hydroxide solution a generic source of silica.

3. The method according to claim 2 , wherein the generic source of silica comprises quartz or colloidal silica.

4. The method according to claim 3 , forming and drying the wet paste is performed to obtain a weight of the final product between 5 and 50% of the original weight, which corresponds to a final moisture content of less than 30%.

5. The method according to claim 1 , wherein obtaining the basic aqueous solution is performed to obtain the alkaline solution of sodium silicate in water with a pH between 12 and 14.

6. The method according to claim 1 , wherein mixing the aqueous solution is performed to obtain a percentage in weight of soda or potash between 0 and 10%, and wherein the caustic hydroxide/alkaline silicate solution and metakaolin, kaolin or fly ash are mixed by mechanical agitation to obtain a formation of a homogeneous viscous paste containing no agglomerates of metakaolin, kaolin or fly ash not adequately dispersed in the solution.

7. The method according to claim 1 , wherein grinding the dried geopolymer aggregate is performed with a temperature between 20° to 300° C. and normally under atmospheric pressure, conditioning up to a vacuum state.

8. The method according to claim 1 , wherein grinding the dried geopolymer aggregate is preferably performed by a ball mill to obtain a product consisting of a dried geopolymer aggregate ground into powder, with a granulometry below 800 microns.

9. A method for obtaining an inorganic binder for friction material without asbestos and insensitive to heat degradation during use, the method comprising:
obtaining a basic aqueous solution, at a pre-fixed pH, of an alkaline silicate and a hydroxide in water through dissolving, in water, an alkaline silicate powder of sodium or potassium;
mixing the aqueous solution of hydroxide and alkaline silicate with a material selected from a group consisting of metakaolin, kaolin, fly ash, and mixtures of thereof until a wet paste is obtained;
forming and drying the wet paste under atmospheric pressure until a dried geopolymer aggregate is synthesized, wherein a final moisture content of the dried geopolymer aggregate is less than 30% in weight calculated on the total weight of the geopolymer binder after drying; and
grinding the dried geopolymer aggregate to a powder, wherein the ground dried geopolymer aggregate constitutes the inorganic binder.

10. The method according to claim 9 , wherein the material mixed with the aqueous solution of hydroxide and alkaline silicate is powder metakaolin.

11. The method according to claim 9 , wherein obtaining the basic aqueous solution further comprises:
dissolving in the basic sodium or potassium hydroxide solution a generic source of silica.

12. The method according to claim 11 , wherein the generic source of silica comprises quartz or colloidal silica.

13. An inorganic binder for friction materials without asbestos and insensitive to heat degradation during use, the inorganic binder comprising:
a hydroxide and an alkaline silicate dissolved, in water, an alkaline silicate powder of sodium or potassium and mixed with a material selected from a group consisting of metakaolin, kaolin, fly ash, and mixtures of thereof until a wet paste is obtained, wherein the wet paste is formed and dried under atmospheric pressure until a dried geopolymer aggregate is synthesized and ground into a powder, wherein the inorganic binder has:
a moisture content less than 30% in weight;
an Si/Al molar ratio between 1.5-6;
a granulometry of less than 800 microns;
an alkaline hydroxide content in the mixing stage between 0 and 10%;
a FTIR spectrum with peak associated with a symmetrical vibration of the Si—O bond which moves from its initial position of 1038 cm −1 for metakaolin to a value of less than 1000 cm −1 for the geopolymer obtained after the mixing stages with the silicate and alkaline hydroxide solution and drying;
an amorphous structure after the synthesis stage;
the ability to reconsolidate if exposed to pressure and temperature between 150 and 2000 kg/cm 2 and 100-250° C.; and
a reconsolidation mechanism of the geopolymer powder for temperature and pressure conditions similar to those normally used in the production of brake pads; and

wherein the inorganic binder maintains its amorphous structure after the consolidation stage.

14. A brake pad with a block of non-asbestos friction material comprising:
inorganic and/or organic and/or metallic fibers;
at least one filler or abrasive;
at least one friction modifier or lubricant; and
at least one binder, wherein the at least one binder is
almost completely or completely and exclusively inorganic,
made up at least 90% of an amorphous geopolymer or a mixture of amorphous geopolymers, and
obtained through
obtaining a basic aqueous solution, at a pre-fixed pH, of an alkaline silicate and a hydroxide in water through dissolving, in water, an alkaline silicate powder of sodium or potassium;
mixing the aqueous solution of hydroxide and alkaline silicate with a material selected from a group consisting of metakaolin, kaolin, fly ash, and mixtures of thereof until a wet paste is obtained;
forming and drying the wet paste until a dried geopolymer aggregate is obtained, wherein a final moisture content of the wet paste is less than 30% in weight calculated on the total weight of the geopolymer binder after drying;
grinding the dried geopolymer aggregate to a powder;
mixing the ground dried aggregate as an inorganic binder with inorganic and/or organic and/or metallic fibers, at least one friction modifier or lubricant, and at least one filler or abrasive into a friction material compound to obtain a raw frictional material compound having as binder the ground dried geopolymeric aggregate; and
hot molding between about 40° C. and about 300° ° C. the raw frictional material compound under pressure greater than a water saturation pressure at the molding temperature to obtain a block of friction material having at least 90% geopolymer as binde

Assignees

• Itt Italia Srl

Inventors

• Sin Xicola Agustin
• Vannucci Francesco
• Colombo Paolo
• Conte Alberto

Classifications

• F16D2200/0095

  Mixing an aqueous slurry of fibres with a binder, e.g. papermaking process · CPC title

• F16D2200/006

  containing fibres or particles · CPC title

• F16D2200/0034

  non-metallic · CPC title

• F16D69/028

  containing fibres · CPC title

• C04B18/08

  Flue dust {, i.e. fly ash} · CPC title