Hydrothermal-assisted transient jet fusion additive manufacturing

Patent metadata

Field	Value
Publication number	US-12036606-B2
Application number	US-202017103430-A
Country	US
Kind code	B2
Filing date	Nov 24, 2020
Priority date	Nov 27, 2019
Publication date	Jul 16, 2024
Grant date	Jul 16, 2024

Abstract

Various embodiments of the present disclosure provide an additive manufacturing method. The method includes forming a first layer of a first ceramic material and forming a second layer of a second ceramic material. The method further includes contacting the first layer of the first ceramic material, the second layer of the second ceramic material, or both with a saturant. The method further includes heating the first layer of the first ceramic material, the second layer of the second ceramic material, or both to a temperature in a range of from about 50° C. to about 300° C. The method further includes applying pressure to the first layer of the first ceramic material, the second layer of the second ceramic material, or both. The pressure can be in a range of from about 10 kPa to about 800 MPa. The method further includes at least partially dissolving a portion of an external surface of a ceramic particle of the first layer of the first ceramic material, the second layer of the second ceramic material, or both. The method further includes fusing a portion of the dissolved portion of the external surface of the ceramic particle to from a product having a density in a range of from about 65% to about 100% relative to a corresponding fully densified product and optionally containing no organic binder.

First claim

What is claimed is:

1. An additive manufacturing method, comprising:
forming a first layer of a first ceramic material with a thickness in the range of 0-500 microns;
forming a second layer of a second ceramic material with a thickness in the range of 0-500 microns;
contacting selected regions within the first layer of the first ceramic material, the second layer of the second ceramic material, or both with a saturant, through an inkjet printhead, independently in a range of from about 1 wt % to about 10 wt % of the first ceramic material and the second ceramic material, wherein the selected regions comprises less than 100% of the first or second layer;
applying pressure to the first layer of the first ceramic material, the second layer of the second ceramic material, or both, wherein the pressure is in a range of from about 10 kPa to about 800 MPa;
heating the first layer of the first ceramic material, the second layer of the second ceramic material, or both to a temperature in a range of from about 50° C. to about 300° C.;
at least partially dissolving a portion of an external surface of a ceramic particle of the first layer of the first ceramic material, the second layer of the second ceramic material, or both, using the saturant;
fusing a portion of the dissolved portion of the external surface of the ceramic particle as the saturant evaporates to form a product having a density in a range of from about 65% to about 100% relative to corresponding fully densified product.

2. The additive manufacturing method of claim 1 , wherein the first ceramic material and the second ceramic material independently comprises vanadium oxide, fused aluminium oxide material, heat treated aluminium oxide material, sintered aluminium oxide material, silicon carbide material, titanium diboride, boron carbide, tungsten carbide, titanium carbide, cubic boron nitride, garnet, fused alumina-zirconia, cerium oxide, zirconium oxide, titanium oxide, silica, barium titanate, calcium phosphate, or mixtures thereof.

3. The additive manufacturing method of claim 1 , wherein the first layer of the first ceramic material, the second layer of the second ceramic material, or both are heated to a temperature in a range of from about 50° C. to about 200° C.

4. The additive manufacturing method of claim 1 , wherein the pressure applied to the first layer of the first ceramic material, the second layer of the second ceramic material, or both, wherein the pressure applied to the first layer of the first ceramic material, the second layer of the second ceramic material, or both is in a range of from about 10 kPa to about 700 MPa.

5. The additive manufacturing method of claim 1 , wherein the pressure is applied by a pressing piston.

6. The additive manufacturing method of claim 1 , wherein the product has a density in a range of from about 80% to about 95% relative to a corresponding fully densified product.

7. The additive manufacturing method of claim 1 , wherein the method is free of contacting a binder with the first layer of the first ceramic material, the second layer of ceramic material, or both.

8. The additive manufacturing method of claim 1 , wherein the saturant comprises water.

9. The additive manufacturing method of claim 8 , wherein the saturant further comprises glycerine, lactam, glycol, or a mixture thereof.

10. The additive manufacturing method of claim 1 , wherein the saturant comprises an organic material.

11. The additive manufacturing method of claim 10 , wherein the organic material comprises a substituted or unsubstituted (C 1 -C 20 )hydrocarbyl.

Assignees

• Univ Iowa Res Found

Inventors

• Song Xuan
• Fei Fan
• Kirby Levi J

Classifications

• B28B1/001

  Rapid manufacturing of 3D objects by additive depositing, agglomerating or laminating of material (selective deposition modelling of metallic powder B22F10/00; rapid manufacturing of 3D objects in general and in particular of plastics B29C64/00) · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B22F2302/256

  Silicium oxide (SiO2) · CPC title

• B22F2302/253

  Aluminum oxide (Al2O3) · CPC title

• B22F2302/105

  Silicium carbide (SiC) · CPC title